滇池流域典型城郊降雨径流污染特征与排放过程

选择滇池流域典型城郊代表性的两个功能区——居民生活区和居民生活-集市混合区进行降雨径流监测,分析降雨径流污染特征及排放过程。结果表明,降雨地表径流中总氮浓度在2.18～29.40 mg·L-1,总磷浓度在0.18～3.90 mg·L-1,氨态氮浓度在0.87～18.48 mg·L-1,硝态氮浓度在0.02～3.64 mg·L-1, CODCr浓度在22.51～362.92 mg·L-1, TSS浓度在7.00～882.00 mg·L-1之间。降雨地表径流污染物浓度高于地表水Ⅴ类水环境质量标准。降雨径流中氮的主要污染物是氨态氮、颗粒态氮和溶解有机态氮,磷的主要污染物以颗粒态磷和PO3-4-P为主。降雨径流污染物浓度随降雨时间发生变化,开始产生径流时污染物浓度较高,之后随着雨强的平衡而趋于下降。降雨径流各污染物浓度是居民生活-集市混合区大于居民生活区,居民生活区径流大于屋面径流;次降雨径流污染物平均浓度（EMC）为居民生活-集市混合区普遍高于居民生活区。居民生活-集市混合区降雨径流EMC变化表现出更大的随机性。     

雨水花园对实际降雨径流的调控效果研究

基于海绵城市倡导的雨水自然积存、自然渗透、自然净化理念,根据西安地区降雨特征,设计建造了入渗型和防渗型两套雨水花园。2015~2017年对33场次降雨事件径流调控效果进行了监测分析。结果表明:(1)以原状土为填料的防渗型雨水花园设施水量削减率为11.2%~100%(中位数=69.14%);(2)污染物浓度超越概率分析结果显示,径流雨水经过雨水花园系统后,总氮、氨氮、总磷和化学需氧量出流浓度超过地表水环境质量标准Ⅳ类限制的概率,与入流浓度超过地表Ⅳ限制的概率相比,分别降低了58.57%,2.71%,20.57%和29.71%;(3)雨水花园设施场次径流水量削减率与污染物负荷削减率的相关关系在0.857以上;(4)通过监测的场次降雨量及系统进水和出水水质水量,估算的雨水花园系统年径流污染物浓度去除率为11.93%~60.97%,径流污染物年负荷削减率基本在70%以上。     

弱透水性下垫面降雨径流污染物输移特性

为了研究弱透水性下垫面降雨径流污染物的输移特性,选择兰州市作为典型城市,基于其降雨分布特点和面源污染特点提出了弱透水性下垫面径流污染物输移模型。通过对大学校园内屋面、路面及其他弱透水性下垫面组合形式下的天然降雨径流取样检测,分析了浊度,COD_cr,TN和TP等主要污染物浓度随时间的变化规律及污染物相关性研究,同时运用模型计算径流污染物初期负荷率。结果表明:校园弱透水性下垫面,降雨径流历时10～20 min各污染物浓度达到峰值。径流历时30 min内,降雨径流浊度,COD_cr,TN和TP的污染物负荷率可达到65%～85%。在中小降雨条件下,降雨径流过程中各污染物显著相关,径流污染物输移模型的适用性较好。     

Behaviour and Fluxes of Dissolved Antibiotics, Analgesics and Hormones During Flood Events in a Small Heterogeneous Catchment in the Grand Duchy of Luxembourg

The objective of this investigation is to analyse the variations of xenobiotic concentrations and the fluxes of dissolved xenobiotics during runoff events in the small rural Mess catchment (35 km²) in the Southwestern part of Luxembourg. Sulfonamides, tetracyclines, analgesics and hormones, dissolved nutrients, sulphate and chloride were measured to gather information about runoff generation. Typically, the highest values can be found during the first flush mainly in the rising limb of the flood hydrographs. The highest concentrations in eleven flood events are measured for ibuprofen (2,383 ng l^-1), estrone (27 ng l^-1) and diclofenac (20 ng l^-1). From the tetracycline group tetracycline (9 ng l^-1) itself is of relevance, while the sulfonamides are mainly represented by sulfamethoxazole (5 ng l^-1). The variable patterns of chemographs are attributed to the heterogeneous runoff generation characterised by different reactions of storm overflows from the combined sewer systems. During single flood events, the fluxes of ibuprofen (maximum 24,000 mg), 17α-ethinylestradiol (122 mg), 17β-estradiol (32 mg) or estrone (274 mg) are rather low.     

