Soil boron status: impact of lime and fertilizers in an Indian long-term field experiment on a Typic Paleustalf

In Indian agriculture, nitrogen (N) and phosphorus (P) fertilizers are predominantly used by the farmers, often ignoring secondary and micronutrients. Significance of boron (B) in nutrient management studies has been increasingly underlined under intensive cropping systems particularly in acid soils. In order to understand the distribution of soil native B in different fractions and their contribution to plant B uptake as influenced by nutrient management, soil samples collected after wheat (2009–2010) from a long-term experiment (LTE) continuing since 1972–1973 on Typic Paleustalf of Ranchi were subjected to sequential fractionation of soil B. Treatments included N alone, NP, NPK, 150% of recommended NPK, NPK + farmyard manure (FYM), NPK + lime, and an unfertilized-control. Five soil B fractions were determined along with hot CaCl₂-extractable (available) B. Averaged across the treatments, the soil had low organic carbon (C), pH and cation exchange capacity (CEC), and high free sesquioxides. Total B content was 21.7 mg kg^?1. Among different B fractions, residual B was the major contributor to total B and other fractions collectively shared 7% of total B only. Application of N alone depleted readily soluble, specifically adsorbed and organically bound B bringing the contents even below unfertilized-control. Conjoint use of lime or FYM with NPK increased significantly these fractions, whereas a decrease in oxide bound B was noticed under these treatments. Available B was positively correlated with these fractions indicating their significance in controlling B availability in the soil. The study revealed that use of lime or FYM helped modifying the distribution of soil B in different fractions by way of changing soil pH and organic C content, resulting in enrichment of plant available pool. A drastically low available B content in different treatments receiving fertilizers alone, however, suggested the necessity of B fertilization at prescribed rates for maintaining soil B fertility as also high crop yields.