改性淀粉胶粘剂在胶合板生产中的应用

通过对淀粉胶粘剂应用于胶合板生产中的关键技术问题进行分析,提出解决方案;探讨制胶中各单因素对改性淀粉胶粘剂粘度的影响;并采用正交试验法确定改性淀粉胶粘剂生产胶合板的最佳热压工艺     

柠条、花棒、杨柴材的pH值、缓冲容量及其对脲醛树脂胶固化时间的影响

本文实测了内蒙古伊盟地区产沙生灌木柠条、花棒、杨柴材的pH值.酸碱缓冲容量,并就脲醛树脂胶固化时间等指标,从理论上分析三种灌木材的酸碱性质对胶合性能的影响。结果表明,三种灌木材均呈弱酸性,pH值为5.88～6.01,酸性接近。三种灌木材总缓冲容量范围为0.326～0.394mmol,其中酸缓冲容量为0.018～0.031mmol,碱缓冲容量为0.295～0.376mmol。脲醛树脂胶的固化时间随着三种灌木材的pH值和碱缓冲容量的增加而增长。     

稻壳/大豆蛋白基黏合剂成型育苗钵性能评价及成因分析

以稻壳为原材料, 采用大豆蛋白基黏合剂捏合成型制备育苗钵, 研究了稻壳育苗钵的耐水特性;通过育苗试验研究了育苗钵对黄瓜的生物学效应, 并分析了育苗钵育苗周期与拉伸强度间的相关性。结果表明:育苗钵最大平衡吸水率及厚度膨胀率分别为26.78%和10.73%,具有较好的耐水特性;育苗钵经干湿热循环处理后拉伸强度最大降幅约50%(P<0.05).生物学效应试验表明, 育苗钵高浓度浸提液对黄瓜发芽率影响显着, 低浓度浸提液对种子发芽率有一定的促进效应;育苗效果试验验证育苗钵对黄瓜生长长势有促进作用。以干湿热循环处理后拉伸强度为自变量, 育苗钵育苗周期为因变量, 建立了相关模型y=-0.35X²+9.43X-5.85(R²=0.947 3).该育苗钵具有适宜的耐水性和强度, 育苗效果良好, 是一种理想的育苗器具, 可应用于作物的育苗。     

落叶松树皮热解油替代部分苯酚合成酚醛树脂胶的研究

为降低酚醛树脂胶(PF)生产成本,提高木材废弃物利用率,利用落叶松树皮热解油部分替代苯酚合成PF胶,探讨其用量对PF树脂胶性能的影响,并进行成本分析.结果表明:落叶松树皮热解油-PF胶具有良好的胶合性能,制备的胶合板可满足GB/T 9846.3-2004中Ⅰ类胶合板的强度要求,且生产成本降低.     

Shear fracture characterization of green-glued polyurethane wood adhesive bonds at various moisture and gluing conditions

Abstract

The shear fracture properties of green-glued one-component polyurethane (PUR) wood adhesive bonds subjected to kiln drying were investigated. The local shear strength and fracture energy of the wood adhesive bonds were determined from experimentally recorded complete shear stress versus deformation curves of the bond line. A stable test set-up and small specimens that were anti-symmetrically loaded were used in order to get a uniform and pure state of shear stress. Different moisture contents (MCs) and pressing times were investigated. The fracture properties of conventionally dry-glued wood adhesive bonds and of solid wood were used as reference. The results show that the fracture energy of green-glued bonds with PUR adhesive is dependent on the MC of wood and on the pressing time. The same fracture energy and strength can be obtained by green gluing as by dry gluing, but there seems to exist a maximum MC of sapwood, in the range between 78% and 160%, and a minimum pressing time, in the range between 3 h and 48 h, for which it can be achieved. Both dry- and green-glued polyurethane adhesive bonds were more ductile than solid wood.     

