重庆三峡库区加工甜橙园土壤养分状况分析

为了解重庆三峡库区加工甜橙园土壤养分含量状况，在重庆7县（区）随机选取132个果园，分析背景土壤和农化土壤pH值、有机质和有效态矿质养分含量。结果显示，分别有56.8%和60.8%的果园背景土壤和农化土壤pH值适宜甜橙生长，农化土壤酸性土比例增加；背景土壤和农化土壤有机质含量不足（<15 mg?Kg-1）的比例分别为77.3%和85.3%，碱解氮处于适宜范围的比例分别为56.8%和61.5%，有效钙过剩（高量和过量）的比例分别为79.6%和76.7%；背景土壤有效磷、钾不足(缺乏和低量)的比例分别为95.4%和72.8%，有效锌、硼不足的比例分别为54.5%和70.5%；农化土壤有效磷、钾不足的比例分别为60.8%和57.6%，有效锌、硼不足比例分别为65.9%和90.7%。背景土壤和农化土壤有效镁、铁、锰及铜不足和过量并存。总体而言，土壤养分状况中等偏差；与背景土壤相比，农化土壤pH值、有机质、有效钙、锌和硼含量下降且缺锌严重，其它养分含量则有所上升。     

超声波辅助溶剂法提取金线莲总黄酮工艺优化

旨在研究金线莲总黄酮的最佳提取工艺条件。采用超声波辅助溶剂法,在单因素实验的基础上,采用响应面法优化了金线莲总黄酮的提取工艺。结果表明:当金线莲颗粒度为100目、乙醇体积分数为40%、料液比为1:40(mg:m L)、超声波功率为250 W、超声波时间为30 min时,所得金线莲总黄酮提取率为2.13%。超声波辅助溶剂法强化了金线莲总黄酮的提取效果。     

Practical use of response surface methodology for optimization of veterinary antibiotic removal using UV/H2O2 process

Three of the most commonly used veterinary antibiotics—enrofloxacin (ENR), sulfamethoxazole (SMX), and oxytetracycline (OTC)—were chosen as representative antibiotics for UV/H₂O₂ treatments. The objective was to determine the optimization of UV/H₂O₂ to remove antibiotics from aquaculture discharge water using response surface methodology. The degradation of the antibiotics was investigated under varying UV/H₂O₂ conditions in environments with different levels of pH, water matrices, humic acid, and constituent ions. The degradation results demonstrated that increasing the H₂O₂ dosage facilitated ENR degradation at a neutral pH while facilitating degradation of SMX and OTC at a slightly acidic pH. The optimum removal conditions for ENR, which was used in all influential effect experiments and the contact tank experiments, was obtained at 10 mM H₂O₂, a pretreated COD of 87.51 mg L⁻¹, and an initial pH of 6.15. Among the tested anions, only the presence of Cl^- showed slight positive effects on ENR degradation, due to the generation of secondary active radicals. During the reaction, the hydroxyl radical (OH) was present at a higher pH while singlet oxygen (¹O₂) was slightly present at a lower pH. The experimental results from H₂O₂ sequential addition indicated that freshly added H₂O₂ could quench the recently generated OH and therefore a high H₂O₂ concentration with frequent adding was not necessary. Our contact system reduced the ENR concentration in both the effluent reservoir and in the UV irradiation zone. The overall results supported the use of the UV/H₂O₂ system to treat remnant antibiotics in the discharge water.     

地稔凝集素的提取及凝血活性的研究

为研究和利用地稔的促凝血活性物质,以地稔为试材,提取地稔凝集素,研究pH、温度和糖等理化因素对凝血活性的影响。结果表明:经硫酸铵沉淀及透析提取的地稔凝集素具有红细胞凝集活性;碱性条件下,抑制作用明显,而酸性条件有较强促进作用;温度对凝集素凝血活性影响很小;半乳糖有明显促进作用。     

油雾润滑技术在流程企业的应用

油雾润滑作为一种新型的机泵润滑方式，具有改善润滑效果、降低轴承故障率、减少润滑油消耗量和降低运行成本等优点，且已在国内外石油化工行业得到广泛应用。本文对油雾润滑系统的工作原理、油雾润滑与传统润滑的性能比较、油雾润滑系统的配置及油雾润滑技术的发展应用情况进行详细综述，并指出油雾润滑技术对装置规模大、集中程度高、人员配置少的生产装置具有很好的应用价值。     

