Composition and transformation of 1.4 nm minerals in cutan and matrix of alfisols in central China

Background, Aims, and Scope  Hydroxy interlayered vermiculite (HIV) and vermiculite are commonly referred to as 1.4 nm minerals. In the subtropical soils of central China, the concentration of vermiculites decreased while that of HIVs increased gradually from north to south as the intensity of soil formation or eluviation increases in the same direction. The cutans in these soils closely interact with air, roots, microbes, water and dissolved ions in soils. Cutans may therefore be expected to exert an important influence on the formation of 1.4 nm minerals relative to the matrix soils. However, little is known about the transformation of 1.4 nm minerals in Alfisols in central China. Here, we investigate the compositional differences of 1.4 nm minerals in cutans and matrix soils, and the probable transformation of vermiculite to HIV or vice versa when sodium citrate and sodium acetate are added to matrix Alfisols. Methods  Cutans and matrix soils were separated from three soils in the northern subtropical zone in China. The samples were analyzed for Fe, Mn, exchangeable cations, organic matter(O.M.), pH, and clay minerals. To 10 mL of matrix soil, suspensions containing about 250 mg (oven-dry weight) of clay was added with 5 mL of 0.4 mol/dm³ or 2 mol/dm³ of sodium citrate or sodium acetate solution and 5 mL of 0.2 mol/dm³ mixed solutions of CaCl₂, Mg(NO₃)₂ and KCl. After its pH was adjusted to 6.0, the mixture was ‘incubated’ for 120 or 210 days (more than one season or half a year) during which period it was shaken for 1 hour every day. The clay mineral composition of the samples was determined after incubation. Results  Both vermiculites and HIVs were present in matrix soils, but only vermiculties were detected in cutans. The addition of organic ligands (citrate and acetate) promoted the transformation of HIV to vermiculite. This transformation was obvious for the matrix soils that had been incubated with 0.5 mol/dm³ sodium citrate for 210 days while sodium acetate was less effective in this regard. The promoting effect of organic ligands is dependent on type and concentration as well as incubation time. This would suggest the reverse transformation occurred in the formation of cutans compared with a vermiculite-to-HIV transformation in the subtropical soils of central China from north to south. Discussion  The position and environment of cutans in the B horizon together with the pH, organic matter and exchangeable base status in cutans seem conducive to the co-existence of vermiculite and HIV in the soils, but only vermiculite is found in cutans. The transformation of HIV to vermiculite in incubation experiments could be divided into two steps: 1) Cheluviation of organic matter to the interlayer hydroxy-aluminums from HIVs. 2) Rebasification of hydrated cations into the interlayers of vermiculites. Conclusions  The clay minerals in cutans can interact with organic ligands and nutrient elements excreted by roots. Under conditions of frequent wetting and drying and high pH, and when the concentrations of exchangeable bases, iron-manganese oxides, clays, and organic matter are high, the exchangeable cations can be incorporated into the interlayers of HIV, thereby promoting the partial transformation of HIV to vermiculite in rhizosphere soils. Recommendations and Perspectives  Cutan is at the interface of material and energy exchange involved in physical, chemical and biochemical reactions in the rhizosphere. These factors strongly affect the compositions of cutans. HIVs in (upper or adjacent) matrix soils may transform to vermiculites during cutan formation in these special soil environments. ESS-Submission Editor: Jizheng (Jim) He (jzhe@rcees.ac.cn)     

Tillage and mulch effects on soil physical environment, root growth, nutrient uptake and yield of maize and wheat on an Alfisol in north-west India

