根际环境中镉的形态转化

用根际箱或根际根际袋试验研究了红壤,黄棕壤植稻或植麦后根际中镉的形态转化状况,并讨论了与铅复合处理对镉形态的影响。结果表明,红壤根际,非根际镉的主要形态为可交换态,黄棕壤则主要为碳酸盐结合态。水稻根际富集铁锰氧化物结合态镉,根际有机结合太镉远远大于非根际。对铅,镉复合污染的研究表明。     

安徽宣州黄棕色土和第四纪红土的比较研究及其古气候意义

通过地貌和型面的考察和研究,发现安徽宣州地黄棕色土的层序位于第四纪红土层之上。用ＥＳＲ测年法测得黄棕色土年龄约为８０ｋａＢ．Ｐ．,红土年龄 ２４０ｋａＢ．Ｐ．,。对这两种成土母质的各项理化性状和磁化率指标进行比较研究,发现黄棕色土受风化作用的程度不如第四纪红土。     

土壤电化学性质的研究——Ⅸ.水稻土的某些表面电化学性质

水稻土的表面电化学性质与水稻土的肥力有密切关系。土壤在淹水种稻和排水落干的季节性交替过程中,其pH、Eh和养分离子浓度等都有颇大的变动,某些固相成份如铁、锰、铝等也发生形态的转化或数量的变动。这些变化都将对水稻土的表面电化学性质有明显影响。过去对水稻土的氧化还原性质已研究很多^[3],而对涉及固液相间的离子平衡的表面电化学性质则研究较少。本工作主要是选用几种代表性水稻土及其相应的母质,研究土壤的电荷性质及其对钾离子和氯离子的吸附、作为胶体电解质而表现出来的离解度的变化、和对钾离子的结合能等,以揭示不同类型的水稻土的表面电化学性质的特点,以及水稻土形成过程中表面电化学性质的变异。     

石灰处理对红壤中镉形态及其毒性的影响

The effect of liming 4 red soils developed from Quaternary red clay and red sandstone on the cadmium forms and its toxicity were investigated. Liming the acid red soils could greatly reduce Cd toxicity to plants because the soluble Cd and organic Cd in the soils decreased significantly while Cd bound to minerals/oxides and residual Cd increased markedly with increasing lime rates (pH).     

大田条件下水稻败育与铜缺乏的关系

The effect of liming 4 soils developed from Quaternary red clay and red sandstone on the cadmium forms and its toxicity were investigated.Liming the acid red soils could greatly reduce Cd toxicity to plants because the soluble Cd and organic Cd in the soils decreased significantly while Cd bound to minerals/oxides and residual Cd increased markedly with increasing lime rates(pH).     

受土壤类型和金属负荷量影响的重金属形态分布

Two series of soil subsamples, by spiking copper(Cu),lead(Pb),zinc(Zn)and cadmium(Cd)in an orthogonal design,were prepared using red soil and brown soil,respectively.The results indicated that heavy metal fractions in these soil subsamples depended not only on soil types,but also on metal loading quantity as well as on interactions among metals in soil.Lead and Cu in red soil appeared mostly in weakly specifically adsorbed(WSA),Fe and Mn oxides bound(OX),and residual(RES)fractions.Zine cxisted in all fractions except organic bound one,and Cd was major in water soluble plus exchangeable(SE)one.Different from the results of red soil,Pb and Cu was present in brown soil in all fractions except organic one,but over 75% of Zn and 90% of Cd existed only in SE fraction.Meanwhile,SE fraction for any metal in red soil was lower than that in brown soil and WSA and OX fractions were higher.It is in agreernent with low cation exchange capacity and large amounts of metal oxides included in red soil.Metal fractions in soil,especially for water soluble plus exchangeable one ,were obviously influenced by other coexisting metals.The SE fraction of heavy metals increased with increasing loading amounts of metals in red soil but not obviously in brown soil,which suggest that metal availability be easily affected by their total amounts spiked in red soil.In addition,more metals in red soil were extracted with 0.20 mol L^-1 NH4Cl（pH5.40）than that with 1.0 mol L^-1 Mg(NO3)2(pH7.0),but the reverse happened in brown soil,implicating significantly different mechanisms of metal desorption from red soil and brown soil.     

