液压液用聚醚研究

Polyethers is one of the main components of water-glycol-base non-inflammble hydraulic fluid. This paper describes an optimized technique synthesizing polyether from ethylene oxide and epoxypropane. The synthetic polyethers meets the technical requirement     

Effect of the Silicic Acid Polymerization Degree on the Coagulating Property of Polyalumium Silicate Chloride

Polyaluminum silicate is a new type of inorganic macromolecular flocculants, which is developed as a complex product in recent years on the base of polyalumium flocculant and polysilicic acid flocculant. Sodium silicate is diluted to the concentration of 3.0% SiO 2 with distilled water. The solution was adjusted to pH 4.5 with sulphate acid and kept at quiescency for different time to get polysilicic acid with different polymerization degrees. Using polysilicic acid prepared and aluminium chloride as materials, a series of polyaluminium silicate chlorides(PASC) with different basicities(B), Al/Si molar ratios and polymerization degree of silicic acid are prepared by copolymerization technique. The Al-Ferron timed complex colorimetric method is applied to characterize species distribution of PASC and to study its influence factors. The interaction between hydrolyzed aluminum species and polysilicic acid with different polymerization degrees in PASC is discussed.The flocculant prepared is applied to the treatment of commercial concrete wastewater. The turbidity removal of commercial concrete wastewater is up to 97% when a PASC, prepared with polysilicic acid of 145 min polymerization degree.     

Dynamics of Actin Polymerization

The process of actin polymerization and depolymerization have some relation with its function,the activation of such process is compatible to its functions. The polymerization progress is divided into four steps: The first step is the activation of the monomer actin. The nucleation of actin nucleus forms in the second step which limits the polymerization speed. The elongation of the F-actin filaments happens in the following step. In the last step, a steady-state is attained, the length of the filament does not change because the polymerizing rate in the barbed end is the same with the depolymerizing rate in the pointed end. Some factors which affect the polymerizing process, such as nucleotide, actin related proteins are discussed. The aim is to know more about how to assemble the complicated system with biomacromolecule and what to function.     

分散、乳化条件及成囊工艺对二甲戊灵微 胶囊形成状态的影响

研究了分散、乳化条件及成囊工艺对以脲醛树脂为壁材采用原位聚合法制备二甲戊灵微胶囊状态的影响。讨论了不同乳化剂及其配比、不同分散乳化时间、搅拌速度、酸化时间和固化温度对微胶囊包封率、粒径大小及分布情况的影响,最终确定以聚丙烯酸钠(PAAS)和苯乙烯-马来酸酐(SMA)按4∶ 1(质量比)混合作乳化剂,1 500 r/min搅拌,分散乳化60 min,酸化90 min,50℃固化90 min作为制备二甲戊灵微胶囊的优化工艺条件。在此条件下可以得到平均粒径10 μm左右、粒度分布均匀的球形微胶囊,包封率在99％以上。     

等离子体聚合法制备聚二乙胺

以二乙胺为单体，采用等离子聚合法，在盖破片等基片上制得了稳定性和附着性均好的聚二乙胺膜，考察了聚合工艺参数对聚合物性状及表现形貌的影响，红外光谱与元素分析结果表明聚合膜的结构具有高度支化与交联特征，且聚合膜中有－ＮＨ２和（或）＝ＮＨ基团。     

疏水缔合阳离子淀粉的合成研究

本研究以环己烷为连续相,Span 80/Tween 80为分散剂,采用氧化还原引发体系,通过反相悬浮聚合技术,合成疏水缔合阳离子淀粉接枝共聚物。研究了反应温度,引发剂用量,反应时间对接枝性能的影响及溶解性能。并用IR、X衍射对共聚物进行了表征。结果表明:采用氧化还原引发剂可使聚合反应低温快速进行,在m(St)∶m(AM)∶m(DMDACC)∶m(OA)为4∶7.4∶1.5∶0.6时,引发剂用量3.1 mmol/L,30℃反应3 h,单体转化率92.6%,接枝率53.8%,粘均相对分子质量(MV)3.26×106。     

