淮河上游全新世黄土-古土壤序列元素地球化学特性研究

在野外考察研究的基础上,对河南禹州全新世风成黄土-古土壤剖面系统采样,利用X-荧光光谱仪测定了常量元素和微量元素的含量及其变化,并与磁化率曲线、粒度变化曲线对比分析发现:常量元素氧化物比值钾钠比、残积系数和以Rb为代表的微量元素含量等随剖面层次呈规律性变化,即在古土壤层(S0)中含量最高,表土层(MS)中次之,在黄土层(L1、Lt、L0)中最低。硅铝率和Sr的含量表现出相反的变化规律。表明在全新世古土壤层和表土层形成时期,气候温暖湿润,成壤作用和次生粘化作用较强;在黄土堆积时期,气候比较干旱,沙尘暴频繁,成壤作用微弱。这些化学参数与磁化率曲线可以进行对比,表明成土过程中元素的迁移变化受全新世以来气候变化和成壤环境变化的控制。与黄土高原腹地的洛川剖面相比,淮河上游禹州剖面中绝大多数常量元素的含量较高,而绝大多数微量元素的含量偏低,磁化率也显著偏低,绝对值差别很大,粒度组成当中细沙成分含量很高,这说明淮河上游黄土物质来源与黄土高原地区明显不同。联系全新世时期黄河频繁泛滥、改道、沉积与黄淮平原盛行东北风形成流沙地的事实,认为淮河上游的黄土是黄河泛滥沉积物质经过风沙活动改造,由东北风力系统搬运而来的近源粉尘堆积,再经过就地风化或者成土改造而形成。     

中国西南地区几种土壤的元素地球化学特征

研究西南地区变性土、铁铝土及水稻土７个剖面的地球化学和矿物学特征的结果表明：铁铝土在元素地球化学分类上可划为铝质富铝化类型，变性土也表现了一定的富铝化趋势，而水稻土最明显的特征是Ｆｅ、Ｍｎ及Ｃａ均相对富集。变性土粘土矿物以蒙脱石为主，铁铝土则以高岭石占优势，水稻土矿物组成取决于母质来源。根据主组元分析结果，可以探讨成土过程中不同剖面的元素分异和相关性，以及元素地球化学的演变趋势。     

黑龙江五常水稻产区土壤地球化学特征研究

对黑龙江五常地区的土壤类型与土壤地球化学特征进行分析，研究表明，五常水稻产区特定的土壤条件和土壤地球化学特征是该区水稻优质高产的主要原因。     

板栗品质与土壤地球化学关系研究进展

板栗具有较高的经济价值,但其地域性较强,品质差异较大。综述了近年来板栗营养品质的评价指标体系的研究进展,板栗品质与土壤性质的关系以及板栗品质和土壤地球化学元素间关系的研究进展,并对板栗产量、质量和施肥技术间的关系进行了分析和论述,最后指出了存在的问题,并对提高板栗营养品质提出了几点建议。     

华南海岛土壤形成的地球化学

The soils in South China sea Islands(SCSI)were divided into three types,nmaely,phospho-calc soils,skeletisols and coastic solonchake,which were derived from bio-clastic and strongly calcareous sediments.In comparison with their parent materials,the phospho-Calc soils have higher contents of P,Zn Cu,Ba,and Cd,which tend to increase gradually with time,and lower contents of Mg,Ca,Sr,B,V,Pb,and Mo,which tend to decrease by degrees with time,The above-mentioned constituents in skeletisols and coastic solonchaks are similar to those in their parent materials except for P and Na,The factors affecting element distribution are mainly special bioclimate and parent material,meanwhile,resulting in the remakable influence on element distribution through soil-forming time.     

基于光释光测年法的三江源地区高山草甸土形成年代与成因研究

[目的]分析三江源区高山草甸土壤的年代及发生发育过程,为维系该区土壤安全和生态安全提供指导.[方法]采用粗颗粒石英与钾长石光释光(OSL)测年法,对三江源区4个高山草甸土剖面夏琼(XQ)、歇武(XW)、桐勒栋(TLD)、斗地村(DDC)土壤的形成发育时间进行研究,结合土壤粒度、元素地球化学特征分析该区土壤形成过程.[结...     