粉煤灰对污染土壤中铜镉的稳定化

采用批衡量吸附和室内培养实验,考察了粉煤灰对Cu和Cd的吸附等温线及0.2%、0.5%、1%和2%用量的粉煤灰对土壤pH、有效态Cu和Cd、以及5种化学形态Cu和Cd分布的影响。结果表明:粉煤灰对Cu和Cd的吸附等温线均可以用Langmuir和Freundlich方程进行拟合,其对Cu的最大吸附量(9.90 mg/g)高于对Cd的最大吸附量(9.43 mg/g)。随着粉煤灰用量的增加,土壤pH显著增加,有效态Cu和Cd显著降低。同时,粉煤灰处理显著降低了离子交换态Cu和Cd含量,增加了铁锰氧化物结合态Cu和Cd含量,降低了Cu和Cd活性,使活性态Cu和Cd逐渐向潜在活性态和非活性态转化。其中培养60天后,2%处理的粉煤灰处理较对照pH提高了0.44个单位,离子交换态Cu和Cd分别降低了35.7%和35.9%。因此,粉煤灰能够有效吸附Cu和Cd,显著降低土壤有效态和离子交换态Cu和Cd的含量,在重金属稳定化修复应用中具有较好的应用前景。     

生物炭对红壤和褐土中镉形态的影响

【目的】重金属对环境危害的大小主要取决于其形态分布,尤其是生物有效态镉 (Cd) 的含量和存在比例。添加生物炭可以降低Cd超标土壤中生物有效态Cd的含量,本文研究了施用生物炭后红壤和褐土中Cd形态的变化及其与生物炭施用量的关系,以加深对生物炭修复Cd污染土壤机理的认识。【方法】选择红壤 (pH 5.21) 和褐土 (pH 7.75) 两类土壤进行了室内培养试验。将两个过2 mm筛的自然风干土壤各40 kg,分别装于20 L塑料盒中,加Cd(NO₃)₂溶液使土壤外源Cd含量达到5 mg/kg,保持70%田间最大持水量,于25℃条件下平衡两周;之后,在每1000 g土内,分别添加生物炭0、5、10、20 g,均匀混合后,室温培养50 d;在培养1、4、7、14、21、35、49 d时分别取样,测定土壤pH和有机碳含量,利用Tessier分级法测定土壤Cd形态。【结果】红壤pH随生物炭施用量的增加显著升高,培养14天后,生物炭施加量为2%时,土壤由酸性变为弱碱性,生物炭对褐土pH的提高作用不显著。红壤和褐土有机碳含量均随生物炭施用量的增加而升高。培养49天后,红壤可交换态Cd含量的降幅较大,降幅为0.31～0.82 mg/kg,且处理2%的可交换态Cd含量最低,为1.24 mg/kg,生物炭施用量2%的红壤碳酸盐结合态Cd含量最高,为1.06 mg/kg,施用生物炭的红壤碳酸盐结合态Cd和Fe、Mn氧化物结合态Cd所占比例增加了3.14%～14.21%、8.20%～23.96%,施用生物炭的褐土碳酸盐结合态Cd和Fe、Mn氧化物结合态Cd升高了0.94%～2.61%、0.80%～7.90%。褐土的土壤有机碳含量和生物炭施用量与土壤可交换态Cd呈极显著负相关关系,与土壤碳酸盐结合态Cd,土壤Fe、Mn氧化物结合态Cd和土壤有机结合态Cd呈极显著正相关关系;红壤pH、有机碳含量和生物炭施用量均与土壤可交换态Cd呈极显著负相关关系,与土壤其他四种形态Cd呈极显著正相关关系。但在红壤中土壤有机碳和生物炭施用量与各形态Cd的相关系数均大于在褐土中的相关系数。【结论】综合分析两种类型土壤中Cd形态的变化,发现生物炭对红壤的修复效果优于对褐土的修复效果,因此生物炭可以作为Cd污染的酸性土壤的一种修复改良材料。     

表面活性剂LAS对土壤Cd形态及Cd在黄豆植株中分配的影响

A pot experiment was conducted to study the effect of an anionic surfactant linear alkylbenzene sulfonate （LAS） application on cadmium （Cd） fractions in soils and Cd distribution in different tissues of soybean （Glycine max） plants as well as soil pH. Soil samples were treated with three levels of Cd （0, 5, and 10 mg kg^-1） and five levels of LAS （0, 5, 15, 50, and 100 mg L^-1）. Results indicated that compared to the control soils （no Cd and no LAS treatment）, soil pH increased and available Cd decreased in the soil treated with external Cd and watered with LAS solutions. Meanwhile, soil exchangeable Cd and Cd bound to carbonates decreased; Cd bound to amorphous iron and manganese oxides and Cd bound to organic matter increased. In addition, LAS application could reduce enrichment of Cd in soybean plants, resulting in decreased Cd in the soybean plants. Thus, suitable LAS application could decrease bioavailability and mobility of soil Cd.     

