Rare earth elements have been used as sediment tracers in river, estuarine and coastal environments but rarely applied as fluvial tributary tracers. Lanthanides (Ln) and yttrium (Y) were quantified in fluvial sediments of the Minho River lower course (NW Iberian Peninsula), where the catchment contains heterogeneous lithologies, to define the characteristic imprints of tributaries and their relevance in the riverine system.
Materials and methodsSurface sediments were sampled at 36 points in the lower Minho riverbed and its nine main tributaries.The <?2-mm fraction was sieved and ground, and ≈?100 mg was completely acid-digested with HF and aqua regia in closed Teflon bombs at 100 °C for 1 h. The residue was evaporated, re-dissolved with HNO3 and Milli-Q water, heated 20 min at 75 °C and diluted to 50 cm3 with Milli-Q water. Lanthanides and yttrium were determined using a quadrupole ICP-MS equipped with a Peltier impact bead spray chamber and a concentric Meinhard nebuliser. Blanks accounted for less than 1% of the element concentrations in the samples. The precision and accuracy of the analytical procedures were controlled through reference materials AGV-1 and MAG-1.
Results and discussionContents ranged from 22 to 153 mg Ln kg?1 and 1.5–22.9 mg Y kg?1 and ES-normalised light-heavy Ln fractionation, (LN/HN), varied between 0.6 and 2.6. These wide ranges, together with Eu and Ce anomalies and element-by-element Ln, varied with changes in parental rocks of the lower Minho basin. Minho sediments showed negative Ce anomalies (0.81?±?0.29) and positive Eu anomalies (1.23?±?0.18). Sediments received traces of granitic pegmatites and gneissic peralkaline rocks from two tributaries: the Gadanha (22.9 mg Y kg?1; 83 mg Ln kg?1; 0.60 LN/HN; 0.51 Eu/Eu*; 0.88 Ce/Ce*) and the Louro (15.9 mg Y kg?1; 110 mg Lnkg?1; 0.97 LN/HN; 0.69 Eu/Eu*; 1.49 Ce/Ce*). The Tamuxe tributary, flowing through a slate and quartzite fault, provided the lowest source (1.6 mg Y kg?1; 28 mg Ln kg?1; 2.48 LN/HN; 1.01 Eu/Eu*; 0.55 Ce/Ce*).
ConclusionsLanthanide and Y signatures in sediments may be used to trace land-tributary-river influences. The imprints are observed downstream of fluvial confluences but not in all cases, responding to basin lithological changes, particularly for pegmatites and peralkaline rocks. The general REE trend is described using Y contents only. Tributaries, which are responsible for one-fifth of the Minho water load, provide one-half of their sediments. Non-homogeneous sediment patterns may be magnified in dammed rivers such as the Minho.
相似文献River sediment, the important sink and source of heavy metals, can provide critical information for aquatic ecosystem health. Heavy metal pollution has been a serious problem facing river systems worldwide and can adversely affect human beings via the food chain. However, no comprehensive study has been conducted on heavy metal pollution in sediments of river systems in the hilly area of southern China, which plays a key role in water supply and ecosystem balance. This study is aimed at comprehensively studying the pollution status of heavy metals in river sediments in the hilly area of southern China and apportioning sources.
Materials and methodsA total of 39 superficial sediment samples were collected from the upstream, midstream, and downstream of 13 rivers (Xiangjiang River, Zishui River, Yuanjiang River, and Lishui River located in Hunan Province; Ganjiang River, Xinjiang River, Fuhe River, Raohe River), and Xiushui River located in Jiangxi Province; Qiantangjiang River and Oujiang River located in Zhejiang Province; Minjiang River and Jiulongjiang River located in Fujian Province) in the hilly area of southern China. The total concentrations of metals of Mn, Zn, Cr, Co, Ni, Cu, As, Cd, Sb, Pb, and V were analyzed using the inductively coupled plasma-mass spectrometry method. The pollution status and potential ecological risk were assessed with the geoaccumulation index (Igeo), sediment quality guidelines (SQGs), and potential ecological risk index (RI). The source apportionment of heavy metals was performed by correlation analysis and principle component analysis (PCA).
