The productivity of grassland farms in seven climatic zones of England and Wales

Records of grassland productivity were kept for 2 years on 152 dairy and 179 beef farms. Results were collated for six lowland zones, delineated primarily on the basis of average rainfall, and an upland zone. Contemporary and long-term average meteorological records were also collected.
In most of the lowland zones stocking rates and use of fertilizer N were similar, but utilized metabolizable energy (UME) output from grass varied; it was 25% higher in the wet, cool zone of north-west England and east Wales than in the dry zone of eastern England. The ranking of zones for utilized output corresponded closely with the ranking for summer rainfall.
On upland farms stocking rate was 25% lower and UME output 15% lower than on lowland farms, but this was achieved from little more than half the N input.
The differences between zones were similar to those shown in other published farm data. They also showed a similar trend to that demonstrated in grass cutting experiments. This suggests that farmers were, on average, able to exploit the extra grass grown in wetter climates. The incidence of difficult topography and impeded drainage was similar in dry and wet zones, but did have a more serious effect in the wet zones. The much higher level of concentrate feeding in the driest zone may have reduced the utilization of grass.     

South-west England grassland survey 1983. 2. Trends in cropping pattern, reseeding and sward composition 1970–83

Seventy-eight farms in south-west England, originally visited in 1970–72, were revisited in 1983 in order to identify changes in land use and re-seeding over the c. 12-year period; changes in sward composition were assessed on fifty-nine of these farms. The results were also compared with Ministry of Agriculture, Fisheries and Food (MAFF) Census results and MAFF Seeds Branch data.
The proportion of tillage had declined from 29 to 24%. This was in agreement with census results for the south-western counties, but contrasted with those for England and Wales as a whole, which showed an increase from 38.8 to 41.7% tillage. It is indicative of grass becoming more predominant in south-west England as east England has become more dominated by tillage cropping.
There had also been a decline in the amount of short-term grassland. In 1970–72 17% of the grassland was intended to last from 1 to 4 years; in 1983 the proportion was only 10%. That these intentions were being carried out was confirmed by the fact that in 1983 there was more grassland in each of the age categories 5·8,9·20 and over 20 years. The trend towards older grassland confirms that shown by regional and national census data, and the trend away from short-term swards is in line with deliveries of herbage seed which indicate reduced use of Italian ryegrass (Lolium multiflorum).
Botanical composition had changed appreciably, with the proportion of Lolium perenne having increased in swards of all ages, e.g. from 35 to 51% in swards 5–8 years old and from 17 to 31% in those aged over 20 years. Other sown species, predominantly Dactylis glomerata and Phleum pratense , had declined markedly in swards over 4 years old. The proportions of Agrostis spp., Festuca spp. and Poa trivialis had fallen, but Holcus lanatus had increased slightly. There had been a marked reduction in infestations of perennial broad-leaved weeds, particularly Ranunculus , but also Rumex and Cirsium spp.     

Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores

Use of amphiphilic triblock copolymers to direct the organization of polymerizing silica species has resulted in the preparation of well-ordered hexagonal mesoporous silica structures (SBA-15) with uniform pore sizes up to approximately 300 angstroms. The SBA-15 materials are synthesized in acidic media to produce highly ordered, two-dimensional hexagonal (space group p6mm) silica-block copolymer mesophases. Calcination at 500 degrees C gives porous structures with unusually large interlattice d spacings of 74.5 to 320 angstroms between the (100) planes, pore sizes from 46 to 300 angstroms, pore volume fractions up to 0.85, and silica wall thicknesses of 31 to 64 angstroms. SBA-15 can be readily prepared over a wide range of uniform pore sizes and pore wall thicknesses at low temperature (35 degrees to 80 degrees C), using a variety of poly(alkylene oxide) triblock copolymers and by the addition of cosolvent organic molecules. The block copolymer species can be recovered for reuse by solvent extraction with ethanol or removed by heating at 140 degrees C for 3 hours, in both cases, yielding a product that is thermally stable in boiling water.     

Herbage growth and utilized output from grassland on dairy farms in southwest England: case studies of five farms, 1982 and 1983. I. Herhage growth

Herbage growth was measured in two contrasting years on five farms representing a range of soil types. On fields cut for conservation in 1982 DM production varied between farms from 12.3 tha^-1 to 14.1 tha^-1 in line with fertilizer N levels, which ranged from 220 to 333 kg ha^-1. In 1983 production was from 10.3 tha^-1 to 12.3 tha^-1; this again corresponded with fertilizer N, except on farm B which had the shallowest soils. On fields used for grazing all farmers used rotational management. Herbage accumulation was measured by trimming to 25 mm and harvesting after 4 weeks. As on conservation fields, herbage accumulation was generally greater on farms using more N, at least up to 300 kg ha-1.
In 1982 growth consistently exceeded predictions based on plot experiments. In 1983 growth was on average less than predicted on grazing fields but slightly more than predicted on cutting fields-We conclude that such predictions of annual production are a valuable aid to farm planning, and need not be reduced to allow for on-farm conditions, although they are least good at low levels of N. Predictions of individual cuts were not satisfactory, with a strong tendency to overestimate first cut and underestimate second cut.
There was no indication that annual herbage production was less on badly drained than on well drained soils. Indeed, in the dry summer of 1983 badly drained land appeared to have an advantage, despite considerable poaching damage in the spring. Furthermore, there was no evidence that production was deficient on swards dominated by Holcus and Agrostis spp.     

Herbage growth and utilized output from grassland on dairy farms in southwest England: case studies of five farms, 1982 and 1983. II. Herbage utilization

Utilized Metabolizable Energy output was calculated and herbage utilization evaluated in two contrasting years on five profitable farms representing a range of soil types.
Annual UME output was 72 GJ ha^-1 on average, with a range from 47 to 91 GJ ha^-1. Grazed grass provided 66% of the utilized metabolizable energy, and conserved grass 34%. Higher utilized metabolizable energy output was not always obtained at higher fertilizer N inputs, even when soil moisture conditions favoured herbage growth.
The efficiency of utilization of herbage conserved (almost always as silage rather than hay) was calculated by expressing utilized metabolizable energy output as a proportion of the quantity of herbage cut, measured by swath weighings; the mean value was 64%, with a range from 55 to 73%. Cellulose analyses indicated that mean dry matter losses via CO₂ and effluent were 10%; the remaining 26% loss appeared to be due to physical losses in the field, surface waste and wastage at feedout.
For grazed herbage the utilized metabolizable energy output was expressed as a proportion of herbage accumulation measured over 28-day periods. The resultant apparent efficiency of utilization averaged 67%, with a wide range from 51 to 83%. The lowest values were on badly drained farms.
It is suggested that:
(i) there is considerable potential for increasing output from grazing on dairy farms; higher grazing pressure and more flexible management would be needed. Targets should probably be set lower on badly drained soils;
(ii) there is great potential for increasing the efficiency of utilization of conserved forage, by careful application of existing technology;
(iii) on the farms studied the utilized metabolizable energy output from grazed and conserved fields appeared to be similar.     

Hierarchically ordered oxides

Porous silica, niobia, and titania with three-dimensional structures patterned over multiple length scales were prepared by combining micromolding, polystyrene sphere templating, and cooperative assembly of inorganic sol-gel species with amphiphilic triblock copolymers. The resulting materials show hierarchical ordering over several discrete and tunable length scales ranging from 10 nanometers to several micrometers. The respective ordered structures can be independently modified by choosing different mold patterns, latex spheres, and block copolymers. The examples presented demonstrate the compositional and structural diversities that are possible with this simple approach.