Assessment of potassium speciation in soil using traditional single leaching and modified sequential extraction processes

Purpose

The bioavailability of potassium (K) depends on its speciation distribution in the soil. Different methods are commonly used to estimate K speciation including traditional single leaching (TSL) and sequential extraction process (SEP). However, K speciation is largely affected by soil pretreatment methods. The effects of both TSL and SEP soil pretreatment methods were evaluated.

Materials and methods

The TSL method classifies K speciation content based on bioavailability, while the SEP classifies the metal speciation based on the effects of environmental conditions. These two methods, together with a modified sequential single leaching (SSL) scheme, were used to evaluate five types of soil including soil without potassium fertilization, soil with long-term K fertilization, alkaline soil, red soil, and forest soil. The soil samples were gathered randomly at depths varying up to 30 cm before being dried in air at room temperature. The samples were then ground and mixed before passing through a sieve (10 mesh or 100 mesh) in order to perform K speciation analysis via the modified SSL technique, the TSL method, and the four schemes of SEP.

Results and discussion

Soil pretreatment influenced K speciation, with higher concentration in soil samples sieved through 100 mesh than through 10 mesh. In alkaline soil, potassium was observed to be associated with carbonate. For the various SEP schemes, K speciation was found to be greatest in the residual fraction, with only 3% observed in the carbonate, exchangeable, metal organic complex, or amorphous hydroxides of Fe or Mn. After following the first two steps of the SEP schemes, the available K was similar to that of the TSL method. Distribution of non-exchangeable K using the TSL method was comparable with the five combined SEP extraction steps which were all affected by environmental conditions.

Conclusions

Pretreatment affected K speciation distribution and total amount of metal in the soil. The 100 mesh sieve was more effective in estimating K soil speciation. The SEP method was acceptable for estimating K speciation, with the Krishnamurti et al. (Analyst 120:659–665, 1995) scheme as a useful appraisal of K bioavailability. Combination analyses using both TSL and SEP methods are useful techniques to enable a better understanding of K speciation transformation in soil.

     

Determination of the magnitudes and values for groundwater recharge from Taiwan's paddy field

Flooded paddy fields have many functions, including not only rice production, and ecological and environmental conservation. This work estimates the extent of paddy field infiltration in Taiwan by adopting a one-dimensional Darcy-based soil/water balance model SAWAH (Simulation Algorithm for Water Flow in Aquatic Habitats). A 10 cm thick plow sole layer with a hydraulic conductivity of 0.03 cm/day, coupled with the soil texture and irrigation data obtained from 15 irrigation associations, is used to estimate the volumetric amount of annual infiltration in Taiwan. Simulation results from SAWAH indicate that the plow sole layer controls the movement of infiltrated water, with a rate about 1.8 billion cubic meters annually. The estimated infiltration rate of 1.8 billion m³/yr comprises more than 40% of the annual infiltration recharge to ground water in Taiwan. Additionally, the amount of infiltration recharge to groundwater is equivalent to 20 billion Taiwan dollars NT$ (or 0.65 billion US$) while the yearly rice crop production is 35 billion NT$ (or 1.13 billion US$). It is evident that the infiltration from rice paddy is of great importance to the economy, environment, and water resources conservation in Taiwan.