不同施肥结构对酸性黄棕壤修复效果研究

利用3年田间定位试验,研究了不同施肥结构对酸性黄棕壤酸性、交换性能以及微生物区系的影响。结果表明:连年施用有机肥以及配施石灰和白云石粉均能显著降低土壤中交换性酸和交换性Al~(3+)的含量,提高土壤pH,且不同施肥结构对修复黄棕壤酸性的效果为有机肥配施石灰有机肥配施白云石粉有机肥;连年施用有机肥以及配施石灰主要提高了土壤中交换性Ca~(2+)含量,而配施白云石粉则主要提高了土壤中交换性Mg~(2+)含量;有机肥配施石灰和白云石粉均降低了土壤中真菌的数量,但提高了土壤中细菌/真菌比、放线菌/真菌比以及细菌和放线菌数量,改善了土壤微生物群落结构,增加了烟叶的产量和产值。     

酸性黄壤施用磷石膏对高粱营养生长和膜保护酶的影响

采用盆栽试验, 研究了贵州强酸性(pH 4.3)黄壤施用磷石膏对高粱生长、养分平衡、细胞膜保护酶活性的影响.结果表明, 在强酸性土壤上种植耐铝能力弱的高粱, 铝毒害明显, 即使施用足量的氮磷钾肥, 作物也生长不良.施用磷石膏和石灰后高粱出苗和生长正常, 各生物学性状均极显著优于对照, 施磷石膏高粱长势优于施石灰处理;高粱干物质量与磷石膏(X1)、石灰(X2)的施用量呈二次曲线变化(回归方程分别为: Yw=6.88+11.92X1-1.65X12, R=0.983**;Yw=6.88+6.39X2-0.72X22, R=0.996**);磷石膏降低酸性黄壤铝毒、提高植物钙含量的效果略逊于石灰, 在提高植物营养3要素(特别是磷、钾元素)的作用方面优于石灰, 施磷石膏植株磷含量是石灰处理的1.17～2.43倍;施高量磷石膏的高粱植株氮/磷、氮/钾、钾/磷比值分别为6.8～7.1、1.2～1.3和5.4～5.6, 比值适中、变幅小, 氮/铝、磷/铝、钾/铝、钙/铝比值提高, 改善和调节了高粱体内氮、磷、钾、钙养分的平衡.高粱叶片细胞膜保护酶(SOD、CAT和POD)活性分析表明, 施磷石膏、石灰后SOD和CAT活性增加, POD活性和脯氨酸含量下降, 施磷石膏效果优于石灰.     

石灰和海泡石对镉污染土壤的修复效应与机理研究

研究了稻作和旱作两种种植制度下,施用石灰、海泡石及两种改良剂配施对镉污染土壤pH值、土壤镉形态变化及作物对镉的吸收等的影响.结果表明,施用改良剂使稻作条件下的土壤pH提高0.3～1.8个单位,旱作条件下土壤pH提高幅度为0.3～2.0个单位:两种种植制度下,作物有效性较高的酸提取态镉含量显著减少,而作物有效性较低的可还原态和残渣态镉含量显著增加,进而引起了水稻和萝卜对镉的吸收量降低.其中以石灰和海泡石配施的效果最好,单施海泡石次之,单施石灰效果最差,且各处理均随改良剂用量的增加效果增强,虽然,施用改良剂可以有效降低土壤中镉的作物有效性,但对水稻产量和生物量及镉在水稻和萝卜两种作物地上部分的分配规律均没有明显的影响.     