Results and discussionResults indicated that Mn, Zn, and Pb concentrations were significantly higher than other metals, especially in the upstream of the Jiulong River and midstream and downstream of the Xiangjiang River. Pollution assessment indicated that Cd pollution of sediments was most serious and that more than 50% of sampling sites were significantly polluted, with a very high potential ecological risk. The rivers in Hunan provinces (HN) were identified as the priority controlled rivers because of the high Igeo and RI index values. Correlation and PCA analysis indicated that Mn, Pb, and Zn originated from natural and mineral exploitation activities; As, V, Ni, and Sb originated from industrial wastewater and mineral-smelting activities; Cu and Co originated from agricultural activities; Cr and Ni originated from natural sources. While the most polluted Cd came from a combination of multiple sources described above.
ConclusionsResults indicated that Cd was the most common heavy metal pollutant, especially in river sediments of Hunan Province. Anthropogenic activities have become the main source of heavy metals in the river sediments of the hilly area of southern China. Special attention should be paid to Cd, and measures must be taken to prevent from further anthropogenic influence on heavy metal pollution.
相似文献The use of rare earth elements (REEs) as tracers provides a high-precision method for quantitative determinations of soil particle movement in soil erosion studies. In this study, a new calculation method was developed and tested to improve the precision of the REE tracing method and to expand the application of this method to areas with coarse-textured soils.
Materials and methodsThis study used purple soil to simulate a catchment with data based on a field survey of a small catchment located in the Three Gorges Area in China. Eight different powdered rare earth oxides, which included La2O3, CeO2, Nd2O3, Sm2O3, Eu2O3, Tb4O7, Ho2O3 and Yb2O3, were applied as tracers to describe soil movement in this scaled catchment during three simulated rainfall events of 1.0, 1.5 and 2.0 mm min?1 rainfall intensity. Leaching experiments were conducted to investigate the vertical migration of REEs in soil layers. Particle size distributions (PSDs) and REE concentrations for each soil particle size class (1–2, 0.5–1, 0.25–0.5, 0.1–0.25, 0.075–0.1, 0.05–0.075, 0.02–0.05, 0.005–0.02 and <0.005 mm) were analysed to evaluate the precision of the proposed calculation method.
Results and discussionMost REEs remained in the first layer during leaching. The scanning electron microscopy-energy dispersive X-ray (SEM-EDX) mapping images showed that more REEs were adsorbed by small particles (≤0.1 mm), with large specific surface areas, than by large particles (>0.1 mm). During the three rainfall events, the coarsest size classes (1–2 and 0.5–1 mm) of the sediment samples were less than that of the soil. In contrast, the other classes, including <0.075 mm, showed the strongest adsorption for REEs, and the weight percentage of grains in eroded sediment was more than that in the source soil. The accuracy of the new proposed calculation method increased by 24.37, 20.25 and 3.84 % for the first, second and third storm, respectively, compared with the uncorrected mass of soil loss from the scaled catchment.
ConclusionsThe REEs bonded well with purple soil particles and the leaching of REEs from the tagged layer to the lower layers was minimal. The <0.075-mm particle size class had the strongest adsorption capacity for REEs. The soil loss estimates were improved with the new calculation method.
相似文献This study investigated the concentrations of cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), nickel (Ni), zinc (Zn), and polycyclic aromatic hydrocarbons (PAHs) in sediments collected from gully pots for road drainage in Hong Kong. The presence and intensity of anthropogenic contamination of road gully sediments were assessed. Identifications of potential sources of trace elements and PAHs were performed to help understand the situation for future control of pollution to the land and aquatic environments.
Materials and methodsGully sediment samples were collected from gully pots of 18 roads that are potentially exposed to different pollution sources in Hong Kong. The selection of roads considered different road features, adjacent land uses, and traffic volumes. Composite samples were collected for the analysis of trace elements (Cd, Cr, Cu, Pb, Ni, and Zn) and PAHs by an accredited environmental testing laboratory. Geo-accumulation index (Igeo), contamination factor (Cf), modified degree of contamination (mCd), ecological risk factor (Er), and pollution load index (PLI) were used to assess the level of ecological risk of trace element contamination. Positive matrix factorization (PMF) and PAH diagnostic ratios were applied to identify the sources of trace elements and PAHs.
Results and discussionElevated trace element concentrations were commonly found in gully sediments. The concentrations of Zn (267–3700 mg kg?1) were the highest compared to the other trace elements. Noticeable high concentrations of Cu (27–1020 mg kg?1), Pb (21–332 mg kg?1), and Cr (14–439 mg kg?1) were found in all samples. The PAH contents were moderate to high (0.6 to 24.7 mg kg?1). Commercial/industrial emissions and road features that cause frequent acceleration-deceleration and turning events showed important influences on the contaminant levels. Strong correlations between the concentrations of Cd, Cr, Pb, and Zn were identified, implying that these trace elements are likely from common sources. The contamination assessment indices reflect significant sediment pollution. The ecological risk ranges from the considerable/moderate-risk class to over the high-risk class.
