基于水盐平衡的绿洲灌区次生盐碱化防治研究

土壤次生盐碱化是威胁新疆绿洲灌区持续发展的关键因子。以位于塔里木河流域的渭干河灌区为例,在简要分析灌区水盐运移的控制因素基础上,以水盐均衡原理为指导,深入剖析了灌区-田块-作物根系3个尺度的土地盐分均衡特点及其相互关系,重点估算了淋洗需水量,简要讨论了次生盐碱化的驱动因子,最后从政策、技术与经济方面给出了控制次生盐碱化的对策。     

噻虫嗪在农田土壤中环境行为的研究进展

噻虫嗪是当前全球销售量最大的新烟碱类农药之一，随着噻虫嗪的广泛使用，噻虫嗪在土壤环境中的迁移转化和归宿问题成为研究热点。本文总结了噻虫嗪对陆生生物（蜜蜂、蚕、蚯蚓、鹌鹑）、水生生物（藻类、大型溞、斑马鱼等）以及土壤微生物的影响，系统综述了噻虫嗪在农田土壤中的残留、降解、吸附解析以及迁移与淋溶等环境行为及主要影响因素，并指出了噻虫嗪在农田土壤中环境行为相关研究存在的不足以及未来研究应该关注的重点和方向，以期为噻虫嗪的科学安全使用以及保障农田土壤生态环境健康提供科学依据。     

Critical drainage and nitrate leaching losses from manures applied to freely draining soils in Great Britain

Abstract. Pig slurry was applied by open-slot injection to experimental plots on a sandy loam site at ADAS Gleadthorpe, Nottinghamshire. Volume and distribution of over-winter drainage were adjusted through the use of rainfall exclusion covers or irrigation. The resultant slurry N leaching over the range of drainage values tested (up to 300 mm) could be satisfactorily described by curve-fitting, using a quadratic or exponential function. Initial simulations of slurry N leaching using the manure nitrogen decision support system manner (v. 3.0) compared poorly with the experimental data, predicting both earlier and greater amounts of nitrate leaching. However, the lack of fit could be explained by consideration of the likely ammonia emissions following slurry injection, the actual volumetric soil moisture capacity at the experimental site and the likely time delay for the nitrification of slurry N following application. Good agreement between modelled and observed data was achieved when these factors were taken into account. The manner model was used to simulate nitrate leaching beyond the range of drainage treatments tested in the experiments and the anticipated sigmoidal relationship between nitrate leaching and drainage was observed. The model was then used to study the effects of manure application timing and the likely impact on nitrate leaching, across the range of rainfall conditions found in Great Britain. Simulations for a range of manure types were undertaken, with manures applied at rates up to the limit of permitted N loading on freely draining sandy loams. Rainfall inputs for these simulations were based on long-term average climatic data. Results are presented for two contrasting manure types, cattle slurry and poultry manure, both of which are subject to controls in Nitrate Vulnerable Zones (NVZs) in Great Britain.     

On-site remediation of chromium-contaminated sediments by combination of sediment washing and stabilization with magnesium oxide/limestone mixtures

