杉木间伐材ACQ防腐与综合强化复合改性研究

在将ACQ与UF树脂调制成相容的复合改性剂对杉木间伐材进行复合改性研究的基础上,深入探索复合改性的机理与综合效果.对浸渍材与表面密实化处理相结合的优化工艺,当弦向压缩率为20%时各项力学性能指标均比素材增加51%以上;进行浸渍处理与ACQ或UF单独处理材经煮沸和抗水、酸、碱抽提的抗流失性对比试验及防腐试验,表明前者比后者有所提高;并采用铜离子跟踪法进行X-射线荧光光谱仪定量分析,测定了浸渍材复合改性剂的含量和分布情况,确认了一次性浸渍优化工艺参数的较佳效果.     

青麸杨复叶类型与肚倍产量关系的初步研究

通过对青麸杨（ＲｈｕｓｐｏｔａｎｉｎｉｉＭａｘｉｍ）四种类型复叶上挂倍数目、位置及肚倍鲜重的研究得知：在各类型复叶中，每片复对上挂１个肚倍的产量极显著高于挂２、３、４个的。在每片更叶上只挂１个肚倍的情况下，小叶数为１３片和１１片的两种复叶类型的产量极显著高于小叶数为９片和７片的产量；而肚倍挂在复叶的左边和右边的小叶上与肚倍的产量差异不显著。     

农林复合模式研究与进展

文章对农林复合经营模式的发展历史、经营类型进行了概述，对其系统结构、生物物种设计原则、生态、经济、社会效益以及今后研究的重点进行了探讨，为农林复合经营模式在实践中的推广和理论研究的深入进行提供了理论依据。     

Reaction behavior of lignin in supercritical methanol as studied with lignin model compounds

 The reaction behavior and kinetics of lignin model compounds were studied in supercritical methanol with a batch-type supercritical biomass conversion system. Guaiacol, veratrole, 2,6-dimethoxyphenol, and 1,2,3-trimethoxybenzene were used as model compounds for aromatic rings in lignin. In addition, 5-5, β-1, β-O-4, and α-O-4 types of dimeric lignin model compounds were used as representatives of linkages in lignin. As a result, aromatic rings and 5-5 (biphenyl)-type structures were stable in supercritical methanol, and the β-1 linkage was not cleaved in the β-1-type structure but converted rapidly to stilbene. On the other hand, β-ether and α-ether linkages of β-O-4 and α-O-4 lignin model compounds were cleaved rapidly, and these compounds decomposed to some monomeric compounds. Phenolic compounds were found to be more reactive than nonphenolic compounds. These results indicate that cleavages of ether linkages mainly contribute to the depolymerization of lignin, whereas condensed linkages such as the 5-5 and β-1 types are not cleaved in supercritical methanol. Therefore, it is suggested that the supercritical methanol treatment effectively depolymerizes lignin into the lower-molecular-weight products as a methanol-soluble portion mainly by cleavage of the β-ether structure, which is the dominant linkage in lignin. Received: December 19, 2001 / Accepted: April 30, 2002 Acknowledgments This research has been done under the research program for the development of technologies for establishing an ecosystem based on recycling in rural villages for the twenty-first century from the Ministry of Agriculture, Forestry and Fisheries, Japan; by a Grant-in-Aid for Scientific Research (B)(2) (no.12460144, 2001.4–2003.3) from the Ministry of Education, Culture, Sports, Science and Technology, Japan; and under the research program from Kansai Research Foundation for Technology Promotion, Japan. The authors thank them for their financial support. This study was presented in part at the 45th Lignin Symposium, Ehime, Japan, October 2000 and the 52nd Annual Meeting of the Japan Wood Research Society, Gifu, Japan, April 2002 Correspondence to:S. Saka     

Reactivity of secondary hydroxyl groups in methylβ-d-xylopyranoside toward aβ-o-4-type quinone methide

Methyl-d-xylopyranoside was allowed to react with-O-4-type quinone methide without a catalyst to elucidate the reactivities of secondary hydroxyl groups at the C2, C3, and C4 positions. Benzyl ether-type lignin-carbohydrate complex (LCC) compounds linked at the C2 and C4 positions were predominant, at a ratio of 23. However, the reactivity of the hydroxyl group at the C3 position was quite low. These results strongly suggest that the reactivity of the C2 hydroxyl group in xylan toward quinone methide intermediate is higher than that of the C3 hydroxyl group during biosynthesis of LCCs.     