ConclusionsThe collected gully sediments are identified as highly contaminated and need to be isolated from the environment upon final disposal. Through the comprehensive analysis of the collected data, this study provides a detailed insight into the contaminant levels of road gully sediments and potential sources of contamination. Disposal of gully sediments and potential impacts due to release of contaminants into the downstream aquatic environment during rainstorm events should receive attention and need further investigation.
相似文献Mercury (Hg) and methylmercury (MeHg) are easily released from sediments to overlying water and cause secondary contamination. In general, Hg concentrations are low in natural aquatic environments, but Hg toxicity is high. Therefore, it is important to assess the mobility and release risks of Hg and MeHg from surface sediment using in situ high-resolution sampling techniques.
MethodsThe profile distribution of Hg and MeHg was obtained for samples from Weishan sub-lake (WL) and Dushan sub-lake (DL) of Nansi Lake, China, by high-resolution dialysis (HR-Peeper probes) and the diffusive gradients in thin films (DGT) technique at mm-resolution. Furthermore, Hg mobility and release risks in sediments were evaluated by combining BCR (European Community Reference Bureau) extraction and DGT-measured data.
ResultsThe soluble concentrations of Hg in surface sediments in WL and DL were 21.70 and 19.38 ng L?1 and the DGT-labile concentration of Hg were 8.21 and 10.30 ng L?1, respectively. The soluble and labile Hg and MeHg concentrations were higher in the surface sediments (from??40 to 0 mm) than in deep sediments. The distribution of the labile-Hg was controlled by the ferrimanganic (hydr)oxide and total nitrogen rather than organic carbon content. The non-residual components accounted for a greater proportion of the interface, which further confirmed Hg was more active on the surface layer of the sediment. The resupply ability indicated that the release of Hg from sediment was insufficient to maintain the initial concentration in the porewater before consumption. The MeHg fluxes in WL (6.18 ng m?2 day?1) were twice those in DL (2.89 ng m?2 day?1), and the risk assessment code revealed a higher risk in the surface layer (25.21–61.88%) than in the deep layer (0–27.75%).
ConclusionsDissolved Hg and MeHg accumulated on the surface of the sediments and were more active than in the deeper sediments. The DGT-labile state can be used for a better understanding of the bioavailability and mobility of Hg. The diffusion direction of Hg and MeHg was from sediment to the overlying water. The release risks of Hg and MeHg from surface sediments (especially in WL) were found to be worthy of concern.
相似文献Here, the roles of sediment components in perfluorooctane sulfonate (PFOS) adsorption onto aquatic sediments and relevant adsorption mechanisms were investigated in terms of adsorption isotherms and influences of TiO2 nanoparticles (NPs) contamination.
Materials and methodsDue to the complexity of the sediments, instead of randomly selecting different component sediments, the selective dissolution method was used to better explore the effects of sediment compositions, such as sediment organic matter (SOM) and ferric oxides (dithionite–citrate–bicarbonate [DCB] Fe), and TiO2 NPs pollution on PFOS adsorption. Mathematical equations (Freundlich, Langmuir, and Temkin) were used to describe the adsorption behavior of PFOS on different sediments and adsorption mechanisms of multiple pollutant interactions. Moreover, the characterization methods of zeta potential, nitrogen (N2) adsorption–desorption, and scanning electron microscopy (SEM) analysis, as well as Fourier transform infrared (FT-IR) spectroscopy, explained effects of the sediment components and TiO2 NPs on PFOS adsorption properties in view of physicochemical theories.
Results and discussionThe adsorption isotherms of PFOS on six tested sediments were all nonlinear (Freundlich model, R2 = 0.992~1.000). The Freundlich sorption affinities (KF) of PFOS on S (original sediments), S1 (sediment organic matter (SOM)-removed S), and S2 (ferric oxides (DCB Fe)-removed S1) were 0.232, 0.179, and 0.120, respectively. Both SOM and DCB Fe influenced the physicochemical properties of the sediments, e.g., zeta potential, specific surface area, and permanent negative charge. The addition of TiO2 NPs increased the KF of PFOS for S, S1, and S2 by approximately 9.9%, 14.5%, and 26.7%, respectively, by increasing the zeta potential and specific surface area (SBET, Sext, and Smicro) and by changing the water and oil properties of the three sediments. However, the addition of TiO2 NPs decreased the linearity of the sorption isotherm (1/n). FT-IR spectroscopy showed that hydrophobicity, ion exchange, surface complexation, and hydrogen bonding interactions (non-fingerprint region) could all play a role in PFOS sorption onto tested sediments. However, the hypothesis of hydrogen bonding to promote PFOS adsorption on sediment layer silicates (fingerprint region) should be studied further.