Treatment of Road Runoff by a Combined Storm Water Treatment, Detention and Infiltration System

Storm water detention devices collect runoff from impermeable catchments. They provide flow attenuation as well as storage capacity, and rely on natural self-purification processes such as sedimentation, filtration and microbial degradation. The aim was to assess the performance of an experimental combined planted gravel filter, storm water detention and infiltration tank system treating runoff from a car park and its access road. Flows were modeled with the US EPA Storm Water Management Model. An overall water balance of the system was compiled, demonstrating that 50% of the rainfall volume escaped the system as evaporation, whereas, of the remaining 50%, approximately two thirds were infiltrated and one third was discharged into the sewer system. These findings illustrated the importance of evaporation in source control, and showed that infiltration can be applied successfully even on man-made urban soils with low permeability. The assessment of the system’s hydrological efficiency indicated mean lag times of 1.84 and 10.6 h for the gravel filter and the entire system, respectively. Mean flow volume reductions of 70% and mean peak flow reductions of 90% were achieved compared to conventional drainage. The assessment of the pollutant removal efficiency resulted in promising removal efficiencies for biochemical oxygen demand (77%), suspended solids (83%), nitrate-nitrogen (32%) and ortho-phosphate-phosphorus (47%). The most important removal processes were identified as biological degradation (predominantly within the gravel ditch), sedimentation and infiltration.     

河岸带植被对非点源氮、磷以及悬浮颗粒物的截留效应

选取草地河岸带和人工林地河岸带,开展了人工模拟农田施肥和径流污染物截留效果的现场试验。分别采集地表径流和渗透水水样,测定分析了总磷(TP)、总氮(TN)、氨氮(NH4—N)以及固体颗粒物的浓度。结果表明,草地河岸带对地表径流TP的截留效果显著优于林地河岸带,草地和林地河岸带对氮元素的截留效果趋于一致;河岸带对地表径流和渗透水中TN,TP和NH4—N的截留率是相似的;草地河岸带对固体颗粒物的截留效果优于林地河岸带;河岸带越宽,其截污功能越强;人为干扰造成了人工林地河岸带截污能力的减弱。并提出了河岸带管理的相关建议。     

Spatial-temporal variations in snowfall chemistry in the montreal region

Snowfall was collected on an event basis for 6 winter storms in 1980 at 10 locations around the greater Montreal region. Six sites were urban, 2 suburban and 2 rural (small town). For all storms, 4 of the urban stations had the highest pH of the 10 locations, with the 6 Montreal Island sites having the highest chemical concentrations. Employing principal component analysis, two chemical species associations are apparent: (1) an alkaline/fly ash factor and (2) an ‘acid snow’ factor. The former indicates the possible effects of local emissions. Generally, the storms produced individual chemical concentrations patterns enabling five of the storms to be separated into distinct events. Three storms were designated as ‘type’ storms in which pH, sulphates, and nitrates varied according to individual storm characteristics and air trajectories. If the air trajectory passed over SO_x and NO_x sources to the west and south-west (Ontario-Great Lakes region) pH values were lower and sulphate and nitrate concentrations in the snowfall higher.     