石灰石粉提高酸性土壤紫云英产量及养分截获

南方耕作土壤酸化问题普遍,探明酸性土壤施用石灰石粉对紫云英产量与养分截获的影响,为紫云英轻简化高产高效栽培提供依据。盆栽试验条件下,在强酸性水稻土和酸性红壤上分别设7个水平的石灰石粉改良剂施用量。每盆装土2 kg,石灰石粉用量分别为0(CK)、0.267 g/盆(T1)、0.534 g/盆(T2)、0.801 g/盆(T3)、1.068 g/盆(T4)、1.335 g/盆(T5)、1.602 g/盆(T6)(折算为0、600、1200、1800、2400、3000、3600 kg/hm²)。盛花期测定紫云英产量、养分截获、土壤pH值及交换性酸。结果表明,与CK相比,水稻土施用石灰石粉的紫云英鲜草产量增幅为41.5%～122.8%,产量随施用量的增加呈先增加后降低的趋势,红壤增幅为175.2%～989.1%,增产效果随施用量的提高呈递增趋势,两种土壤分别以T4与T6处理鲜草产量最高,与CK差异显著;水稻土施用石灰石粉氮素截获量增幅为147.5%～614.7%,红壤氮素截获量增幅为285.7%～1316.8%。水稻土施用石灰石粉后土壤pH值较CK增长1.5%～5.1%,交换性铝含量降幅为7.3%～55.9%,红壤施用石灰石粉pH值比CK增长3.4%～18.8%,交换性铝含量降幅为32.3%～95.4%;红壤施用石灰石粉后鲜草及干草产量与土壤pH值呈极显著正相关关系。酸化土壤是限制紫云英产量与养分截获提升的重要的因素。在红壤和水稻土上施用石灰石粉能提高紫云英的产量、养分截获、土壤pH值,降低土壤交换性铝含量。相同用量下,在酸性红壤上的改良效果优于强酸性水稻土。强酸性水稻土与酸性红壤施用石灰石粉后土壤pH值分别为4.66和7.05时,紫云英鲜草和干草产量最高。     

酸性土壤施石灰对土壤性质与烤烟品质的影响

试验研究酸性土壤施石灰对土壤生物化学性质、烤烟生长和品质的影响结果表明,施用适量石灰可增加土壤细菌、放线菌、好气性纤维素分解菌数量,增强脲酶、酸性磷酸酶、过氧化氢酶和纤维素酶活性。pH值5.2的土壤石灰施用量以750～1125kg/hm~2为宜,可促进烤烟根系生长,提高烤烟产量和品质。     

调节茶园土壤pH对其土著微生物区系及生理群的影响

茶园酸性土壤按其重量1.4%的比例施用石灰,能使土壤pH值从4.1提高到6.88;土壤中细菌和放线菌数量能提高近百倍,适于酸性环境的真菌数量略低于不施用石灰的对照组;酸性土壤经pH调节后,土壤pH值在前45天呈缓慢下降趋势,随后有所升高;细菌各类生理群数量在pH调节后前期呈快速上升变化,经过20～30天稳定期后,开始下降;调节茶园酸性土壤的pH是提高茶园土壤土著微生物数量和活性的最好方法。     

不同酸化剂对石灰性土壤pH值、磷有效性的影响

以滴灌方式通过少量多次向土壤施用酸化剂,研究不同酸化剂对石灰性土壤的酸化效果及对玉米磷吸收的影响,以期为提高石灰性土壤的磷素有效性提供理论依据。试验设置对照及两种酸化剂(磷酸脲,硫酸铵+氯甲基吡啶),酸化剂投入量相当于P2O5=60或120 kg/hm~2的等价酸,共计5个处理。施用酸化剂显著降低局部土壤pH值,磷酸脲的作用最佳,土壤pH值最大降幅为0.11个单位,同时也显著提高土壤有效磷含量;在等养分投入和管理水平下,施用酸化剂能增加玉米植株的生物量,提高植株的磷素累积量,且与对照相比,120 kg/hm~2的硫酸铵+氯甲基吡啶处理的玉米产量提高了8.3%。滴灌条件硫酸铵+氯甲基吡啶的酸化效果优于磷酸脲,且高酸化剂量土壤酸化强度较大。滴灌条件下施用酸化剂或酸性肥料是提高石灰性土壤养分有效性和作物增产的一种有效方法。     