ConclusionsThe content of both SOM and DCB Fe affected the physicochemical properties of sediment. Both SOM and DCB Fe showed a positive relationship with sorption of PFOS on sediment. The addition of TiO2 NPs increased PFOS sorption by altering the sediment surface properties. Hydrophobic interactions certainly impelled and ligand and ion exchange and hydrogen bonding (non-fingerprint region) could promote PFOS sorption on the sediments.
相似文献Antibiotics are emerging contaminants of increasing concern in recent years. A total of 71 representative farmland soils along the Fenhe River in Shanxi Province were collected to investigate the occurrence of tetracyclines (TCs), sulfonamides (SAs), and quinolones (QLs). Additionally, the effects of population, livestock and poultry density, and soil properties on antibiotic distribution were also evaluated.
Materials and methodsFarmland topsoil samples along the Fenhe River were collected and freeze-dried at ??20 °C. The antibiotics in soils were extracted with a mixture of acetonitrile, EDTA-SPB, and Mg(NO3)2-NH3·H2O at the ratio of 2:1:1 (v/v/v). The extracted antibiotics were analyzed by liquid chromatography tandem mass spectrometry (LC-MS/MS).
Results and discussionThe antibiotics were universally detected. The detection frequencies of sulfaclozine, enrofloxacin, norfloxacin, and ciprofloxacin reached 100%. Norfloxacin was the most abundant antibiotic in soils (27.21 μg kg?1). The distribution of antibiotics in soils along Fenhe River varied as midstream (8.62 μg kg?1) > downstream (4.58 μg kg?1) > upstream (3.49 μg kg?1). Oxytetracycline along the upstream and midstream was mainly caused by the emission of livestock and poultry and the overuse of human. The main sources of antibiotics along the downstream were livestock and poultry farms. Antibiotics were generally negatively correlated with sand content, pH, and organic matter, while cation exchange capacity had positive correlation with most of antibiotics such as tetracycline, sulfamonomethoxine, enrofloxacin, sulfameter, and sulfachinoxalin. SAs and TCs had little ecological risk, while QLs posed low or medium ecological risks.
ConclusionsThis study provided a scientific basis for antibiotic pollution control and agricultural safety supervision along the Fenhe River. Although no high risk of antibiotics was observed in soil samples based on the calculation, the widespread distribution of antibiotics in farmland soil along Fenhe River should be addressed.
相似文献Are rare earth element (REE) patterns employable as tracers in human interventions of bulk soil disturbances, when high concentrations of metals are involved in the in situ soil disturbance? In terms of bulk soil disturbance, it is difficult to distinguish between bulk soil disturbances and emplacement of new earthen material. Chemical fingerprinting, in particular REE plus yttrium, is applied across many fields, but predominantlyin tracking the sources of potential environmental contaminants.
Materials and methodsThe REE normalised patterns (HNO3:HF:HCl 3:1:1 digestion, ICP-MS) of two Calcaric Cambisols were compared with those of a Geric Ferralsol (Novic, Technic) originated from selective overburden of nickel mining (20°40′ N, 75°35′ W).
Results and discussionThe sum of REE, including Y and Sc, ranged between 48 and 101 mg kg?1. Principal component analysis (PCA) shows a discriminant role of REE. REE signature normalised to the upper continental crust shows slight positive Eu and negative Ce anomalies in the case of both Calcaric Cambisols, while the Geric Ferralsol shows anomalous patterns with the same anomalies plus a slight positive anomaly of Y, as a consequence of the addition of mining by-products.
ConclusionsHere, we show that REE patterns of the individual horizons of a soil have characteristics that allow us to distinguish undisturbed from soils mixed with other soil materials, including those with different pH values and high metal contents (e.g. Cr, Mn, and Ni ≥?0.5%, Fe ??5 wt%). Our results demonstrate, by using soils with contrasting characteristics, that their origins can be traced via the patterns of their REEs, even in the presence of high concentrations of other metals. In perspective, when background maps of all REE elements in soils are available worldwide on an appropriate scale, this enables us to obtain a level of discriminatory detail on a local scale.
