| 化学改性提高木质素水溶性及其对Zn2+的络合能力 |
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| 引用本文： | 曹胜磊,耿增超,王月玲,尚杰,孙润仓.化学改性提高木质素水溶性及其对Zn2+的络合能力[J].农业环境科学学报,2016,35(11):2216-2223. |
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| 作者姓名： | 曹胜磊 耿增超 王月玲 尚杰 孙润仓 |
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| 作者单位： | 1. 西北农林科技大学资源环境学院,陕西 杨凌,712100;2. 陕西省土地工程建设集团，陕西地建土地工程技术研究院，西安 710075;3. 北京林业大学材料科学与技术学院,北京,100083 |
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| 基金项目： | 国家自然科学基金项目(31430092，31110103902) |
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| 摘 要： | 以生物炼制并通过酸沉淀获得的玉米芯工业碱木质素(L)为原料,经过酚化(PL)及酚化+羟甲基化(HPL)两种前处理,增加反应活性位点,再分别对前处理产物PL和HPL进行羧甲基化改性得到CMPL和CMHPL。以期通过化学改性增强木质素水溶性和对Zn~(2+)的络合能力,从而使改性木质素具有作为水溶性螯合微肥施用的价值,进一步运用红外、热重、荧光显微镜、元素、电位滴定分析方法对木质素和改性木质素的结构及化学性质进行了探究,结果表明:通过酚化和羟甲基化两步前处理再经羧甲基化改性可以显著提高木质素的水溶性和对Zn~(2+)的络合能力。
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| 关 键 词： | 木质素 酚化 羟甲基化 羧甲基化 螯合剂 |
| 收稿时间： | 5/7/2016 12:00:00 AM |
Modification of lignin for improvement it's water-soluble property and ability to complex with Zn2+ |
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| CAO Sheng-lei,GENG Zeng-chao,WANG Yue-ling,SANG Jie and SUN Run-cang.Modification of lignin for improvement it''s water-soluble property and ability to complex with Zn2+[J].Journal of Agro-Environment Science( J. Agro-Environ. Sci.),2016,35(11):2216-2223. |
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| Authors: | CAO Sheng-lei GENG Zeng-chao WANG Yue-ling SANG Jie and SUN Run-cang |
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| Institution: | College of Resources and Environment, Northwest A & F University, Yangling 712100, China,College of Resources and Environment, Northwest A & F University, Yangling 712100, China,College of Resources and Environment, Northwest A & F University, Yangling 712100, China,Shaanxi Land Construction Group, Shaanxi Construction Land Engineering Technology Institute, Xi''an 710075, China and College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, China |
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| Abstract: | In this study, corn cob lignin(L) from biorefining followed by acid precipitation was pretreated to increase the reaction activity sites. Lignin was modified by phenolation to obtain PL and further treatment by hydroxymethylation to obtain HPL. Then the acquired PL and HPL were modified through carboxymethylation to synthesize CMPL and CMHPL, respectively. L, PL, HPL, CMPL and CMHPL were further characterized by FTIR and elemental analyses, and L and CMHPL were determined by thermogravimetric analysis. The microscopic states of L, CMPL and CMHPL dispersed in water were observed by using a fluorescence microscope. The acid-base properties and the complexation phenomenon between lignins and Zn2+ were further analyzed by using a potentiometric titrator. Results showed that CMHPL had the best water-soluble property and the strongest ability to complex with Zn2+. |
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| Keywords: | lignin phenolation hydroxymethylation carboxymethylation chelating agent |
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