连施石灰对 Cd污染土壤 Cd形态及稻麦吸收 Cd的影响

为探索成都平原轻度Cd污染耕地有效治理措施,以稻麦轮作耕地为研究对象,采用田间试验,施加不同梯度石灰作为钝化剂,研究连续3年施加石灰后,对土壤Cd形态以及水稻、小麦籽粒吸收Cd的影响。结果表明,当每季石灰施用量为2 250 kg/hm~2时,稻麦产量较高,籽粒重金属Cd含量达到《食品安全国家标准-食品中污染物限量》(GB 2762-2012)规定的限值。当石灰施用量为1 500～3 000 kg/hm~2时,能有效提高土壤pH值,改善土壤酸性。随石灰用量的增加土壤Cd有效性降低,且水稻、小麦籽粒Cd含量也随之降低。与对照相比,每季石灰施用量为2 250和3 000 kg/hm~2的处理,水稻籽粒Cd含量分别降低到0.12和0.08 mg/kg;小麦籽粒Cd含量分别降低到0.097和0.075 mg/kg。施用石灰可促进土壤中可交换态Cd向可还原态和残渣态Cd转换,土壤可交换态Cd从对照的44.1%降至3 000 kg/hm~2石灰处理的29.0%;而残渣态从对照处理的18.8%升高到34.3%。     

不同改良剂对酸性土壤的修复效应

为明确不同改良剂对酸性植烟土壤的修复效应,采用盆栽试验,分析了施用丰收延酸性土壤改良剂、金叶酸性土壤改良剂及石灰后土壤pH、水解性酸、潜性酸及土壤交换性能的动态变化。结果表明:施用改良剂可提高土壤pH 3.01%~24.11%,降低土壤水解性酸16.08%~50.46%、交换性Al 3+51.80%~64.27%、交换性H+含量84.12%~93.56%,提高土壤交换性盐基总量45.18%~46.16%、阳离子交换量0.33%~20.10%、盐基饱和度21.35%~49.78%。施用土壤改良剂后,土壤pH先升高后下降,至移栽60天后趋于稳定;土壤水解性酸在烤烟移栽后30~90天差异较小,至移栽后120天略有增加。施用石灰的土壤交换性氢、交换性铝一直下降,但施用丰收延、金叶酸性土壤改良剂的土壤交换性铝下降至烟苗移栽后120天略有增加,土壤交换性氢上升至烟苗移栽后120天大幅度下降。施用土壤改良剂后,土壤交换性盐基总量、阳离子交换量、盐基饱和度一直提高,但变化幅度较小。不同土壤改良剂的材料来源及组成成分不同,其对酸性土壤的恢复效果也不同,以施用石灰的效果最好。     

有机无机肥配施锌肥和石灰对双季稻产量及土壤养分特性的影响

在南方典型双季稻种植区,通过2年试验综合评价在有机无机肥配施基础上施用锌肥和石灰对双季稻产量与土壤养分特性的影响,以期提出培肥土壤和提高水稻产量的理想施肥模式。设置有机肥+无机肥(T1)、锌+有机肥+无机肥(T2)、石灰+有机肥+无机肥(T3)、锌+石灰+有机肥+无机肥(T4)4个处理,测定了土壤有效锌、碱解氮、有效锌含量和pH,分析了水稻产量和土壤综合肥力。结果表明:(1)相比T1处理,T2处理显著提高了早晚稻千粒重和结实率,显著增产8.7%,而T3处理不利于水稻稳产,显著降低了千粒重,并在第2年减产(5.6%)显著;T4处理表现出来的产量规律与T3处理类似,均于第2年表现减产。(2)施用锌肥、石灰均有利于提高土壤有效磷和碱解氮含量,石灰显著提高土壤pH,但T3、T4处理土壤有效锌含量显著下降,较T1处理分别下降39.0%和31.9%,而连年施用锌肥有利于有效锌的提高,T2较T1处理土壤有效锌含量提高22.2%。(3)土壤综合肥力表现为T2T4T1T3,施用锌肥相比石灰更有利于提高土壤肥力。综上所述,施用锌肥能显著提高土壤速效养分含量,增产显著,而连年施用石灰显著降低了土壤中有效锌含量。因此,在缺锌土壤中需慎施石灰,而长期施用石灰的土壤,应追施锌肥。综合土壤养分含量和水稻产量评价,有机+无机+锌肥的施肥模式为理想施肥模式。     