相似文献The purpose of this research was to study the generation, sink, and emission of greenhouse gases by soils on technogenic parent materials, created at different stages of the Moskva River floodplain development (1—construction and 2—landscaping of residential areas).
Materials and methodsField surveys revealed the spatial trends of concentration and emission of the greenhouse gases in following groups of soils: Retisols (RT-ab-ct) and Fluvisols (FL-hu, FL-hi.gl) before land engineering preparation for the construction, Urbic Technosols Transportic (TC-ub-ar.tn and TC-ub-hu.tn) at stage 1 and Urbic Technosols Folic (TC-ub-fo) at stage 2. CO2 and CH4 concentration in soils and their emission were determined using subsurface soil air equilibration tubes and the closed chamber method, respectively. Bacterial methane generation rate (MGR) and methane oxidation rate (MOR) were measured by kinetic methods.
Results and discussionIn natural soils MOR is caused only by intra-aggregate methanogenesis. The imbalance of methane generation and oxidation was observed in FL-hi.gl. It caused CH4 accumulation in the profile (7.5 ppm) and its emission to the atmosphere (0.11 mg CH4 m?2 h?1). RT-ab-ct acted as the sink of atmospheric methane. CO2 emission was 265.1?±?24.0 and 151.9?±?37.2 mg CO2 m?2 h?1 from RT-ab-ct and FL-hi.gl, respectively. In Technosols CH4 concentration was predominantly low (median was 2.7, 2.9, and 3.0 ppm, in TC-ub-ar.tn, TC-ub-hu.tn, and TC-ub-fo, respectively), but due to the occurrence of peat sediments under technogenic material, it increased to 1–2%. Methane emission was not observed due to functioning of biogeochemical barriers with high MOR. In TC-ub-ar.tn and TC-ub-hu.tn, the barriers were formed at 60-cm depth. In TC-ub-fo, the system of barriers was formed in Folic and Technic horizons (at 10- and 60-cm depth). CO2 emission was 2 times lower from TC-ub-ar.tn and TC-ub-hu.tn and 1.5 times higher from TC-ub-fo than from natural soils.
ConclusionsGreenhouse gas generation, sink, and emission by natural soils and Technosols in floodplain were estimated. CO2 and CH4 content in Technosols varied depending on the properties of parent materials. Technosols at stage 1 did not emit CH4 due to formation of biogeochemical barriers—soil layers of high CH4 utilization rates. Urbic Technosols (Folic) at stage 2 performed as a source of significant CO2 emission.
相似文献In contaminated streams, understanding the role of streambank and streambed source contributions is essential to developing robust remedial solutions. However, identifying relationships can be difficult because of the lack of identifying signatures in source and receptor pools. East Fork Poplar Creek (EFPC) in Oak Ridge, TN, USA received historical industrial releases of mercury that contaminated streambank soils and sediments. Here, we determined relationships between the contaminated streambank soils and sand-sized streambed sediments.
Materials and methodsField surveys revealed the spatial trends of the concentrations of inorganic total mercury (Hg) and methyl mercury (MeHg), Hg lability as inferred by sequential extraction, particle size distribution, and total organic carbon. Statistical tests were applied to determine relationships between streambank soil and streambed sediment properties.
Results and discussionConcentrations of Hg in streambank soils in the upper reaches averaged 206 mg kg?1 (all as dry weight) (n?=?457), and 13 mg kg?1 in lower reaches (n?=?321), while sand-sized streambed sediments were approximately 16 mg kg?1 (n?=?57). Two areas of much higher Hg and MeHg concentrations in streambank soils were identified and related to localized higher Hg concentrations in the streambed sediments; however, most of the streambank soils have similar Hg concentrations to the streambed sediments. The molar ratio of Hg to organic carbon, correlation between MeHg and Hg, and particle size distributions suggested similarity between the streambank soils and the fine sand-sized fraction (125–250 μm) collected from the streambed sediments. Mercury in the fine sand-sized streambed sediments, however, was more labile than Hg in the streambank soils, suggesting an in-stream environment that altered the geochemistry of sediment-bound Hg.
ConclusionsThis study revealed major source areas of Hg in streambank soils, identified possible depositional locations in streambed sediments, and highlighted potential differences in the stability of Hg bound to streambank soils and sediments. This work will guide future remedial decision making in EFPC and will aid other researchers in identifying source–sink linkages in contaminated fluvial systems.