An experimental approach to determine pull-out strength of single and multiple axially loaded steel rods bonded in glulam parallel to the grain

ABSTRACT

A glued-in rods' connection is generally constituted by a group of steel bars bonded by an adhesive into timber elements. In the past, most of the research focused on single-rod connections, in order to exploit the maximum resistance of the connection without accounting for interaction among bars or splitting failure in the timber member due to close edge distances or spacing between bars. Such interaction problems arise when dealing with multiple rods, thus requiring specific investigation to fully understand the behavior of the connection as a whole and to determine its capacity. In both cases, existing test procedures determine bond strength in specific geometrical configuration. The paper aims to determine the pull-out strength of single and multiple axially loaded steel rods bonded in glulam parallel to the grain differentiating the adhesive failure from the other failure modes. After an initial review of typical applications and existing design procedures, test results on single rod with confined or unconfined test setup on single rod at different embedment depths are presented and discussed, indicating that the confinement has a negligible influence on the pull-out capacity. Subsequently, interaction between bars is investigated by a specific unconfined configuration. The accounted parameters are the embedment depth of the bars, the dimensions of the timber section, and the spacing between bars. Results are discussed and compared with three-dimensional numerical simulations. Both experimental and numerical results suggest that the critical value at which the transition from pull-out to timber-related failure is observed depends on the mechanical properties of the timber and on the properties of the adhesive, such that a single value of spacing should not be provided in design standard if the full capacity of the adhesive is to be exploited.     

ACQ防腐胶合板胶合性能的研究

用氨(胺)溶性季铵铜(ACQ)作防腐剂,采用浸渍法对单板进行防腐处理,分别以酚醛树脂(PF)和脲醛树脂(UF)为胶黏剂,压制防腐胶合板,研究ACQ对胶合性能的影响。结果表明:用PF将经防腐处理的单板压制成胶合板,单板ACQ吸药量对胶合性能影响不明显。马尾松和杨木单板的ACQ吸药量分别为7.81和15.54 kg.m-3时,最佳胶合强度分别为1.50和1.69 MPa。用UF将经防腐处理的单板压制成胶合板,单板ACQ吸药量对杨木胶合板胶合性能影响不明显,吸药量为8.75 kg.m-3时,胶合强度最佳,为1.60 MPa;但ACQ防腐剂对UF胶马尾松胶合板胶合性能有负面影响,使胶合强度达不到国家标准要求,如果将马尾松单板蒸煮处理后再浸渍ACQ或者浸渍ACQ后在低温下干燥,胶合强度明显提高,最大值分别达到1.32和1.03 MPa,这是由于经过处理去除了马尾松单板内的部分抽出物或阻止了ACQ与抽出物的某些成分反应,从而减小了ACQ对UF胶马尾松胶合板胶合强度的影响。     

环境友好型胶合板用脲醛树脂胶黏剂的研究

对不同固化体系下低摩尔比脲醛树脂胶黏剂的固化时间、适用期进行探讨,研究其对胶接性能、甲醛释放量的影响。结果表明：不同固化体系,物理力学性能不同,胶接强度均达到国家标准II类板的要求,甲醛释放量均达到E0级。当使用NQ-J0-1,n甲醛∶n脲素=1∶1,V固化剂∶m胶液=5 mL∶100 g,性能最佳。     

色板对葱蓟马诱捕量的BP神经网络模型预测

利用羧甲基纤维素钠和甘油为主要原料配制的水溶性胶黏着剂制作3种颜色粘板,在露天菜地的同一处地点进行田间蓟马诱捕测试。将测试结果作为BP神经网络模型的训练样本与预测样本进行建模分析,结果表明,黏合剂中诱虫物质的添加因素对葱蓟马田间诱捕量的影响权重最大,蓝色大型粘板诱捕蓟马效果最好,模型对预测样本的预测值与实际观测值基本吻合。     

可见光固化天然胶乳压敏胶的研制

采用可见光引发体系固化将降解天然胶乳与萜烯树脂乳液的其他助剂组合制备水乳型压敏胶,研究在一定光照强度下,降解天然胶乳与萜烯树脂乳液的不同配比,天然胶乳不同分子量,其他助剂的用量对压敏胶性能的影响。结果表明,降解天然胶乳与萜烯树脂乳液质量比为1∶1、降解天然胶乳分子量为19.8&#215;10^4、引发剂1.2%、交联剂15%、促进剂0.4%时压敏胶性能最优。DSC和TG/DTG表明含有光引发剂的压敏胶在光照后热稳定性提高,压敏胶的Tg升高了5℃,仍具有很低的使用温度。