昆明市云龙水库径流区氮磷非点源污染负荷分析

云龙水库是昆明市最大的城市集中式饮用水源地。水源区农业非点源污染是影响水库水质的主要来源,因此分析水库径流区氮磷非点源污染负荷与来源构成,可为饮用水源区水质保护提供科学依据。采用输出系数模型法,对昆明市云龙水库径流区氮、磷负荷的产生量与入库量进行了估算。结果表明:(1)云龙水库径流区氮、磷非点源污染负荷产生量分别为2079.8和454.32t/a,入库量分别为207.98和24.73t/a。(2)从不同乡镇分析,撒营盘镇的氮、磷负荷产生量最高,云龙乡和茂山镇产出量较低,其余乡镇产生量相近。(3)从不同污染源类型分析,该区非点源污染的主要污染源为农村生活污染和畜禽粪便污染。     

A Traditional Analysis of the First Flush Effect for Nutrients in Stormwater Runoff from Two Small Urban Catchments

Nonpoint stormwater runoff remains a major threat to surface water quality in the USA. More effective stormwater control measures can be designed by understanding patterns in pollutant export with respect to the runoff hydrograph. In particular, nutrient concentrations in urban stormwater can cause deleterious effects in sensitive watersheds in the Southeast and Mid-Atlantic USA. A year-long study captured stormwater samples from 36 storm events at two catchments (one primarily impermeable and the other substantially wooded) and analyzed for total suspended solids and various nutrient species. Using these data, the first flush effect (the assumption that the initial portion of a rainfall-runoff event is more polluted than the later portions) was evaluated based on several published methods and definitions. Based on an analysis of multiple methodologies, the ranking of first flush strength among the pollutants was total suspended solids (TSS) > ammonia (NH₃) > total Kjeldahl nitrogen > NO₂-NO₃ > total phosphorus > orthophosphate (O-PO₄). Nitrogen species generally displayed a stronger first flush than phosphorus species, with O-PO₄ showing the weakest first flush effect. Various relationships ° climate, land use, and the first flush strength were also explored. Of the rainfall characteristics analyzed, total rainfall and runoff volume each inversely affected the first flush strength of TSS on the more impervious catchment. Although orthophosphate did not have a strong first flush effect, the relative first flush strength for O-PO₄ increased with increasing rainfall or runoff. Land use did not influence the first flush strength of the pollutants. On average, most pollutants exhibited a slight first flush effect, but substantial pollutant loading still occurred in the latter portion of the storm??s total runoff volume. Thus, treating the majority of a storm??s total pollutant load requires capturing a commensurate fraction of runoff volume.     

A Field Evaluation of Rain Garden Flow and Pollutant Treatment

Rain gardens have been recommended as a best management practice to treat stormwater runoff. However, no published field performance data existed on pollutant removal capabilities. Replicated rain gardens were constructed in Haddam, CT, to capture shingled-roof runoff. The gardens were sized to store the first 2.54 cm (1 inch) of runoff. Influent, overflow and percolate flow were measured using tipping buckets and sampled passively. Precipitation was also measured and sampled for quality. All weekly composite water samples were analyzed for total phosphorus (TP), total Kjeldahl nitrogen (TKN), ammonia-nitrogen (NH₃-N), and nitrite+nitrate-nitrogen (NO₃-N). Monthly composite samples were analyzed for copper (Cu), lead (Pb) and zinc (Zn). Redox potential was measured using platinum electrodes. Poor treatment of NO₃-N, TKN, organic-N, and TP in roof runoff was observed. Many Cu, Pb and Zn samples were below detection limit, so statistical analysis was not performed on these pollutants. The only pollutants significantly lower in the effluent than in the influent were NH₃-N in both gardens and total-N in one garden. The design used for these rain gardens worked well for overall flow retention, but had little impact pollutant concentrations in percolate. These results suggest that if an underdrain is not connected to the stormwater system, high flow and pollutant retention could be achieved with the 2.54 cm design method.     