相似文献Currently, the distribution characteristics and transport processes of the radionuclides 137Cs and 239?+?240Pu in the sediments of estuaries are still a controversial issue. Thus, in the present study, we investigated the distribution characteristics, sources and migration path of 137Cs and 239?+?240Pu in sediment cores of the Liao River estuary (LRE), China, and evaluated the relative contributions of the Pacific Proving Grounds (PPG) and riverine sources of Pu for the sediments in this area. We used 137Cs and Pu isotopes for dating the sediments and estimated the sedimentation rates by the two radionuclides in the LRE.
Materials and methodsSeven sediment samples were collected using a box corer from the Liao River estuarine wetland and tidal flat in the LRE in October 2012 and April 2015, respectively. The activities of 137Cs in the various samples were determined by γ spectrometry using HP-Ge detectors with 60% relative counting efficiency. Approximately 2–5 g of sediment were spiked with 242Pu (ca. 1 mBq) as a chemical yield tracer for Pu isotopic analysis at the School of Radiation Medicine and Protection, Soochow University. The measurement of Pu isotopes (239Pu, 240Pu, 242Pu) was performed by a sector field ICP-MS. In order to quantitatively differentiate the relative proportions of global fallout and PPG, we employed a two-end member mixing model to estimate their contributions.
Results and discussionThe average values of 137Cs, 239?+?240Pu activity concentrations, and 240Pu/239Pu atom ratios in the surface sediment samples of the LRE were 6.727?±?0.251 mBq g?1, 0.294?±?0.024 mBq g?1, and 0.188?±?0.049 (1σ), respectively. The average 240Pu/239Pu atom ratios ranged from 0.180?±?0.034 to 0.199?±?0.021 in sediment cores from the east and west sides of the LRE. For core LT-2 values for 137Cs and 239?+?240Pu concentrations were from below the detection limit: 3.380?±?0.414 and 0.036?±?0.007 to 0.105?±?0.007 mBq g?1. The mean 240Pu/239Pu atom ratio 0.217?±?0.050 (1σ) in sediment core LT-2 lies between the global fallout and PPG close-in fallout.
ConclusionsWe found that atmospheric fallout is the main source of Pu in sediment cores from the east and west sides of the LRE. For core LT-2, atmospheric fallout and riverine input (~?73.4%) are the major sources of Pu with the source of the rest of Pu (~?26.6%) attributed to the PPG via the Tsushima Warm Current and the coastal water of the East China Sea. The sedimentation rates (means 0.62–0.8 cm year?1) estimated by the two radionuclides were in good agreement and without any statistically significant difference.
相似文献Stripping contaminants from sediments with granular activated carbon (GAC) is a promising remediation technique in which the effectiveness depends on the rate of contaminant extraction from the sediment by the GAC. The purpose of the present study was to investigate the effect of mixing intensity on the short-term extraction rate of polycyclic aromatic hydrocarbons (PAHs) from contaminated sediment.
Materials and methodsPAH desorption from sediment at a wide range of rotational speeds (min?1; rotations per minute (rpm)) was monitored by uptake in Tenax polymeric resins using a completely mixed batch reactor. Desorption data were interpreted using a radial diffusion model. Desorption parameters obtained with the radial diffusion model were correlated with particle size measurements and interpreted mechanistically.
Results and discussionFast desorption rate constants, D e /r 2, with D e the effective diffusion coefficient and r the particle radius, ranged from 3.7 × 10?3 to 1.1 × 10?1 day?1 (PHE) and 6 × 10?6 to 1.9 × 10?4 day?1 (CHR), respectively, and increased with the intensity of mixing. The D e /r 2 values would correspond to D e ranges of 1.8 × 10?14–1.2 × 10?16 m2 × day?1 and 1.8 × 10?12–3.7 × 10?15 m2 × day?1, assuming fast desorption from the measured smallest particle size (9 μm) classes at 200 and 600 rpm, respectively.
ConclusionsDesorption of PAHs was significantly accelerated by a reduction of particle aggregate size caused by shear forces that were induced by mixing. The effective intra-particle diffusion coefficients, D e , were larger at higher mixing rates.