不同改良剂降低矿区土壤水溶态重金属的效果及其长效性

为了解施用不同种类改良剂对降低矿区土壤重金属移动性的长期效果,进行为期6年的模拟试验,用化学提取方法评价磷灰石、农用石灰、坡缕石、钙镁磷肥、沸石、猪粪和水稻秸秆7种常用改良剂对降低土壤重金属溶解性的影响。结果表明,农用石灰、钙镁磷肥、磷灰石、坡缕石和沸石对降低矿区土壤水溶态重金属均有良好的效果,但猪粪和水稻秸秆有机物改良剂的效果较差。降低土壤水溶态Cd的效果以钙镁磷肥为最佳(平均可降至29%),降低土壤水溶态Cu的效果以坡缕石为最佳(平均可降至65%),降低土壤水溶态Pb的效果以磷灰石、石灰和钙镁磷肥3种改良剂为佳(平均可降至27%左右);降低土壤水溶态Zn的效果以钙镁磷肥为最佳(平均可降至48%)。磷灰石和沸石对土壤重金属的稳定性有较长的作用效果,坡缕石、石灰和钙镁磷肥对土壤重金属稳定性随试验时间增加有明显的下降;有机物类改良剂对土壤重金属的稳定效果较差,且随有机物质的降解,其稳定效果显著下降。     

Effect of zeolite application and soil pH on cadmium sorption in soils

Abstract

In this study the influence of zeolite application and soil liming on cadmium (Cd) sorption by soils in Greece was investigated. The zeolite was natural and consisted mainly of clinoptilolite. The soil samples were strongly acid surface horizons of an Alfisol limed from a pH of 4.0 to 8.5, and a neutral Bt horizon. The result showed that liming and zeolite application substantially increased sorption of Cd in the soils. Cadmium sorption was described adequately by the Freundlich equation whereas the Langmuir model failed to describe Cd sorption in the soils. The Freundlich constant K increased in value by zeolite application as well as by soil liming. A strong relationship was observed between this parameter and soil pH. A high percentage of cadmium sorbed was released in the desorption procedure. The amount of Cd released was reduced by zeolite application as well as by soil liming. It is concluded that zeolite application as well as soil liming increased Cd sorption by the soils.     

冻融循环与沸石掺配对黑土物理性质的影响

冻融循环作用是东北黑土区发生土壤侵蚀的原因之一,施加土壤改良剂是减弱土壤侵蚀的有效方法。该研究以未经冻融循环作用和未经沸石掺配的黑土作为对照,将天然沸石与黑土按不同比例掺配,探究冻融循环作用和沸石掺配对黑土物理性质的影响,研究表明:1)冻融循环作用增大黑土容重、粘聚力、微孔占比、次大孔占比,减小土壤总孔隙度和内摩擦角,沸石掺配可以降低冻融循环作用对除内摩擦角以外土壤物理性质的影响;2)沸石掺配黑土增大黑土容重、粘聚力、内摩擦角、微孔占比,减小土壤总孔隙度,冻融循环作用对沸石掺配黑土的作用会产生负面影响,但是随着沸石掺配比例增大,冻融循环作用的影响减弱。     