Efficiency of a grass buffer strip for limiting diuron losses from an uphill vineyard towards surface and subsurface waters

Grass buffer strips limit the transfer of pesticides from cultivated fields to rivers. These solutions are generally efficient at reducing polluted surface flows, mainly by infiltration of the soil, raising the question of the fate of the infiltrated pollutants. An environmental evaluation was conducted on the efficiency of a grass strip receiving diuron-contaminated water from an uphill vineyard in France. During two runoff events, the following measurements were taken: surface inflow and outflow with Venturi flumes, vertical percolated flow below the root layer (0-50 cm), and variations in water and solute content of the root layer. One runoff event occurred under natural rainfall conditions, while the other runoff event was artificially provoked with water doped by diuron and bromide. For the natural runoff event, representative of medium intensity events, 94% of the diuron was retained in the root layer, whereas 2% left the grass strip by surface runoff and 4% left the grass strip in the water percolating under the root zone. For the artificial event, representative of intense runoff events, more than half of the incoming diuron was retained by the grass strip, whereas 24% and 18% of it were transferred by surface runoff and percolation, respectively. These results showed that the capacity of the root layer to retain diuron was highly significant despite a large percolation flux. However, for large runoff events, surface and subsurface losses can still be considerable, up to 40% of the pesticide load entering the strip.     

Field Performance of Bioretention Systems for Runoff Quantity Regulation and Pollutant Removal

Bioretention systems are of immense importance as they serve as small “sponges” for cities, cutting stormwater runoff, removing pollution, and using precipitation resources. However, performance data for these facilities are generally lacking, particularly at the field scale. This study investigated the runoff quantity regulation and pollutant removal performance of bioswale and rain garden systems from 2014 to 2017. A performance assessment of these facilities demonstrated that anti-seepage rain garden, bioswale-A, and bioswale-B effectively retained inflow volumes by the filter media, reducing runoff volumes by 54.08, 98.25, and 77.65%, respectively, on average, with only two events of overflowing. According to the water quality data in 24 rainfall events, the main pollutant indexes for the new city include total nitrogen and chemical oxygen demand, and the median values for their respective effluent event median concentrations were 1.29 and 40.13 mg/L for anti-seepage rain garden and 1.68 and 74.00 mg/L for bioswale-B systems. The mean values of pollutant removal of the three bioretention systems, except for infiltration rain garden, were 39.8–59.73% (median?=?54.32%), 61.06–72.66% (median?=?73.47%), and 76.67%–88.16% (median?=?80.64%). Meanwhile, outflow volume of water was found to be most influenced by inflow volumes for the bioswales and anti-seepage rain garden. Mass removals were higher than concentrations owing to water volume attenuation. Based on the data of monitored pollution loads, this study estimated the annual pollutant load removal as 75.45 and 90.7% for anti-seepage rain garden and bioswale-B according to the percent of monitoring rainfall depth in total annual precipitation. This study also established the target pollutant service life model on the basis of accumulated annual load and media adsorption capacity. The results of this study will contribute to a greater understanding of the treatment performance of bioretention systems, assisting in the design, operation, and maintenance of them.     

High Temporal Resolution Monitoring of Multiple Pollutant Responses in Drainage from an Intensively Managed Grassland Catchment Caused by a Summer Storm

This work presents data on a suite of diffuse pollutants, monitored in a stream draining an intensively managed grassland on a 30 min time step during a period of intense rainfall to better understand their sources and pathways. Nitrite (92 μg l^?1), particulate phosphorus (107 μg l^?1) and soluble phosphorus (74 μg l^?1) exceeded environmental limits during base flow. Concentrations of nitrate and nitrite were decreased during the storm event, whereas all other pollutants generally increased and exceeded environmental limits where specified, especially when associated with a small subsidiary hydrograph on the rising limb of the main hydrograph. Total pollutants loads, when using a 60 min sampling frequency, would have led to significant over and under-estimations depending on which 60 min sample set was used. In the worst case, loads of ammonium could have been under-estimated by 35% or over estimated by 25% with errors being associated with loads on the rising limb of the hydrograph and more specifically a small subsidiary hydrograph. This subsidiary hydrograph may have occurred as a result of runoff from the farm hard standings within the catchment. Incidental transfer of pollutants associate with this runoff have masked the overall grassland pollutant response. To better understand these different source areas and pollutant dynamics, there is a need for novel tracing techniques to elucidate their relative contribution and pathways.     