相似文献Purpose
The geochemistry of rare earth elements (REEs) taken from the sediments of a karst lake was analyzed to track the provenance of the sediments and the history of soil erosion in the Jiuzhaigou Nature Reserve (JNR) in Sichuan Province in southwest China.Materials and methods
The REE concentrations of 177 samples including 150 lake sediments, 13 soils, 8 loess, 3 carbonate rocks, and 3 water were determined using a quadruple inductively coupled plasma mass spectrometer (Q-ICP-MS). The grain size distributions of 139 sediment samples were measured using a Malvern Master Size 2000 laser particle size analyzer. The carbonate contents of 159 sediment samples were determined using a gasometric method. The dried remains after reaction with HCl were defined as acid-insoluble residues. The mineral composition of the sediments was measured using a Philips X'Pert Pro X-ray diffractometer.Results and discussion
The lake sediments in the JNR exhibit features similar to those of the neighboring soils, i.e., enriched REE content, a greater ratio of light REEs to heavy REEs, greater δCe values, and lower δEu values relative to those in the carbonate rocks. The REE signatures in the silt and sand fractions of the sediments are similar to those in the soils and carbonate rocks, respectively. The REE content, LREE/HREE, and δCe values in the sediments strongly negatively correlate with the carbonate content, indicating an intense carbonate effect on the REE geochemistry. The content of acid-insoluble residues is obviously positively correlated with ∑REEs in the sediments, and a negative relationship is observed between ∑REEs and the ratio of calcite to quartz in the sediments.Conclusions
The sediments in the JNR originate from eroded soils and authigenic travertine deposits in the lakes. It is proposed that the increased ∑REEs in the sediments resulted from the elevated proportion of soil particles in lacustrine deposits was due to increasing soil erosion intensity. This hypothesis is evidenced by the coupling of ∑REEs with the intensity of soil erosion and anthropogenic activities in the JNR. In karst drainage, the total REE concentration might be a potentially powerful indicator for reconstructing the history of soil erosion. 相似文献It has been reported the bioaccumulation of γ-ferric oxide nanoparticles (Fe2O3 NPs) or oxytetracycline (OTC) in crops. However, there have been little references investigating their uptake and bioaccumulation in crops after the combined exposure. The present study focused on Fe2O3 NPs and OTC accumulation on root surface and in the tissues of rice (Oryza sativa L.) seedlings under combined exposure. And, the interactive influence mechanism was also discussed.
Materials and methodsHydroponic experiments were conducted to investigate the Fe and OTC accumulation on root surface and in rice tissues under individual and combined exposure of Fe2O3 NPs and OTC. The dynamic change of particulate Fe, ionic Fe, and Fe plaque concentrations on root surface was determined under the influence of OTC from Fe2O3 NPs and Fe-EDTA exposure. Fe2+ from Fe-EDTA was selected in order to compare the Fe bioaccumulation from ionic Fe and nanoparticle Fe exposure. Hydrodynamic diameter and ζ-potential of Fe2O3 NPs in solution were investigated when OTC was present or not, and the changes of OTC concentrations were also determined during hydroponic culture. SEM, XRD, and TEM were used to analyze Fe2O3 NP distribution on root surface and inside root under the influence of OTC.
Results and discussionOTC promoted surface-Fe and shoot-Fe accumulation in Fe2O3 NPs treatments, which was just an opposite result from Fe-EDTA treatments. Upon Fe2O3 NP exposure, Fe plaque was formed through the direct adsorption of NPs on the outside root surface and then incorporated into plaque as its crystalline components. OTC elevated notably surface-Fe accumulation mainly through increasing adsorption and precipitation of Fe2O3 NPs on the root surface due to low repulsive electrostatic interaction between NPs and the root surface after adding OTC. Fe2O3 NPs increased surface-OTC and root-OTC levels. Compared to Fe-EDTA, surface-Fe from NP treatments can hold strongly OTC due to Fe2O3 particle precipitated on root surface with high specific surface area. NPs reduced shoot-OTC under 25 mg L?1 OTC, but not under 100 mg L?1 OTC.
ConclusionsThis study clearly demonstrates that Fe/OTC accumulation in rice was always in the order root surface > shoot > root, whether Fe2O3 NPs/OTC was individual or combined exposure. The combined exposure will increase their root surface distribution comparing with individual exposure, and Fe2O3 NPs increased also root-OTC levels, which could pose a potential risk to food safety in subsequent growth of rice.
相似文献This study examined the usefulness of 15N natural abundance (δ15N) with in situ core incubation to quantify the predominant N transformation processes in a natural suburban forest of subtropical Australia, which was subjected to prescribed burning.
Materials and methodsIn situ core incubation for 3 days with 20 ml water, or 160.79 ml of 60 mg L?1 NO3?-N surface application, and in situ core with 160.79 ml water but without incubation were set up in Toohey forest for sampling three times as before (once) and after (twice) a prescribed burning. The δ15N of NH4+-N and NO3?-N in the top 5 cm soil before and after the incubation, and δ15N of NO3?-N in the 5–10 cm soil before incubation were compared with each other to examine the soil N mineralisation, nitrification, denitrification, and nitrate leaching processes.