鄂尔多斯市工业化进程中产业结构的演进分析

鄂尔多斯市是我国重要的能源重化工基地,因其工业经济呈现出超常规的发展态势,被称为鄂尔多斯现象。文中以鄂尔多斯市的工业经济和三次产业为研究对象,利用1949～2009年间的产值与就业结构统计数据,对其工业化进程与产业结构的变动轨迹进行了分析。结果表明:60a来,鄂尔多斯市工业化发展阶段性特征明显,目前其工业经济已进入重工业化的中后期阶段。三次产业中,第一产业的产值与就业比重快速下降,二、三产业比重持续上升,并行发展;就业结构虽逐年优化,但仍相对滞后于产业结构与工业化进程,产业结构与就业结构的协调度较低。近年来工业结构的重化趋势凸显,工业主导型的产业结构与主导产业群已经形成。     

Importance of Noncrystalline Hydroxide Phases in Sequential Extractions to Fractionate Antimony in Acid Soils

Abstract

Sequential extraction techniques have been used to make inferences about speciation of phosphorus (P) and to a lesser extent arsenic (As) in soils. However, sequential extraction studies on the less‐abundant group V element, antimony (Sb), are limited. In this work, a widely used P sequential extraction scheme was modified and used to extract P, As, and Sb from two acidic soils from the Macleay River floodplain, NSW, that were enriched with Sb (26.9 and 23.0 mg kg^?1). An ammonium oxalate–oxalic acid step was included in the extraction sequence to dissolve the noncrystalline iron (Fe) and aluminium (Al) hydroxide phase. It extracted 30 to 47% of Sb, indicating the importance of this fraction, which may be mobilized in the floodplain by acid sulfate soil processes and periodic waterlogging. The original method overestimated P, As, and Sb in the residual fraction (30–71%). Relative efficiency values of extracts for P, As, and Sb were compared, and inferences about phase distributions were made. The results suggest some potential in using extractions to assess bioavailability of Sb in soil.     

农机检测实验室样品管理研究

样品管理是实验室工作中的重要环节，规范化、制度化的样品管理工作可保障实验室管理体系的有效运行。阐述实验室样品管理的总体要求与原则，从样品接收、标识、确认、流转、贮存、处理等环节人手，介绍样品全过程跟踪管理方法，为做好实验室样品管理工作提供参考。     

生物酶法提取中草药活性成分研究进展

对酶提方法的原理、酶类选择依据、酶提工艺,以及酶提法应用现状进行了综述,旨在为同类研究提供技术参考。中草药具有广泛的应用前景和开发潜力,为提高中药疗效,方便临床用药,生产中常需要对中草药进行提取,然而传统的提取方法较为繁杂。随着科技进步,一些现代中药提取方法不断涌现。酶提方法是一种应用酶工程技术提取中药的现代中药提取方法,该方法具有高效、无毒、反应条件温和等优点,是一种发展潜力较大的中药提取方法。     

分散固相萃取结合UPLC-Orbitrap MS联用测定鸡蛋中五氯苯酚残留量

建立了超高效液相色谱-静电轨道阱质谱联用测定禽蛋中五氯苯酚残留量的分析方法。取均质后的禽蛋样品经乙腈溶液提取,加入无水硫酸镁和氯化钠进行脱水和盐析,高速离心分层后,取适量乙腈层溶液经0.1%(V∶V)甲酸稀释后,用酸性氧化铝粉末进行样品净化并以10000 r/min离心取上清液,过0.22μm滤膜后上机测定。使用反相色谱柱进行分离,流动相为乙腈:0.1%甲酸=75∶25,采用等度程序进行洗脱,静电轨道阱质谱进行定性定量分析。结果表明,五氯苯酚在0.5~100μg/kg范围内线性关系良好(r>0.995),方法的最低检出限为0.2μg/kg,最低定量限为0.5μg/kg,添加回收率在74.43%~96.85%之间,批内批间变异系数CV%<10%。该方法具有较好的准确度与精密度,适用于禽蛋中五氯苯酚残留量的测定。