Field experiments were conducted for 6 years on a silty clay loam to study the effect of soil management on soil physical properties, root growth, nutrient uptake and yield of rainfed maize (Zea mays L.) and wheat (Triticum aestivum L.) grown in a sequence. Treatments were: no-tillage (NT), NT+pine needle mulch at a rate of 10 t ha⁻¹ (NT+M), conventional tillage (CT), CT+pine needle mulch at a rate of 10 t ha⁻¹ (CT+M) and deep tillage (DT). The soil is classified as a Typic Hapludalf and has compact sub-surface layers. The NT treatment increased the bulk density of the surface layer but this problem was not observed in the no-tilled treatment having mulch at the surface (NT+M). The CT+M and NT+M treatments favourably moderated the hydro-theregime resulting in greater root growth, nutrient uptake and grain yields of maize and wheat. The DT treatment, imposed only once, at the beginning of the study, also enhanced root growth and grain yields. The yields were similar to the mulched treatments for maize and somewhat less than the mulched treatments for wheat. Mulched treatments generally showed significantly greater total uptake of N, P and K than corresponding unmulched ones. Since NT+M was comparable to CT for maize and superior for wheat, the latter is preferable since it does not require ellaborate tillage.     

The status and fluxes of alkali and alkaline-earth metals in a savanna Alfisol under long-term cultivation

Information on the status and fluxes of alkali (Na, K and Rb) and alkaline-earth metals (Ba, Ca, Mg and Sr) in cultivated soils is required to predict their responses and sensitivity to acidification. The soils for this study were fertilized with NPK (NPK-plot), farmyard manure (FYM-plot) and combined application of FYM and NPK (FYM+NPK-plot) for 50 years. A control-plot, which neither received NPK nor FYM for 50 years, and a natural site were also sampled. Compared to the natural site, significant losses of alkali and alkaline-earth metals occurred in NPK-plot. The FYM+NPK-plot gained excess mass of Ca and Mg, but incurred losses of Na, Rb, K, Ba and Sr. In the FYM-plot, 4% excess mass of Mg and 65% excess mass of Ca were added to the soil, while in the FYM+NPK-plot, 18% excess mass of Mg and 61% excess mass of Ca were added to the soil. The excess masses of Ca and Mg added to these plots partly accounted for from incidental additions through FYM and NPK fertilization and from aeolian sources which, together, were accounted for between 40% and 56% of the Ca-enrichment and between 45% and 100% of Mg-enrichment. Evidence in the study supports the notion that sole application of NPK fertilizers leads to chemical degradation and increases the risk of acidification of savanna Alfisols under continuous cultivation.     

An evaluation of furrows for managing soil and water loss from a shallow Alfisol under simulated rainfall

Furrows are widely used in rainfed areas of semi-arid India for soil and water conservation. The orientation of furrows, either down or across slope, and their spacing influence the effectiveness of furrows as soil and water conservation measures. We evaluated treatments with furrows aligned down and across 3% sloping land at spacings of 90, 60 and 30 cm under simulated rainfall intensities of 80 and 100 mm/h on a shallow Alfisol. A bare plot without any furrows was considered as a control. A large (24 m × 3 m) rainfall simulator developed at the Central Research Institute for Dryland Agriculture (CRIDA), Hyderabad, was used for this controlled study. Run-off was measured by a calibrated tipping bucket run-off recorder. The effects of the treatments on peak flow rate (L/s), sediment loss with run-off water (kg/ha/mm), peak sediment concentration (g/L), run-off (per cent rainfall) and time to peak (min) were investigated. When compared with the control (no furrows), across slope furrowing with 60- and 30-cm spacing reduced sediment yields by 19.9 and 21.3 kg/ha/mm of run-off, respectively, under a rainfall intensity of 80 mm/h and 24 and 25.3 kg/ha/mm of run-off, respectively, under a rainfall intensity of 100 mm/h. For the control, sediment loss was 50.72 kg/ha/mm run-off and 56.68 kg/ha/mm run-off for rainfall intensities of 80 and 100 mm/h, respectively. Similar trends were recorded from observations of peak flow, time to peak and peak sediment concentration. Run-off hydrographs demonstrated the conservation value of across slope furrowing by delaying run-off initiation, reducing run-off and slowly releasing the run-off after the cessation of rainfall. The results show that furrow orientation has major effects on reducing run-off, whereas furrow spacing has insignificant effects.     

