大茴香油聚合树脂的合成及应用研究

以乙酸乙酯为溶剂 ,无水AlCl3作催化剂 ,由大茴香油在室温下反应 4h ,合成了聚合物大茴香油聚合树脂 (简称PAOR) ,凝固点降低法测定了树脂的分子质量 ,对树脂进行IR、UV测试分析 ,并考察了树脂对桔皮色素的柱层析吸附分离性能。结果表明 ,合成树脂的分子质量约 1.0 2× 10 3,PAOR在 965cm- 1吸收峰减弱 ,在 70 0～ 80 0cm- 1之间出现 3个新峰 ;PAOR紫外最大吸收峰蓝移 11nm ,表明大茴香油中的双键参与了聚合反应 ,产物中存在芳环三取代物。讨论了反应机理 ,PAOR对桔皮色素有良好的吸附作用 ,树脂的重复使用性较好。     

竹筋陈材与新伐材主要物理力学性质的比较研究

以３５年前的毛竹为研究对象，并以经气干的同龄、同径的新伐毛竹材作为对照，根据国际规定及相关试验方法，对两类试材在完全相同的实验条件下进行物理性质、力学性能、化学成份等的测定和对比分析，结果表明，影响竹材使用寿命的主要因素是水分的侵蚀和虫害，载荷作用的时间长短及性质对它的影响轻微，因此，在加工、保管和使用竹材的过程中要十分重视防水、防潮和防虫，保持竹材尺寸稳定，达到提高耐久性的目的。     

彩叶植物及园林应用

简要介绍彩色植物的分类,呈色的影响因素,园林配置方式和研究、应用的发展方向。     

黄山松人工林球果生物量的测定

采取平均木法实测不同立地条件的 10年生黄山松球果生物量 ,阐明黄山松球果生物量与立地条件以及测树因子之间的相互关系。 10年生黄山松山脊球果生物量最高平均每株 0 5 8kg ,而山坡最低为 0 4kg。应用树高和胸径分别推导出预测黄山松球果生物量的回归方程。     

天然次生白桦林凋落物的分解及其生态效应

1988～1990年间以长白山支脉张广才岭帽儿山老爷岭生态站天然次生白桦林为研究对象,对林分凋落物的积累,组成与分解进行了定位观察研究。结果表明,38年生白桦林凋落物的现存量为13.644t/ha,其中叶为10.49t/ha,枝为2.58t/ha,树皮、种实、动物尸体及粪便等仅为0.57t/ha,年凋落盈为3.38t/ha,年分解量为0.633t/ha,年分解率为18.7％。     

白蜡虫优良种虫及种群性比组成的研究

白蜡虫(Ericerus pela Chavannes)是我国特产资源昆虫,国内产区很多。实验表明各产区繁育白蜡虫的产量与质量差异显著,其中以金沙江下游云、贵、川三省相接壤的白蜡虫产区,繁育的白蜡虫产卵数量多、雄卵比率高、产蜡时间长、产蜡量多,同时蜡虫的产量高,是我国白蜡虫的优良种虫。     

The effects of replacement of whole‐plant corn with oat and common vetch on the fermentation quality,chemical composition and aerobic stability of total mixed ration silage in Tibet

The objective of this experiment was to evaluate the effects of replacement of whole‐plant corn with oat and common vetch on the fermentation quality, chemical composition and aerobic stability of total mixed ration (TMR) silage in Tibet. Four TMR that varied in the forage sources on dry matter basis were used: (i) 52% whole‐plant corn (Control); (ii) 43% oat + 12% common vetch (OC3.6); (iii) 38% oat + 18% common vetch (OC2.2); and (iv) 33% oat + 23% common vetch (OC1.5). Silos were opened on day 45 and then subjected to an aerobic stability test for 12 days. The results showed that all silages were well preserved with low pH and NH₃‐N, and high lactic acid and V‐scores. With the increasing proportion of common vetch, crude protein, ether extract increased (P < 0.05), and neutral detergent fiber and acid detergent fiber decreased (P < 0.05). Under aerobic conditions, treated silages were more stable than the control silage as indicated by lower (P < 0.05) pH and yeast population. It was concluded that replacement of whole‐plant corn with oat and common vetch had no unfavorable effects on the fermentation quality and improved crude protein content and aerobic stability of TMR silage. OC2.2 silage was the best among three treated TMR silages.     

Synthesis, insecticidal activity, and QSAR of novel nitromethylene neonicotinoids with tetrahydropyridine fixed cis configuration and exo-ring ether modification

To keep the nitro group in the cis position, a series of nitromethylene neonicotinoids containing a tetrahydropyridine ring with exo-ring ether modifications were designed and synthesized. All of the compounds were characterized and confirmed by 1H NMR, high-resolution mass spectroscopy, elemental analysis, and IR. The bioassay tests showed that some of them exhibited good insecticidal activities against pea aphids. On the basis of 10 nitromethylene derivatives, the quantitative structure-bioactivity relationship (QSAR) was analyzed and established. The results suggested that AlogP98 and Dipole_Mopac might be the important parameters related with biological activities.     

Development of an enzyme-linked immunosorbent assay for the detection of pentachloronitrobenzene residues in environmental samples

A competitive enzyme-linked immunosorbent assay (ELISA) for pentachloronitrobenzene (PCNB), a fungicide and chemical intermediate, was developed using a polyclonal antiserum produced against a hapten-protein conjugate of pentachlorophenoxypropionic acid-bovine serum albumin (BSA). An indirect competitive ELISA of PCNB showed an IC50 of 37 ng/mL and a limit of detection (LOD) of 7 ng/mL. The ELISA can tolerate up to 10% (v/v) methanol, 5% (v/v) acetonitrile, or 5% (v/v) acetone without significant fluctuation of Amax and IC50. The assay sensitivity showed little change in a range of pH from 6 to 8 and concentrations of 0.05-0.2 M NaCl in the assay buffer. Very low cross-reactivities were observed for some structurally related compounds except for hexachlorobenzene (12%). The average recoveries of PCNB from fortified well water, river water, and soil samples were in ranges of 88-94, 80-91, and 70-81%, respectively. The correlations between the gas chromatographic and ELISA results were excellent (r 2 >or= 0.97, slopes from 0.86 to 1.10) for those fortified samples. The ELISA is a good alternative tool for monitoring PCNB residues in environmental samples.