珠海城区暴雨径流污染负荷估算及其评价

基于对广东珠海城区暴雨径流污染的监测,引用SCS模型对城区暴雨径流污染负荷进行估算并分析评价。结果表明,珠海城区暴雨产流年平均1529.2mm,其中以交通主干道和商业区径流量最大。暴雨径流污染物浓度水平较高,T—N,T—P,COD_(Cr)和BOD_5负荷总量分别为765.27,74.06,11 958.94和1104.71t,其中COD_(Cr)负荷为工业点源污染的72.32％,占珠海非点源污染总负荷的24.69％。暴雨径流在雨后短时间内会使受纳水体的水质迅速恶化。因此,珠海城区暴雨径流对水环境的威胁较大。     

缓冲带截除农业面源强污染的效果

为了摸清草皮缓冲带对农田径流冲击负荷的耐受能力,通过工程尺度的现场试验,研究了高浓度污染负荷冲击对百慕大草皮缓冲带截除农业面源污染物能力的影响。结果表明:在高浓度污染负荷下,百慕大缓冲带能有效地截留农田径流中的悬浮固体(suspended solids,SS),SS浓度变化趋势与一般浓度污染负荷基本一致,前端下降速度较快,后端逐渐趋缓,2种污染负荷条件下末端出水SS质量浓度均在90mg/L以下,高浓度污染负荷冲击对农田径流SS的去除基本没有影响。缓冲带对高浓度氮磷污染负荷具有一定的净化效果,径流途径总氮(total nitrogen,TN)、氨态氮(ammonia nitrogen,NH4+-N)、总磷(total phosphorus,TP)的末端去除率为23%、16%和26%,分别为一般浓度污染负荷下末端去除率的59%、55%和70%;百慕大草皮缓冲带对渗流途径TN、TP具有一定的净化效果,2种浓度污染负荷下渗流水TN、TP浓度变化趋势基本一致,两者无显著差异(p>0.05),但TP去除速率较TN慢。该文为滨岸缓冲带的优化设计、维护管理及推广应用提供了依据。     

小流域非点源污染负荷流失特征监测研究——以广东省珠海正坑小流域为例

以GIS为技术支持,完成了以元胞自动机(CA)为模型的基于土地利用变化的土壤侵蚀空间演化分析。通过对土地利用规划前和规划后不同利用模式制约下侵蚀发展状况的模拟,预测了不同利用模式中各地块单元土壤侵蚀的发展方向,为评价土地利用合理程度提供了理论依据。     

The Influence of Sediment Sources and Hydrologic Events on the Nutrient and Metal Content of Fine-Grained Sediments (Attert River Basin, Luxembourg)

Nutrient (C, N and P) and metal (Cr, Cu, Ni, Pb and Zn) content and dynamics of suspended and channel bed sediments were analysed within the rural Attert River basin (Luxembourg). This basin is representative of the main physiographic characteristics of the country, where there is currently little information available on the composition and dynamics of fluvial sediment. Stream bed fine-grained sediment samples (n?=?139) collected during low flow conditions and time-integrated suspended sediment samples (n?=?183) collected during storm runoff events (October 2005 to April 2008) in seven nested basins ranging from 0.45 to 247?km² were analysed. Nutrient and metal spatial patterns, temporal trends and the relationship between their content and storm runoff characteristics (e.g. maximum discharge and sediment concentration) were assessed. Results showed a high spatial and temporal variability, mainly associated with basin characteristics and local inputs. Higher values of total C were measured in the highly forested basins located in the northern part of the Attert River basin, whereas the highest values of total P were mainly associated with material coming from grassland and with the inflow of wastewater treatment plants (i.e. higher values of total P were measured in the southern part of the basin). The abundance of metals, not only in suspended but also in channel bed sediments, was generally as follows: Zn > Cr > Ni > Pb > Cu. Both nutrient and metal concentrations were at a maximum at the beginning of the wet season, after having been accumulated during the summer. These values tended to decrease during autumn and winter due to sediment mobilisation, and a higher flow capacity to transport coarser particle fractions from the sources. In general, concentrations of nutrients and metals on suspended sediment were negatively correlated with antecedent precipitation, total precipitation, total specific discharge and maximum discharge, which has been previously associated to a ??dilution?? effect during storm runoff events. Results show that both sediment sources and hydrologic events play an important role on the spatial and temporal variability of sediment-associated nutrient and metal contents.     