Effect of 46 years' application of fertilizers,FYM and lime on physical,chemical and biological properties of soil under maize–wheat system in an acid Alfisol of northwest Himalayas

Imbalanced fertilizer use with intensive cropping has threatened the sustainability of agroecosystems, especially on acid soils. An understanding of the long-term effects of fertilizers and amendments on soil health is essential for sustaining high crop yields. The effects of application of fertilizers, and amendments for 46 years on soil properties and maize yield in an acid Alfisol were investigated in this study. Ten fertilizer treatments comprising different amounts of NPK fertilizers, farmyard manure (FYM) and lime, and one control, were replicated three times in a randomized block design. At 0–15 cm soil depth, bulk density was least (1.20 t/m³), porosity (49.8%) and water holding capacity (61.7%) were greatest in 100% NPK + FYM, corresponding to the largest organic carbon content (13.93 g/kg). Microbial biomass C and dehydrogenase activity in 100% NPK + FYM were 42% and 13.7% greater than 100% NPK, respectively. Available nutrients were significantly more with 100% NPK + FYM and 100% NPK + lime than control and other fertilizer treatments. At 15–30 cm depth, the effect of various treatments was comparable to the surface layer. Grain yield declined by 55% and 53% in 100% NPK(-S) and 100% NP, respectively, compared with 100% NPK, whereas 100% N as urea alone eventually led to crop failure. Soil porosity recorded the greatest positive correlation (r = .933**), whereas bulk density recorded a negative significant correlation (r = −.942**) with grain yield. The results suggest that integrated use of FYM/lime with chemical fertilizers is a sustainable practice in terms of crop yield and soil health, whereas continuous application of urea alone is detrimental to the soil health.     

Characterization of iron oxides in Fe-rich concretions from an imperfectly-drained Greek soil: a study by selective-dissolution techniques and X-ray diffraction

Fe-rich concretions commonly occur in Greek soils with alternating drying and waterlogging periods. This study was conducted to characterize the iron oxides in Fe-rich concretions from the upper solum of an Alfisol with seasonal perched water table by the combination of selective dissolution and X-ray diffraction (XRD) techniques. The results showed that more than 75% of the total iron (Fet) was associated with the crystalline and the amorphous Fe oxides, indicating a strong accumulation of free iron oxides (Fed) in concretions. Amorphous iron compounds (Feo) was present at high concentrations and fluctuated with profile depth. The active Fe ratio (Feo/Fed) values that ranged from 0.35 to 0.41 reflected an association of poorly crystalline goethite with some ferrihydrite. The XRD data showed that the Fe-rich concretions consisted of quartz, feldspars, illite and gypsum. The mineralogy of iron oxides in concretions was determined by comparison of XRD patterns for dithionite-citrate-bicarbonate (DCB) treated (deferrated) and untreated (non-deferrated) samples. Poorly crystalline goethite as demonstrated by broad lines in the diffraction patterns and ferrihydrite were the iron oxides detected in the concretions. This mineral assemblage appears to be related to the pedoenvironmental conditions in which the concretions were formed and indicates that the mechanisms governing the formation of crystalline Fe oxides from ferrihydrite are retarded by the presence of crystallization inhibitors.     

Chemical Fractions of Zinc and Their Contribution toward Its Availability under Long-Term Integrated Nutrient Management in Rice–Wheat Sequence in an Acidic Alfisol

This study was carried out in an ongoing field experiment initiated during the 1991 kharif season (May–October) on an acidic soil in the Western Himalayas of India to evaluate the effect of integrated nutrient supply on transformation of zinc (Zn) into various chemical pools. The continuous use of chemical fertilizers alone for 20 years brought about marked depletion in different pools of Zn compared to buffer plots, while integrated use of organic and chemical fertilizers recorded greater content than chemically treated plots. Nonspecifically adsorbed exchangeable Zn (Zn I) was the most important fraction of Zn contributing to diethylene triamine penta-acetic acid (DTPA)–extractable Zn. Content of DTPA-extractable Zn also increased in soil with integrated application of chemical fertilizers and organics over the years. Residual Zn was the most dominant form of Zn, contributing about 55% to total Zn, whereas nonspecifically adsorbed exchangeable Zn was the most important fraction of Zn contributing to DTPA Zn.     