Goal, Scope and Background  The remediation of heavy-metalcontaminated soils and sediments is of significant value to industrial areas around the world. The spread of such pollutants can result in a potential risk of entering the groundwater system and being transported to potential receptors. Leaching techniques can be an effective treatment option for the metal removal from soils and sediments. This approach consists of washing or leaching the contaminated soil with an appropriate reagent and the subsequent treatment of the leaching in an above-ground installation (on-site treatment) where metals can be removed and concentrated into a smaller volume. Among the heavy metals, chromium is a commonly identified soil contaminant, particularly in sites with intensive economic activities including agriculture, industrial, mining and mineral,processing. Objective  The objective of this work was the evaluation and development of a leaching process for the remediation of soils and sediments polluted with chromium at laboratory scale. Chromium soil pollution was generated after the breakdown of a channel containing chromium wastes from a tannery plant. The pollution extension has been estimated to be on the order of thousands of tonnes of soil to be treated, with chromium contents ranging from 500 to 17,000 mg kg^-1 soil. Methods  The whole process investigated in this study integrates three stages; a) chromium leaching from a sediment using a diluted sulphuric acid solution, b) treatment of the leaching effluents with a magnesium oxide/limestone mixture for the precipitation of chromium hydroxide after acidity neutralisation, and c) polishing step to remove the eventual remaining chromium by adsorption onto natural zeolite. The amount of contaminated sediment treated ranged from 0.5 to 2 kg with chromium contents of between 2000 and 17,000 mg kg^-1. Results and Discussion  The paper describes results on the performance of the process and the optimisation of steps including influence of acid sulphuric concentration, chromium removal efficiency as well as alkaline reactive mixture proportions. Effluents from the leaching cells showed a significant decay on the chromium concentration with the increase of leaching runs and a high content of acidity (pH values close to 0.5). The treatment of these effluents in a second cell containing magnesium oxide/ limestone mixtures resulted in a high efficiency in neutralisation of acidity (pH values around 7) and chromium removal (concentrations below 5 mg 1^-1). The passage through a third compartment containing zeolite as an adsorbent decreased the chromium concentration below 0.5 mg 1^-1, Conclusions  From the results obtained on the chromium leaching and immobilisation with magnesium oxide/limestone mixture at a laboratory scale, it could be pointed out that: (a) diluted sulphuric acid solutions (3%) demonstrated a high efficiency on chromium removal from sandy polluted soils on the kilogram scale, (b) mixtures of magnesium oxide/limestone demonstrated a high capacity to neutralise the residual high acidity present on the effluents and to remove chromium by precipitation and (c) between the limestone and caustic magnesia mixtures, those containing more than 60% of caustic magnesia provide the higher efficiency. Recommendation and Outlook  Future work would be directed to the evaluation of the integrated process of leaching and chromium precipitation on column at a scale of 100 to 1000 kg.     

The effects of crop husbandry and nitrogen fertilizer on nitrate leaching from a shallow limestone soil growing a five course combinable crop rotation

Abstract. Nitrogen (N) leaching losses from a shallow limestone soil growing a five course combinable croprotation (oilseed rape, wheat, peas, wheat, barley) were measured from 1990 until 1995 using porous ceramic cups, at 60 cm depth, and drainage estimates. The crops were grown with three husbandry systems and two levels of N fertilizer. The husbandry systems were designed to reflect local practice (Standard), the best possible techniques to reduce N loss (Protective) and an Intermediate system which was a compromise between the two. Nitrogen was applied at full and half recommended rates. Drainage started during September in four years and November in one year, with above average drainage in three years. Losses of N were largest after peas (58 kg/ha) and oilseed rape (42 kg/ha), and least (17 kg/ha) before peas sown in spring after a cover crop. Over five years, the Protective management system, which used early sowing and shallow cultivation wherever possible, lost least N (31 kg/ha/y) and the Standard system, with conventional drilling dates and ploughing as the primary cultivation, lost most (49 kg/ha/y). Halving the N fertilizer decreased N loss by 11 kg/ha/y, averaged over the rotation. None of the treatments gave mean drainage water nitrate concentrations of less than 50 mg/l, averaged over the five years. Changes to arable cropping alone will not eliminate the need for other measures to control nitrate concen-trations in public drinking water supplies.     

下辽河平原潮棕壤稻田的无机态氮淋溶

应用陶土渗滤管法．研究了不同施氮和渗漏条件下潮棕壤稻田的氮淋溶损失。结果表明：稻季各次施用氮肥后，60cm和90cm深处渗漏液中NH4^＋-N含量都小于2mg／L。并且各施氮肥处理和对照间差别不显著；但硝酸盐淋溶比较显著，多集中在3～15mg／L之间。硝酸盐淋溶随施氮量增加而增加，90cm深度渗漏液中这一趋势更为明显。水分渗漏状况影响硝酸盐在不同土层深度的累积：渗水越快。硝酸盐淋溶深度越大。渗水较快或者施氮量高时，硝酸盐的淋溶浓度高于国际饮用水卫生标准10mg／L。施用基肥后灌水．NH4^＋ -N、NO3^- -N立即出现高峰．而施用分蘖肥和穗肥后，高峰出现在施肥后10d或更久；另处基肥时期淋溶氮的浓度也比较高。     