6种固化剂对土壤Pb Cd Cu Zn的固化效果

通过在重金属污染土壤中分别施加沸石、石灰石、硅藻土、羟基磷灰石、膨润土和海泡石6种固化剂,研究了这6种固化剂对土壤中Pb、Cd、Cu、Zn的固化效果,筛选出几种效果较好的固化剂。实验结果表明：沸石、石灰石和羟基磷灰石均能够有效地降低土壤中交换态Pb、Cd的含量,并且明显减少了土壤中Pb、Cd的毒性浸出量,其中沸石最多降低土壤中交换态Pb、Cd含量分别达到48.7%和56.2%,减少土壤中Pb、Cd的毒性浸出量达到37.1%和30.1%;沸石、石灰石均能够有效降低土壤中交换态Cu的含量,降低量分别高达68.1%和85.2%,膨润土能有效减少土壤中Cu的毒性浸出量,减少量最高达到66.51%;石灰石对土壤中Zn有着良好的固化效果。     

Soil cadmium stabilization using an Iranian natural zeolite

In recent years, natural substances such as zeolite have been used to absorb heavy metals in soil in an attempt to decrease their availability to plants. Compared to other techniques, the use of zeolite is fast, clean, and inexpensive. This research was carried out to investigate the effects of an Iranian natural zeolite (clinoptilolite) on stabilizing Cd-contaminated soil treated with 0.01 M CaCl₂ leaching solution. Zeolite from Firoozkouh (Tehran Province) was added to four soils from Gilan province, northern Iran. The stabilization of Cd in soils mixed with zeolite was measured in both column and batch experiments. The results from the batch experiment showed that application of zeolite to soil reduced Cd leaching in all the contaminated soils. When more zeolite was added to soil, lower Cd concentrations were detected in the leaching solution. When 15% zeolite was applied, Cd concentration in the leachate decreased to below 0.1 mg l^− 1. Cadmium depth analysis showed little migration of Cd in sand and clay textures with no zeolite addition and after adding 15 and 75 pore volumes of leaching solution, the remaining Cd levels were 12% and 35% of the original Cd concentration, respectively. However, these values for 9% zeolite treatments were 97% and 99%, respectively. The higher cation exchange capacity of the zeolite/soil mixture and the higher pH levels were responsible for stabilizing Cd in these soils. The effect of preventing heavy metals from leaching was found to be more pronounced when zeolite was applied to clay soils.     

铵饱和沸石对几种重金属离子的吸附解吸特性影响研究

通过室内分析的方法比较了天然沸石及铵饱和沸石对重金属离子Cd2+、Zn2+、Cu2+、Pb2+的吸附及解吸特性。研究结果表明:铵饱和沸石对4种重金属离子的吸附量大小顺序依次为Pb>Cu>Zn>Cd,而解吸量和解吸率的大小顺序为Cd>Zn>Cu>Pb,这主要与四种金属离子的水合离子半径和水合能密切相关。与天然沸石相比,铵饱和沸石一方面增加了对4种重金属离子的吸附,同时又降低了其解吸率。原因是铵饱和沸石的阳离子交换量和比表面积有所增加,同时铵饱和沸石的孔穴和通道也较天然沸石更加均一和畅通。因此,铵饱和沸石在农业生产实践中,特别是土壤污染治理方面具有广阔的应用前景。     

Growth,photosynthesis, and uptake of heavy metals by barley and corn plants influenced by different methods of zeolite and phosphogypsum application

Abstract

Natural zeolite can be used as a heavy metals adsorbent from phosphogypsum, applied as a soil amendment. We used barley and corn seedling to investigate the effect of different methods of zeolite and phosphogypsum application on (a) growth, photochemical activity of chloroplasts and chlorophyll content; (b) uptake of strontium (Sr), calcium (Ca), and cadmium (Cd) in relation to photosynthetic activity, and content of these elements in the soil. Phosphogypsum was found to negatively influence the growth and development of the seedlings, affecting their morphology traits, biomass production and photosynthetic activity. Therefore, the application of phosphogypsum together with natural zeolite, according to the recommended technique, “in mixture”; completely erased consequences of phosphogypsum treatment. Uptake of Sr by barley plants was noticed to be highly dependent on photosynthetic activity and leaf area, however, there was no close correlation found between the content of water soluble Sr in the soil and its accumulation in plants.     