Continuous Cropping,Fertilization, and Organic Manure Application Effects on Potassium in an Alfisol under Arid Conditions

Effects of continuous cropping and addition of organic manures (farmyard manure, FYM, and groundnut shells, GNS) along with inorganic fertilizers on nonexchangeable potassium (K) release kinetics in a K-deficient Alfisol were studied in a 20-year manurial experiment under arid conditions. There was a depletion in available K under continuous cropping without K input (control) as compared to other treatments such as 100% nitrogen–phosphorus–potassium (NPK), 50% NPK + 4 metric tons (MT) groundnut shells ha^?1, 50% NPK + 4 MT FYM ha^?1, and 100% organic (i.e., 5 MT FYM ha^?1). Over 20 years of cropping without K input, available K was reduced from 155 kg ha^?1 (in 1985) to 82 kg ha^?1 (in 2005), showing a negative balance of 73 kg ha^?1. Soil in control plots showed available K in the deficient range (<50 mg kg^?1), whereas four other fertilizer and manurial treatments were greater than the critical limit. Considerable improvements in nonexchangeable K-release parameters such as step K and cumulative K release were observed in manured plots over control. Parabolic diffusion and first-order kinetic equations explained K release from soils. Potassium-release rates were drastically reduced in control plots, and there were increased release rates with continuous addition of manures. Results suggest that soils with groundnut shells or FYM (4 MT ha^?1) along with 50% inorganic fertilizer additions could maintain greater K release rates after 20 years of cropping as compared to cropping without K input.     

Role of zeolites in persistence of high altitude ferruginous Alfisols of the humid tropical Western Ghats, India

The high altitude ferruginous Alfisols associated spatially with shrink–swell soils on the Deccan basalt plateau and dissected table lands in the Western Ghats of India were analysed for their morphological, chemical and mineralogical properties with a view to comprehend their formation and persistence in the tropical humid climate prevailing since the early Tertiary. The study indicates that despite their acidic pH the soils have high bases and their clay fractions are dominated by interstratified smectite-kaolin. The persistence of these non-kaolinitic and/or non-oxidic Alfisols has been possible due to the presence of base-rich zeolites of amygdoloidal basalt. It suggests that for an open system such as soil, the existence of steady state is a more meaningful concept than thermodynamic equilibrium. The knowledge gained on the role of zeolites in soils provides a check on the reasoning of models on the formation of soils in tropical humid climate. The study also indicates that the supply of bases from zeolites can prevent the soils from losing their productivity even in intense leaching environment.     

Residual Effect of Long Term Application of Organic and Mineral Fertilizers on Selected Chemical Properties of a Savanna Alfisol

The residual effect of organic and mineral fertilizers on selected chemical properties of an Alfisol in the long term soil fertility trial established in 1950 at Samaru, Nigerian savanna was assessed. The trial was left fallow for fourteen years due to lack of funds. Topsoil was collected from plots that received three levels of cow dung （D）, nitrogen （N） and phosphorus （P） in all possible combinations. The soils were analyzed for selected chemical properties. Except for significant effect of applied P on available P, sole application of cow dung, N or P had no significant effect on all the measured soil properties. The interaction of D and P significantly affected the mean values of exchangeable Ca, Mg, K and ECEC in the range of 1.12-1.96, 0.62-1.11, 0.37-0.64 and 2.82-4.11 cmol/kg respectively. The most important results were the ability of the plot that received neither D nor P to significantly increase these parameters than the plots that received only one of the treatments. The results show that the fallow period has changed the effects of application of organic and mineral fertilizers on the soil chemical properties under continuous cultivation by modifying them towards those of a native savanna Alfisol.