田林老山中山杉木人工林生产力及营养元素循环的研究

广西田林县老山林场中山区气候冷凉潮湿,土壤肥力较高,能满足杉木速生要求。17年生杉木人工林乔木层的生物量达138.46t/ha,平均净生产量为8.15t/ha·a,与杉木中心产区相当。乔木层对N,P,K,Ca,Mg5种营养元素的吸收量为224.04kg/ha·a,其中42.3％存留在林木层,42.5％通过凋落物,15.2％通过降雨淋洗归还土壤。通过凋落物归还是N,P,Ca,Mg归还的主要途径,K的归还主要通过降雨淋洗;K,Ca,Mg的循环系数较大,分别达到0.58,0.68和0.60;N,P相对较小,分别为0.48和0.33。林木正处于生长旺盛阶段,杉木对5种营养元素的吸收量、存留量和归还量以及循环系数都有较高水平,生物量积累也较大。     

In situ net N transformations in pine,fir, and oak stands of different ages on acid sandy soil, 3 years after liming

Summary The effect of liming on in-situ N transformations was studied in two stands of different ages of each of Scots pine (Pinus sylvestris L.), Douglas fir [Pseudotsuga menziesii (Mirb.) Franco], and common oak (Quercus robur L.). The stands were located on acid sandy soils in an area with high atmospheric N input. The organic matter of the upper 10-cm layer of the soil, including the forest floor, had a relatively high N content (C: N ratio <25) in all stands. Using a sequential core technique, N transformations were measured in both control plots and plots that had been limed 3 years previously with 3 t ha^-1 of dolomitic lime. Limed plots had a higher net NO _inf3 ^sup- production and a higher potential for NO _inf3 ^sup- leaching than the controls in all stands except that of the younger oak. Net N mineralization did not differ significantly between limed and control plots in oak stands and younger coniferous stands but was significantly lower in the limed plots of the older coniferous stands. It is concluded that long-term measurements of net N mineralization in limed forest soils are needed to evaluate the effect of liming with respect to the risk of groundwater pollution.     

The effect of precipitation and application rate on dicyandiamide persistence and efficiency in two Irish grassland soils

The nitrification inhibitor dicyandiamide (DCD) has had variable success in reducing nitrate () leaching and nitrous oxide (N₂O) emissions from soils receiving nitrogen (N) fertilizers. Factors such as soil type, temperature and moisture have been linked to the variable efficacy of DCD. As DCD is water soluble, it can be leached from the rooting zone where it is intended to inhibit nitrification. Intact soil columns (15 cm diameter by 35 cm long) were taken from luvic gleysol and haplic cambisol grassland sites and placed in growth chambers. DCD was applied at 15 or 30 kg DCD/ha, with high or low precipitation. Leaching of DCD, mineral N and the residual soil DCD concentrations were determined over 8 weeks high precipitation increased DCD in leachate and decreased recovery in soil. A soil × DCD rate interaction was detected for the DCD unaccounted (proxy for degraded DCD). In the cambisol, degradation of DCD was high (circa 81%) and unaffected by DCD rate. In contrast, DCD degradation in the gleysol was lower and differentially affected by rate, 67 and 46% for the 15 and 30 kg/ha treatments, respectively. Variation in DCD degradation rates between soils may be related to differences in organic matter content and associated microbiological activity. Variable degradation rates of DCD in soil, unrelated to temperature or moisture, may contribute to changing DCD efficacy. Soil properties should be considered when tailoring DCD strategies for improving nitrogen use efficiency and crop yields, through the reduction of reactive nitrogen loss.     

不同施氮量对夏玉米产量、氮肥利用率及氮平衡的影响

通过田间小区试验研究了不同施氮量对夏玉米产量、氮肥利用率、硝酸盐淋溶及氮平衡的影响。结果表明,施氮对夏玉米子粒有显著的增产作用,但随施氮量的增加产量变化不大。氮肥利用率在9.2%~22.6%之间,随施氮量的增加而降低。施氮可明显提高0~160 cm剖面土壤NO3--N含量,而且随深度的增加NO3--N含量呈降低趋势,累积峰主要在20~60 cm之间。玉米收获后,随着施氮量的增加氮素的损失量增加,各施氮处理的硝态氮残留量在121~221 kg/hm2之间,以N250处理的残留量最高,残留率近65%。