Geochronology,geochemistry, and Sr-Nd isotopes of Early Carboniferous magmatism in southern West Junggar,northwestern China: Implications for Junggar oceanic plate subduction

West Junggar is a key area for understanding intra-oceanic plate subduction and the final closure of the Junggar Ocean. Knowledge of the Carboniferous tectonic evolution of the Junggar Ocean region is required for understanding the tectonic framework and accretionary processes in West Junggar, Central Asian Orogenic Belt. A series of Early Carboniferous volcanic and intrusive rocks, namely, basaltic andesite, andesite, dacite, and diorite, occur in the Mayile area of southern West Junggar, northwestern China. Our new LA-ICPMS zircon U-Pb geochronological data reveal that diorite intruded at 334 (±1) Ma, and that basaltic andesite was erupted at 334 (±4) Ma. These intrusive and volcanic rocks are calc-alkaline, display moderate MgO (1.62%-4.18%) contents and Mg# values (40-59), and low Cr (14.5×10^-6-47.2×10^-6) and Ni (7.5×10^-6-34.6×10^-6) contents, and are characterized by enrichment in light rare-earth elements and large-ion lithophile elements and depletion in heavy rare-earth elements and high-field-strength elements, meaning that they belong to typical subduction-zone island-arc magma. The samples show low initial ⁸⁷Sr/⁸⁶Sr ratios (range of 0.703649-0.705008), positive ε_Nd(t) values (range of 4.8-6.2 and mean of 5.4), and young T_DM Nd model ages ranging from 1016 to 616 Ma, indicating a magmatic origin from depleted mantle involving partial melting of 10%-25% garnet and spinel lherzolite. Combining our results with those of previous studies, we suggest that these rocks were formed as a result of northwestward subduction of the Junggar oceanic plate, which caused partial melting of sub-arc mantle. We conclude that intra-oceanic arc magmatism was extensive in West Junggar during the Early Carboniferous.     

辽东山地冰缘地貌上覆土壤粒度及元素地球化学

对辽东山地典型冰缘地貌上覆土壤的粒度、常微量化学元素进行测试分析,结果表明:土壤颗粒组成包括黏粒20.79%、粉粒69.54%和砂粒9.67%,平均粒径整体偏细,约为6.45Ф,不同土壤类型、地貌类型及坡向的粒度分布存在一定差异。土壤元素化学组成以SiO₂（45.60%）,Al₂ O₃（12.90%）,Fe₂O₃（3.90%）,K₂O （2.17%）为主,最大比例可达73.36%。元素Ca,Na,P,Sr显著淋溶,而Mn,Ti,Cu,Zn则相对富集,其他元素迁移不甚明显。少数元素还表现出与粒度分布存在显著关联,其中K,Na,Sr,Ba多存在于砂质土壤中,而元素Ti则容易在粒度更细致的黏土颗粒中留存。化学风化指数CIA均值约为65.50,Rb/Sr约为0.70,反映风化程度较低,且长期经历干冷气候,A—CN—K三角模型表明,研究区土壤风化以脱钙钠、富铝为主,风化水平尚处于低等风化阶段中后期。     

Differences in chemical composition of soil organic matter in natural ecosystems from different climatic regions - A pyrolysis-GC/MS study

Soil organic matter (SOM) is a key factor in ecosystem dynamics. A better understanding of the global relationship between environmental characteristics, ecosystems and SOM chemistry is vital in order to assess its specific influence on carbon cycles. This study compared the composition of extracted SOM in 18 topsoil samples taken under tundra, taiga, steppe, temperate forest and tropical forest using pyrolysis-GC/MS. Results indicate that SOM from cold climates (tundra, taiga) still resembles the composition of litter, evidenced by high quantities of levosugars and long alkanes relative to N-compounds and a clear odd-over-even dominance of the longer alkanes. Under temperate conditions, increased microbial degradation generally results in a more altered SOM chemistry. SOM formed under temperate coniferous forests shows an accumulation of aromatic and aliphatic moieties, probably induced by substrate limitations. Tropical SOM was characterized by an SOM composition rich in N-compounds and low in lignins, without any accumulation of recalcitrant fractions (i.e. aliphatic and aromatic compounds). Lignin composition moreover varies according to vegetation type. Results were validated against 13 new samples. The humic signature of topsoil organic matter formed under different biomes indicates a dominating effect of (i) SOM input composition related to vegetation, and (ii) SOM breakdown reflecting both climate and input quality. No evidence was found for a chemically stabilized SOM fraction under favorable decomposition conditions (temperate or warm climate with broadleaved vegetation).