魔芋葡甘聚糖接枝共聚物的合成及其抗菌活性

考察了一种实验室自制的魔芋葡甘聚糖季铵盐衍生物(KGM-g-DMAE-BC)的合成以及抗菌性能。正交试验优选出的最佳合成条件为:反应温度70℃,单体质量比(mKGM∶mDMAE-BC)1∶5,引发剂用量0.7 mmol/L,反应时间3 h。悬菌定量实验结果表明:KGM-g-DMAE-BC(接枝率为38.5%)对大肠杆菌、金黄色葡萄球菌及白色念珠菌有较强的杀菌作用,在振荡作用15 m in后,平均灭杀率分别为99.99%、94.26%和99.99%。     

Antiproliferative activity of Goldfussia psilostachys ethanolic extract on K562 leukemia cells

A dose-dependent and significant (P<0.01) antiproliferative effect of Goldfussia psilostachys ethanolic extract was observed on K562 cells. The IC(50) is ca. 0.5 microg/ml. The extract markedly increases the proportion of cell in G2/M phases and decreases the population of cells in G0/G1 phases. Moreover, the antimitotic effect is correlated with polymerization of microtubule assembly. These results indicate that G. psilostachys ethanolic extract inhibits the proliferation of K562 cells and disrupts the normal dynamic of microtubules during mitosis.     

聚磷酸铵对砖红壤和石灰性土壤上磷素吸附解吸行为的影响

以砖红壤和石灰性土壤为供试土壤,探索不同聚磷酸铵(APP)对土壤中磷吸附解吸的影响,为评价磷的有效性提供数据参考。在等磷等氮条件下,分别以APP1(以中聚为主)、APP2(以低聚为主)、APP3(聚合度分布均匀且高聚含量高)、MAP(磷酸一铵)、A-M(APP3和MAP以P₂O₅质量比1∶1的比例混合)、CK(空白对照)为供试材料,设置6个处理(各处理名同所用材料),在砖红壤和石灰性土壤上进行50 d的培养,测定各处理下磷的吸附解吸特性。结果显示,在石灰性土壤和砖红壤上,朗缪尔(Langmuir)方程、弗罗因德利希(Freundlich)方程和Temkin方程均可很好地拟合土壤中磷的等温吸附特征,且以Freundlich方程的拟合效果最好(相关系数在0.86~0.98)。在石灰性土壤上,除CK外,以APP1处理下土壤对磷的吸附性最强,A-M处理下土壤对磷的吸附性最弱,磷解吸量最大,磷解吸率最高;在砖红壤上,除CK外,以APP1处理下土壤对磷的吸附性最强,APP2处理下土壤对磷的吸附性最弱,磷解吸量最大,磷解吸率最高。结果表明,聚合度分布均匀且高聚含量高的APP配施MAP可减少石灰性土壤对磷的吸附,提高磷的有效性;而以低聚为主的APP可减少砖红壤对磷的吸附,保持土壤磷的平衡和供磷能力。     

蒙脱土改性尿素醛肥料的制备及性能研究

【目的】研制氮缓释性能优异且制备工艺简单的缓控释肥料。【方法】采用溶液聚合法将具有纳米层状结构的蒙脱土(MMT)穿插在含有营养元素的聚合物缓释肥料尿素醛(UF)中,制备得到一种具有插层结构的新型生物降解高分子缓控释肥料。采用FTIR、XRD对制备肥料的结构进行表征,通过SEM观察肥料的表面形貌,研究原料配比对肥料加工性能的影响,测定肥料在静水中的释放特性。【结果】随着MMT的加入,制备的缓控释肥料的动态流变性能得到极大提升;其对氮具有优异的缓释效果,在静水中培养70 d,氮的最大累积释放率为38.79%,表明通过破坏结晶性聚合物原有的晶体结构可以提高其缓释性能。【结论】研究结果对于解决目前使用最普遍的化学合成型缓释化肥尿素醛由于高结晶度而导致的缓释性能差的问题具有参考意义。