Distribution of Aluminum Fractionation in the Acidic Rhizosphere Soils of Masson Pine (Pinus massoniana Lamb)

The modified Tessier’s sequential extraction procedure and rhizobox cultivation were employed to investigate the distribution of aluminum (Al) fractions in the acidic rhizosphere soil of Masson pine (Pinus massoniana lamb) seedlings. The results showed that the Al in soils was fractionated into five operationally defined fractions. Three sets of soil samples used in the rhizoboxes were collected from the three forest sites in the southeast of China: Sichuan, Zhejian, and Jiangsu. At the end of 100-day cultivation, the rhizosphere Al fractions for the original or bulk soils were in the order of residual > iron-manganese (Fe-Mn) oxides > organic > carbonate > exchangeable. However, in rhizosphere soil, the Al fraction follows the order of residual > organic > Fe-Mn oxides > carbonate > exchangeable. On average, the rhizosphere experienced significant increase in organically bound Al and slight decrease in exchangeable Al contents, but had decreases in contents for the other three Al fractions compared to the nonrhizosphere. The correlation analysis indicated that the Al contents accumulated in roots were significantly and positively correlated with exchangeable Al contents in the rhizosphere, and also characterized by the major portion of organically bound Al, which exhibited a bioavailable transformation of Al fractions. Results indicated that decreases in both redox potential and soil pH, as well as increase in dissolved organic carbon (DOC), were observed in the rhizosphere. Exchangeable Al and organic Al fractions were dependent mainly on soil pH (hydrogen ion concentration) and DOC, accordingly. Decreasing rhizosphere pH from 5.93 to 3.42 accelerated the secretion of organic carbon. These data are helpful for understanding the mobility and bioavailability of Al fractions in the acidic rhizosphere soils of Masson pine.     

水稻子实对不同形态重金属的累积差异及其影响因素分析

在分析成都平原核心区土壤重金属(Cd、Cr、Pb、Cu、Zn)全量、各形态含量及相应点位种植的水稻子实重金属含量的基础上,通过统计分析、空间插值及线性回归方程的模拟,研究了土壤Cd、Cr、Pb、Cu、Zn全量的空间分布状况、各形态重金属含量统计特征,以及水稻子实对重金属各形态的累积差异及其影响因素。结果表明,成都平原水稻土重金属污染较轻,除Cd外,均低于国家土壤环境质量二级标准。土壤中重金属的可交换态含量均较低,Cd主要以铁锰氧化态存在,Cr、Cu、Zn、Pb主要以残渣态存在。水稻子实对5种重金属的累积效应顺序为:Cd>Zn>Cu>Pb>Cr。与水稻重金属累积关系密切的重金属活性形态(可交换态、碳酸盐结合态、铁锰氧化物结合态和有机物结合态)主要有:Cd的碳酸盐结合态、Cr的可交换态、Pb的有机物结合态和Cu的碳酸盐结合态含量;Zn各活性形态对水稻子实含量的影响不明显。土壤理化性质对不同活性形态重金属元素的影响效应各不相同。活性态Cd主要受有机质、pH和容重的影响;活性态Cr与pH、有机质、CEC和容重密切相关;活性态Pb与有机质、容重、中细粉粒、砂粒等均有密切的关系;Cu的活性主要受粘粒、有机质含量的影响;Zn的有效性主要受pH、有机质、砂粒、容重的影响。总的看来,对土壤Cd、Cr、Pb、Cu、Zn各活性形态含量影响效应较强的是有机质、pH、容重,而与土壤吸附性能密切相关的颗粒组成、CEC的影响不甚明显。     