Effects of varying air trajectories on spatial and temporal precipitation chemistry patterns

This study was designed to determine if judicious use of synoptic data and an operational trajectory model could identify probable source regions of anthropogenic pollutants in northeastern United States precipitation and thus relate receptor measurements to emissions data without consideration of the complex intervening meteorological and chemical processes. The storm event of April 8 to 10, 1979, was selected for intensive study. Precipitation chemistry data were obtained from event samples at six MAP3S sampling sites and from hourly samples at Brookhaven National Laboratory. Concentrations of hydrogen, sulfate, nitrate and ammonium ions were used as receptor data. Some emissions data for SO_x and NO_x were obtained from the MAP3S emissions inventory. Surface and upper air meteorological data were analyzed. Backward trajectories ending at each of the sampling sites during the precipitation period were computed with the Heffter Interactive-Terminal Transport Model using selected transport layers. Results show that concentrations of pollutant species in event precipitation samples were much higher at stations at end points of trajectories passing through the Ohio River valley than at stations with other trajectories. Likewise, concentrations at Brookhaven were much higher during the end period of a trajectory through the same region than with more northerly and more southerly tracks. The model produced back trajectories consistent with synoptic flows. Concentrations of air pollutants in precipitation were roughly proportional to the number of major pollutant sources along the trajectory. These results suggest that a larger number of studies might identify more restricted source areas or even establish a quantitative relationship between source emissions along a trajectory and concentrations in precipitation at receptor sites.     

Modeling enrichment of soluble pollutants in snow covers

Snowmelt runoff presents an enhanced threat of environmental damage. Soluble impurities which have accumulated in the snow during winter months are transported to the lower portion of the snow cover early in the melting season due to melt-freeze cycles. These contaminants are removed rapidly at very high concentrations within the first fractions of snowmelt runoff causing sudden bursts of enriched pollutants. This paper reports a physically-based mathematical model to simulate the enrichment process in a snow cover. The model is based on the liquid water flow, heat transport, and pollutant transport equations. These nonlinear partial differential equations are solved simultaneously using a six-point implicit finite difference scheme.     

人工生物土壤结皮特性及其集雨潜力的研究

为探讨在太行山半干旱区利用人工土壤生物结皮进行集雨的潜力和可行性,以自然生长的生物土壤结皮为种子,通过培育建立人工土壤生物结皮和生物结皮集雨,对人工土壤生物结皮建成后土壤物理性状、渗透率的变化及人工生物结皮集雨面的集流效率进行了研究。结果表明,人工土壤生物结皮与自然生长的生物结皮一样,可显著改变土壤的颗粒组成,使0~1 cm表层土壤的小颗粒物质含量增加、大颗粒物质减少,但对0~5 cm的土壤容重影响不显著。对土壤入渗速率的测定结果表明,人工培育的土壤生物结皮具有降低入渗速率的作用,与自然土壤相比,生物结皮的土壤初始入渗速率和稳定入渗速率分别下降59.1%和44.4%,达到稳定入渗的加水量也减少50.0%。人工营建的生物结皮集雨面的平均集雨效率达60.86%,与自然土面相比,提高23.0%。对集雨面效益分析表明,生物结皮集雨面不仅具有较高的集雨效果,且使用年限较长,并具有明显的减少地表径流沉积物含量,提高土壤抗蚀性的作用。综上结果可以看出,人工土壤生物结皮是一种极具潜力的绿色环保型集雨材料。