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阿维菌素土壤吸附特性研究
引用本文:谢显传,张少华,王冬生,皇甫伟国,杨挺,赵健.阿维菌素土壤吸附特性研究[J].中国农业科学,2007,40(9):1959-1963.
作者姓名:谢显传  张少华  王冬生  皇甫伟国  杨挺  赵健
作者单位:1. 上海市农业科学院植物保护研究所/上海市设施园艺技术重点实验室,上海,201106;南京大学环境学院,南京,210093
2. 宁波市农业科学研究所农产品检测中心,宁波,315040;宁波市产品质量监督检验所,宁波,315040
3. 上海市农业科学院植物保护研究所/上海市设施园艺技术重点实验室,上海,201106
4. 宁波市农业科学研究所农产品检测中心,宁波,315040
基金项目:上海市科技兴农科技攻关项目
摘    要: 【目的】研究阿维菌素在土壤中的环境行为。【方法】应用平衡法研究了阿维菌素在5种土壤上的吸附特性。【结果】土壤对阿维菌素具有很强的吸附特性,且随着土壤理化性质的差异,土壤对阿维菌素的吸附性有着明显差异;阿维菌素在土壤中的吸附符合Fruendlich方程,其吸附常数Kaf值与土壤有机质含量和粘粒含量呈显著正相关性;阿维菌素在土壤上的吸附自由能为10.9859~25.1538 kJ•mol-1。【结论】阿维菌素在土壤上的吸附主要是物理吸附;表面活性剂吐温-80对水稻土、菜地土和山地红壤上吸附的阿维菌素具有显明的增溶作用,而对山地黄壤和盐碱土则有着增加土壤对阿维菌素的吸附能力的影响。

关 键 词:阿维菌素  土壤    吸附    液相色谱法
收稿时间:2006-6-29
修稿时间:2006-06-26

Adsorption of Abamectin in Soil
XIE Xian-chuan,ZHANG Shao-hua,WANG Dong-sheng,HUANG PU Wei-guo,YANG Ting,ZHAO Jian.Adsorption of Abamectin in Soil[J].Scientia Agricultura Sinica,2007,40(9):1959-1963.
Authors:XIE Xian-chuan  ZHANG Shao-hua  WANG Dong-sheng  HUANG PU Wei-guo  YANG Ting  ZHAO Jian
Institution:1 Plant Protection Research Institute,Shanghai Academy of Agricultural Science,Shanghai Key Laboratory of Protected Horticultural Technology,Shanghai 201106;2 School of the Environment,Nanjing University,Nanjing 210093;3 Analytical Center of Agricultural Produce,Ningbo Academy of Agricultural Science,Ningbo 315040;4 Ningbo Superuvision and Inspection Institute for Product Quality,Ningbo 315040
Abstract:Adsorption of abametin in 5 different soils was studied by batch equilibration technique. The result showed that soils had strong adsorption of abamectin, which, however, varied with the different properties of the soil tested. The isotherm data were fitted to Fruendlich equation, The Kaf values increased with increasing organic matter and clay content of soil, the correlative coefficient of Kaf values and organic matter and clay content of soil were significantly positive .The free energy of sorption ranged from 10.9859 kJ/mol to 25.1538 KJ/mol indicates that the spontaneity of the given sorption process of abamectin in soils.
Keywords:Abamectin  Soil  Adsorption  HPLC
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