五氯酚在酸性土壤表面的吸附-解吸特征研究

本实验研究五氯酚在江西红壤和南京黄棕壤表面的吸附-解吸特征,结果表明:Freundlich和Langmuir等温吸附方程均能较好地描述PCP在两种土壤表面的吸附,且黄棕壤表面的最大吸附量大于红壤。用动力学方程对PCP在红壤中的吸附过程进行拟合,Elovich方程、双常数方程和一级动力学方程均得到较好的结果,其相关系数(R2)在0.96 ~ 0.99之间,达到极显著水平。Elovich方程反映出PCP在土壤表面吸附的能量非均质分布;而抛物线扩散方程不能描述PCP的吸附过程,其相关系数0.46 ~ 0.48。PCP在土壤中的解吸率与有机质含量和pH值相关,随有机质含量增加,PCP解吸率降低,即黄棕壤表土<黄棕壤底土,红壤表土<红壤底土;随模拟酸雨的pH值降低,土壤因对PCP的吸附能力增加,其解吸率降低。     

适量施磷有效提高苋菜对镉污染土壤的修复能力

  【目的】  土壤性质和化肥施用均影响作物对重金属污染土壤的修复效果。探究不同磷肥施用量对苋菜镉 (Cd) 吸收和累积的影响,为通过养分管理减少作物对重金属的积累提供依据。  【方法】  以苋菜 (Amaranshus mangostanus L.) 为供试作物,以黄棕壤和赤红壤为供试土壤进行盆栽试验。在两个供试土壤中,加入分析纯CdCl₂?2.5H₂O (Cd 15 mg/kg土), 平衡一个月后,用于苋菜栽培。设置5个磷肥（P）施用水平:0 (CK)、50、100、200、400 mg/kg土,以磷酸二氢铵 (分析纯) 加入。苋菜生长45天后收获,调查地上部和根部生物量,分析其磷、镉含量,并测定土壤中DTPA提取的有效态Cd含量。  【结果】  施用磷肥能提高苋菜的生物量,随着施磷量的增加,苋菜生物量也随之增加,且各处理均与CK处理差异显著。在黄棕壤上,苋菜地上部生物量增幅为9.2%～39.0%,根部为4.0%～15.0%;在赤红壤上,苋菜地上部增幅为7.7%～46.0%,根部为10.0%～100.0%。苋菜Cd含量与CK处理相比均显著降低,在黄棕壤上,苋菜地上部和根部Cd含量的降幅分别为7.4%～50.2%和7.9%～58.8%;在赤红壤上,降幅分别为9.9%～55.8%和21.7%～66.0%。苋菜Cd累积量与CK处理相比均呈上升趋势,黄棕壤上苋菜地上部和根部Cd累积量的增幅分别为36.2%～54.3%和7.4%～38.9%;在赤红壤上,增幅分别为34.3%～62.8%和5.4%～55.4%。当施磷量为P 50 mg/kg土时,苋菜地上部、根部在黄棕壤和赤红壤上的Cd累积量均最大。施磷降低了土壤中镉的生物有效性。随着施磷量的增加,土壤有效态Cd含量显著降低,黄棕壤上的降幅为0.9%～7.2%,赤红壤上的降幅为1.2%～7.9%。植株体内Cd含量与磷含量之间存在一定的负相关性。  【结论】  施用磷肥显著提高苋菜的生物量,同时降低土壤中有效态镉的含量。虽然施磷肥显著降低了苋菜地上部和根部的Cd含量,但显著提高的生物量有效增加了苋菜对土壤Cd的总吸收和累积量,提高了其对镉污染土壤的植物修复效率。盆栽结果表明,在镉浓度为15 mg/kg 土的黄棕壤和赤红壤上,磷肥施用量为50 mg/kg土时修复效果最佳。     

Contribution of Iron and Aluminum Oxides to Electrokinetic Characteristics of Variable Charge Soils in Relation to Surface Charge

The contribution of iron and aluminum oxides to electrokinetic characteristics of variable charge soils was studied through determination of electrophoretic mobilities of the red soils treated with either removal of iron oxides or coating of aluminum oxides,and of those deferrated under natural conditions.After removal of the iron oxides,zeta potentials of the latosol and the red earth decreased obviously with a shift of IEP to a lower pH,from 6.4 to 5.3 and 4.1 to 2.4 for the former and the latter,respectively,and the electrokinetic change for the latosol was greater than for the red earth.Zeta potentials of the kaolinite sample increased markedly after coated with iron oxides.The striking effect of iron oxides on electrokinetix properties of the soils was also demonstrated by the electrokinetic differences between the samples from the red and white zones of a plinthitic horizon formed naturally,and between the samples from the gley and bottom horizons of a paddy soil derived from a red earth.The coatings of aluminum oxides on the latosol and the yellow earth made their zeta potentials rise pronouncedly and their IEFs move toward higher pHs,from 6.2 to 6.8 and 4.3 to 5.3 for the former and the latter,respectively.The samples with different particle sizes also exhibited some electrokinetic variation.The experiment showed that the effects of iron and aluminum oxides were closely related to the pH and type of the soils.     