Effect of zeolite on saturated hydraulic conductivity and crack behavior of silty clay paddled soil

The addition of zeolites to soil modifies soil physical and chemical properties. The objectives of this research were to study the effect of zeolite on saturated hydraulic conductivity, K _s, and crack behavior in a silty clay paddled soil. Soil samples were mixed with 0, 4, 8 and 12 g kg^?1 of zeolite for K _s determination, and 0, 2, 4, 8 and 12 g kg^?1 for soil crack measurements. Saturated hydraulic conductivity was measured using the constant head method. The results indicated that K _s was significantly increased at a zeolite application rate of 8 g kg^?1. Furthermore, an increase in zeolite content up to 8 g kg^?1 decreased soil crack area after paddling and first rewetting. Higher amounts of zeolite (e.g. 12 g kg^?1) increased crack density after the second rewetting. However, a 50% reduction in crack depth occurred with zeolite application rates of 8 and 12 g kg^?1 in comparison with controls. Thus, a zeolite application rate of 8 g kg^?1 is recommended for soil crack reduction in intermittent-flood irrigation. Furthermore, a relationship was obtained between crack area density (Ln), gravimetric soil water content and zeolite application rate. After the second irrigation, a relationship was also obtained between crack depth, gravimetric soil water content and zeolite application rate. Crack depth showed a positive and highly significant linear correlation with crack width.     

石灰石和海泡石组配对水稻糙米重金属积累的影响

为了研究组配改良剂(石灰石+海泡石,LS)对于重金属Pb、Cd、Cu和Zn复合污染稻田的修复效果,在湘南某矿区附近稻田中进行了组配改良剂的田间试验。结果表明:施用0~1.8 kg m-2的组配改良剂LS使土壤pH和CEC显著增加,使土壤中Pb、Cd、Cu和Zn交换态含量显著降低。土壤Pb、Cd、Cu和Zn交换态含量的降低是pH升高,土壤胶体的CEC增加及土壤吸附能力增强的共同作用。施用组配改良剂LS显著降低了3个水稻品种(黄华占、丰优9号、Ⅱ优93)糙米中Pb、Cd和Cu的累积量,最大降幅分别为55.8%、66.9%、37.4%,而对糙米中Zn的含量没有明显影响。当LS施用量为1.8 kg m-2时,能使丰优9号糙米中Cd含量(0.195 mg kg-1)达到国家食品中污染物限量标准(0.20 mg kg-1)以下。土壤中交换态Pb、Cd和Cu含量的降低是糙米中重金属累积量减少的原因。土壤交换态Pb、Cd和Cu含量的对数值(lnC交换态)与其糙米中含量(lnC糙米)的对数值之间存在显著的线性相关关系。     

Zinc Uptake by Spinach (Spinacia oleracea L.) as Affected by Zn Application Rate,Zeolite, and Vermicompost

Zinc deficiency in calcareous soils is a serious problem, which may be ameliorated by the application of some soil amendments. A completely randomized factorial experiment was done to investigate the effect of zeolite, vermicompost, zeolite + vermicompost, and Zn application to a calcareous soil on Zn availability, dry weight of spinach (Spinacia oleracea L.), and Zn concen-tration in spinach. Results indicated that zeolite had no effect on soil Zn availability, dry weight, and Zn concentration in spinach. Vermicompost significantly increased dry weight (1.33 g pot^?1) and decreased Zn concentration in spinach (16 mg kg^?1). Application of zeolite + vermicompost significantly increased dry weight (by 2.8 times) and Zn uptake in spinach and it also decreased Zn concentration in spinach less than vermicompost. Zinc application increased Zn concentration in spinach (up to 496 mg kg^?1), but did not affect dry weight except in soils treated with zeolite + vermicompost. Generally, application of zeolite + vermicompost is recommended instead of separate zeolite or vermicompost application for improvement of soil Zn fertility and Zn uptake by spinach.