[Fe(CH3bipy)(NCS)2]2bpym及其相关配合物光电性质的理论研究

以密度泛函和含时密度泛函为理论基础,通过Gaussion03程序,应用密度泛函中的B3LYP方法,在6-31G(d)基组下,对[Fe(CH3bipy)(NCS)2]2bpym及其相关配合物的电子结构、光谱性质进行了系统的量子化学理论研究,比较了配合物的几何构型、红外光谱和前线分子轨道。该研究可以对有关铁为中心金属离子的具有较好发光性质的配合物的开发与利用有一定的促进作用。     

浅谈混凝土拱桥扣锚索张拉技术

本文详细介绍了主拱拱肋斜拉扣挂施工中扣锚索的自平衡张拉、塔偏实时监测新工艺。在建造过程中通过采用新工艺进行智能化张拉扣锚索使得扣锚索索力以及塔架偏位在工程精度之内,扣锚索自平衡张拉、塔偏实时监测新工艺的成功实施,有效控制了扣塔在悬臂施工过程中的安全风险,实现了特大桥梁施工过程监测智能化,该工艺值得大力推广。     

水泵叶片空间曲面计算和数控加工

论述了水泵叶片空间曲线的计算和用数控铣床加工的基本方法,并介绍在江苏省江都第一抽水站更新改造工程中成功应用的实例,现场实测结果表明数控加工的叶片能够保证水泵设计性能。     

铁路桥梁混凝土表面气泡和砂纹的防治措施

通过对铁路桥梁混凝土表面气泡和砂纹形成原因的分析,从桥梁预制工艺5个方面进行试验研究,并提出了相应的防治技术措施。     

简支转连续梁桥扁锚局压应力分析

从工程实际出发,针对简支转连续梁桥扁锚局压问题的特殊性,从锚下设置钢筋网的深度和齿板深度角度考虑,分4种不同情况分别对其进行了空间有限元分析。研究各种情况下扁锚锚下应力分布状态及其造成的开裂行为,找出开裂机理,解释开裂过程。     

Production of a desirable Brassica oleracea CMS line using an alloplasmic B. rapa CMS line carrying Diplotaxis erucoides cytoplasm as a bridge plant

In Brassica oleracea, production of F₁ hybrid seeds mainly makes use of the improved Ogura cytoplasmic male sterile (CMS) line. However, reliance on one particular line is a risk, and it would be advantageous to develop other CMS lines. In this study, we transferred Diplotaxis erucoides cytoplasm to B. oleracea cultivars using an alloplasmic B. rapaCMS line as a bridge plant to avoid incompatibility between donor and recipient plants. The new B. oleraceaCMS lines, which were derived by four generations of backcrossing, had small rudimentary anthers with no pollen grain and showed complete male sterility. There was no functional defect in other floral organs, and the ability to receive normal pollen did not appear to be impaired. Moreover, the B. oleraceaCMS lines carrying D. erucoides cytoplasm had larger leaf areas and a normal plastochron. As a consequence, the B. oleraceaCMS lines carrying D. erucoides cytoplasm have the potential to be valuable alternatives for use in commercial B. oleracea hybrid seed production.     

浇筑式钢桥面铺装层推挤变形病害机理分析

以贵州省北盘江大桥钢桥面铺装层推挤变形病害为研究背景,采用凝胶渗透色谱法(GPC)和傅里叶变换红外光谱法(FTIR),从沥青分子尺度分析钢桥面铺装产生推挤变形的原因。分析结果表明:沥青老化并不是造成钢桥面铺装层推挤变形的主要原因;从现场调查可知,第2层粘层粘结能力的降低是造成钢桥面铺装层推挤变形病害的次要原因;通过级配分析发现,造成钢桥面铺装层推挤变形的主要原因是浇筑式沥青混合料(GA)级配偏细以及GA中集料颗粒的棱角性较差所致。     

地震下高墩刚构桥桥台背土相互作用分析方法对比

针对重力式U型桥台背土相互作用,结合现行抗震规范,提出了4种分析模型及其力学本构关系和计算式。采用非线性时程法对比研究了某在建高墩双薄壁连续刚构桥的桥台背土相互作用效应。结果表明：只有弹簧模型可以求得与精细模型基本一致的高阶弹性模态;在纵桥向,滚轴模型和支座模型的结果都比精细模型小,弹簧模型相对精细模型的计算误差最小,关键内力误差不超过20%;在横桥向,支座模型的内力最接近精细模型,而弹簧模型和滚轴模型的结果都偏保守;桥台刚度对关键地震内力的影响幅度低于10%,而桥台有效参与质量的影响幅度也低于15%。综合考虑分析精度和计算成本,弹簧模型在抗震设计中更值得推荐。     

A single screw technique compared to a two screw and wire technique as a temporary transphyseal bridge for correction of fetlock varus deformities

A single screw technique is described as a temporary transphyseal bridge for the treatment of fetlock varus angular limb deformity in foals. This has been compared to tension band wiring with regards to rate of correction, cosmetic result and incidence of complications. The single screw was found to be an effective technique resulting in more rapid improvement of deviations in foals aged up to 5 months. Complications were minimal following both techniques and the final cosmetic result was better following single screw surgery.     

Routing protocol of the wireless sensor networks for bridge health monitoring

By analyzing the reason that why the existing routing protocols cannot be applied to the wireless sensor networks for bridge health monitoring, a new routing protocol is proposed. Since the locations of the collecting modules are fixed, the proposed protocol exchanges the routing information between the neighbor nodes by adjusting the exchange cycle according to reliability of the modules. For the low routing security requirement, while to increase the routing efficient, the middle nodes replying the routing requirements with variable thresholds is introduced. In order to make full use of information in route discovering procedure, the backup routes mechanism is adopted. The proposed protocol can efficiently forward data and is suitable for the bridge health monitoring.