白银市污灌区土壤-小麦系统镉赋存特征及其健康风险评价

为探明白银市有色冶炼污灌区土壤镉(Cd)形态、空间分布特征及小麦中Cd含量对人体健康的影响,采用连续分级提取法和地理信息系统(ArcGIS)空间插值方法,研究污灌区表层土壤和不同污染程度典型土壤剖面Cd赋存形态及其空间分布差异,阐明污灌区Cd在不同生育期春小麦不同器官中分布和富集特征,并利用健康风险模型计算Cd的健康风险水平并进行空间区划。结果表明,表层土壤Cd不同形态平均含量依次为碳酸盐结合态>可交换离子态>铁锰氧化物结合态>残渣态>有机结合态,占全量比例依次为碳酸盐结合态>残渣态>可交换离子态>铁锰氧化物结合态>有机结合态,其空间分布与Cd总量分布相似。Cd的五种形态均与pH呈显著负相关,与土壤有机质(SOM)呈显著正相关。除残渣态外,其他四种Cd形态和阳离子交换量(CEC)呈显著正相关。0~60 cm土壤剖面Cd形态以碳酸盐结合态和铁锰氧化物结合态为主,可交换离子态随污染程度降低而降低,残渣态随污染程度降低而增加。春小麦不同器官的Cd含量随春小麦生长总体表现为根>叶>茎>籽粒。Cd健康风险分布与土壤Cd总量、土壤可交换离子态和碳酸盐结合态Cd的空间分布一致。不同区域居民食用小麦对成人的健康风险指数(HQ)范围在1.2~5.6之间,均大于1,已存在非致癌健康风险。本研究结果为白银市土壤重金属Cd污染综合防控提供了科学依据。     

新乡市寺庄顶污灌区土壤及小麦重金属污染特征的研究

通过田间采样及室内样品分析,对新乡市寺庄顶污灌区土壤和小麦子实中重金属污染特征进行了初步探讨。结果表明,土壤中cr含量达标,Cd、Ni、Zn和Cu的含量超标,其平均含量分别为65．31、1196．64、2799．25和145．78mg·kg-1,是国家土壤环境二级标准的108．85、19．94、9．33和1．46倍;污染最严重的Cd主要以铁-锰氧化物结合态存在,所占比例平均为56．84％,Ni主要以铁-锰氧化物结合态和残渣态存在,所占比例平均为37．44％和39．55％,Zn主要以残渣态存在,所占比例平均为78．24％,Cu主要以有机结合态存在,所占比例平均为57．70％。小麦子实中cd污染最严重,其平均含量为2．55mg·kg-1,是国家食品卫生标准的25．5倍,这主要是由于土壤中Cd总量严重超标且迁移能力最强的可交换态所占比例较高引起的,Ni、Cr和Zn含量分别是国家食品卫生标准的12．98、6．12和1．32倍,表明长期污水灌溉对寺庄顶灌区小麦的食品安全造成严重威胁,应引起足够的重视。     