Results and discussionThe significant decrease in δ15N of NH4+-N after incubation under 20 ml water treatment was ascribed to soil N mineralisation, and the significant decrease in δ15N of NH4+-N and significant increase in δ15N of NO3?-N after incubation with elevated water and nitrate inputs were associated with N mineralisation and nitrification, respectively, 2 months after the burning. The 160.79 ml water treatment also triggered nitrification in the baseline soil cores in both samplings after the burning. Water was crucial to stimulate soil N mineralisation and nitrification, but excessive water depleted labile N pools and reduced N mineralisation and nitrification. Burning effects were hard to separate from the seasonal impacts on soil N cycling processes.
ConclusionsThe δ15N in soil mineral N pools was sensitive to indicate soil N mineralisation and nitrification processes. Soil water and labile N were determining factors for N transformations in the soil. It is suggested that δ15N combined with soil inorganic N concentrations and net N transformation rates could be used to identify primary N transformation processes. More frequent samplings would be needed to differentiate burning impacts from the seasonal impacts on soil N cycling processes.
相似文献Accelerated erosion removes fertile top soil along with nutrients through runoff and sediments, eventually affecting crop productivity and land degradation. However, scanty information is available on soil and nutrient losses under different crop covers in a vertisol of Central India. Thus, a field experiment was conducted for 4 years (2010–2013) to study the effect of different crop cover combinations on soil and nutrient losses through runoff in a vertisol.
Materials and methodsVery limited information is available on runoff, soil, and nutrient losses under different vegetative covers in a rainfed vertisol. Thus, the hypothesis of the study was to evaluate if different crop cover combinations would have greater impact on reducing soil and nutrient losses compared to control plots in a vertisol.
This experiment consisted of seven treatment combinations of crop covers namely soybean (Glycine max) (CC1), maize (Zea mays) (CC2), pigeon pea (Cajanus cajan) (CC3), soybean (Glycine max)?+?maize (Zea mays) ??1:1 (CC4), soybean (Glycine ma x))?+?pigeon pea (Cajanus cajan) ?2:1 (CC5), maize (Zea mays)?+?pigeon pea (Cajanus cajan) ??1:1 (CC6), and cultivated fallow (CC7). The plot size was 10?×?5 m with 1% slope, and runoff and soil loss were measured using multi-slot devisor. All treatments were arranged in a randomized block design with three replications.
Results and discussionResults demonstrated that the runoff and soil loss were significantly (p?<?0.05) higher (289 mm and 3.92 Mg ha?1) under cultivated fallow than those in cropped plots. Among various crop covers, sole pigeon pea (CC3) recorded significantly higher runoff and soil loss (257 mm and 3.16 Mg ha?1) followed by that under sole maize (CC2) (235 mm and 2.85 Mg ha?1) and the intercrops were in the order of maize?+?pigeon pea (211 mm and 2.47 Mg ha?1) followed by soybean?+?maize (202 mm and 2.38 Mg ha?1), and soybean?+?pigeon pea (195 mm and 2.15 Mg ha?1). The lowest runoff and soil loss were recorded under soybean sole crop (194 mm and 2.27 Mg ha?1). The data on nutrient losses indicated that the highest losses of soil organic carbon (SOC) (25.83 kg ha?1), total nitrogen (N), phosphorus (P), and potassium (K) (7.76, 0.96, 32.5 kg ha?1) were recorded in cultivated fallow (CC7) as compared to those from sole and intercrop treatments. However, sole soybean and its intercrops recorded the minimum losses of SOC and total N, P, and K, whereas the maximum losses of nutrients were recorded under pigeon pea (CC3). The system productivity in terms of soybean grain equivalent yield (SGEY) was higher (p?<?0.05) from maize?+?pigeon pea (3358 kg ha?1) followed by that for soybean?+?pigeon pea (2191 kg ha?1) as compared to sole soybean. Therefore, maize?+?pigeon pea (1:1) intercropping is the promising option in reducing runoff, soil-nutrient losses, and enhancing crop productivity in the hot sub-humid eco-region.
ConclusionsStudy results highlight the need for maintenance of suitable vegetative cover as of great significance to diffusing the erosive energy of heavy rains and also safe guarding the soil resource from degradation by water erosion in vertisols.
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