几种有机酸对可变电荷和恒电荷土壤吸附镉的影响

The objectives of this study were to illustrate the reaction processes, to identify and quantify the precipitates formed, and to estimate the porosity losses in order to eliminate drawbacks during remediating monochlorobenzene （MCB） and trichloroethylene （TCE）-contaminated aquifers using the ORC-GAC-Fe^0-CaCO3 system. The system consisted of four columns （112 cm long and 10 cm in diameter） with oxygen-releasing compound （ORC）, granular activated carbon （GAC）, zero-valent iron （Fe^0）, and calcite used sequentially as the reactive media. The concentrations of MCB in the GAC column effluent and TCE in the Fe^0 column effluent were below the detection limit. However, the concentrations of MCB and TCE in the final calcite column exceeded the maximum contaminant level （MCL） under the Safe Drinking Water Act of the US Environmental Protection Agency （US EPA） that protects human health and environment. These results suggested that partitioning of MCB and TCE into the gas phase could occur, and also that transportation of volatile organic pollutants in the gas phase was important. Three main precipitates formed in the ORC-GAC-Fe^0-CaCO3 system： CaCO3 in the ORC column along with Fe（OH）2 and FeCO3 in the Fe^0 column. The total porosity losses caused by mineral precipitation corresponded to about 0.24% porosity in the ORC column, and 1% in the Fe^0 column. The most important cause of porosity losses was anaerobic corrosion of iron. The porosity losses caused by gas because of the production and entrapment of oxygen in the ORC column and hydrogen in the Fe^0 column should not be ignored. Volatilization, precipitation and porosity losses were considered to be the main drawbacks of the ORC-GAC-Fe^0-CaCO3 system in remediating the MCB and TCE-contaminated aquifers. Thus, measurements such as using a suitable oxygen-releasing compound, weakening the increase in pH using a buffer material such as soil, stimulating biodegradation rates and minimizing the plugging caused by the relatively high dissolved oxygen levels should be taken to eliminate the drawbacks and to improve the efficiency of the ORC-GAC-Fe^0-CaCO3 system.     

七种钾释放动力学方程的比较和动力学参数的应用

Batch equilibrium experiments were conducted to investigate cadmium （Cd） sorption by two permanent-charge soils, a yellow-cinnamon soil and a yellow-brown soil, and two variable-charge soils, a red soil and a latosol, with addition of selected organic acids （acetate, tartrate, and citrate）. Results showed that with an increase in acetate concentrations from 0 to 3.0 mmol L^-1, Cd sorption percentage by the yellow-cinnamon soil, the yellow-brown soil, and the latosol decreased. The sorption percentage of Cd by the yellow-clnnamon soil and generally the yellow-brown soil （permanent-charge soils） decreased with an increase in tartrate concentration, but increased at low tartrate concentrations for the red soil and the latosol. Curves of percentage of Cd sorption for citrate were similar to those for tartrate. For the variable-charge soils with tartrate and citrate, there were obvious peaks in Cd sorption percentage. These peaks, where organic acids had maximum influence, changed with soil type, and were at a higher organic acid concentration for the variable-charge soils than for the permanent charge soils. Addition of cadmium after tartrate adsorption resulted in higher sorption increase for the varlable-charge soils than permanent-charge soils. When tartrate and Cd solution were added together, sorption of Cd decreased with tartrate concentration for the yellow-brown soil, but increased at low tartrate concentrations and then decreased with tartrate concentration for the red soil and the latosol.     

黄棕壤添加重金属的毒性评价及其临界浓度确定

在连续盆栽水稻、小麦的过程中研究了加入黄棕壤的Cu、Cd、Pb的毒性(发光细菌法)。结果表明,当以水提取黄棕壤中三元素,浓度低,不显毒性,这与水提取红壤的结果相反;当以0.1mol L^-1HCI提取黄棕壤中三元素,则浓度明显提高而显示毒性。在相关显著水平P=0.001的基础上建立了土壤金属浓度与剩余发光度(毒性指标)优化拟合方程。规定含金属土壤的临界剩余发光度为90%(EC₁₀)。据此,估算出黄棕壤中Pb、Cu、Cd的临界浓度(μg/g土)分别为:488-587,17.8-25.3,2.11-2.12。     

南方稀土矿区水土保持植物根际土壤碳氮及pH特征

选取南方稀土矿区芒萁、宽叶雀稗、枫香和木荷四种典型水土保持植物,研究其根际与非根际土壤各种形态氮素和有机碳含量特征以及pH的变化。研究表明,根际较非根际土壤全氮、铵态氮和硝态氮平均分别高出79.7%、34.2%和30.7%,土壤有机碳平均高出164.9%,pH平均高出0.13个单位。除pH外,根际土壤与非根际土壤全氮、铵态氮、硝态氮和有机碳之间均差异显著(p0.05)。四种植物根际土壤全氮、硝态氮、铵态氮和有机碳的含量均较非根际土壤含量高。宽叶雀稗的根际土壤pH大于非根际土壤,而木荷、芒萁和枫香的根际土壤p H与非根际土壤无显著差异。在根际与非根际土壤中,土壤全氮与土壤有机碳之间呈显著正相关,而土壤全氮与土壤铵态氮、土壤全氮与土壤硝态氮之间均无相关性。即稀土矿区四种植物对碳氮主要养分均具有较强的截存效应,可作为稀土矿区生态恢复的主要植物。