三种林木次生物质对星室木虱产卵驱避作用的初步研究

应用柠檬桉(Eucalyptuscitriodora)、樟树(Cinnamomumcamphora)、苦楝(MeliaazedarachL.)等3种植物茎叶的乙醇、丙酮和三氯甲烷的提取物对橄榄星室木虱(PseudophacopteroncanariumYangetLi)成虫产卵的驱避作用进行研究,利用干扰控制指数IIPC进行评价。结果表明,柠檬桉的驱避作用最强,其乙醇、丙酮、三氯甲烷的提取物IIPC分别达0 126、0 209、0 307;樟树次之,分别为0 392、0 298、0 438;苦楝效果较差,只有0 589、0 574、0 638。柠檬桉、樟树的乙醇、丙酮提取物对星室木虱产卵的控制作用达到60%以上,乙醇提取物第4d的持续控制效果为52 7%和50%。     

4种木材常温下醛和萜烯挥发物的释放

利用高效液相色谱仪和气相色谱仪分析4种木材(杉木、杨木、马尾松和尾叶桉)中有机挥发物的成分及含量,结果表明:4种木材生材常温均可释放多种醛和萜烯挥发物,其中乙醛的释放量最高;杉木和杨木释放的醛类明显高于马尾松和尾叶桉;杉木释放的萜烯类明显高于其他3种木材;温度由20 ℃上升到40 ℃,杉木醛类和萜烯类释放量显著增加.     

Comparative effectiveness of two alkylammonium compounds as wood preservatives

This study describes a laboratory evaluation of the efficacy of two alkylammonium compounds [didecyldimethylammonium tetrafluoroborate (DBF) and didecyldimethylammonium chloride (DDAC)] when applied via vacuum impregnation or superficial treatment. Treated wood specimens were tested for their termite and microbial resistance under controlled laboratory conditions. The higher chemical retentions were needed to suppress the feeding by Coptotermes formosanus ≦3% mass loss in the multichoice test than in the no-choice test. The DBF and DDAC retention levels necessary to meet the performance requirement ≦3% mass loss after 12-week fungal exposure varied with wood species. The retention level of 3 kg/m³ for DBF and DDAC was generally high to keep the nondurable wood species free of decay. Although there was no difference between DBF and DDAC in the efficacy against decay and termite attack, the former slightly outperformed the latter as an antimold and antisapstain agent.     

扬州市邗江低湿江滩地林农复合构建模式早期经济效益研究

对江苏省扬州市邗江渔业乡低湿江滩地构建的4类16种林农复合模式的经济效益评估结果表明,意大利杨与菊苣、意大利杨与荩草、意大利杨与苏丹草、意大利杨与银杏苗、意大利杨与棕榈、意大利杨与莲、水杉与药用蚂蝗、水杉与精鱼等8种复合模式是低湿江滩地开发经济效益高的优良构建模式;围网养殖尤其是船带网箱移动养殖长江水特产品是江滩水面资源开发利用的高效特色模式。认为滩地开发应在巩固“八五”绿化滩地,营建抑螺防病林成果的基础上,引进新树种,新种植、养殖优良生物品种,用新技术进行优化配置,以优化现有湿地森林结构,创立体现沿江湿地林渔特色的“多物种、多功能、多效益”人工林系统,建设观光林网,观光渔业,滨江湿地森林生态旅游村,进一步促进江滩湿地资源深度开发及沿江农村经济与社会可持续发展。     

Variations in soil chemical properties and microbial biomass in artificial gaps in silver fir stands

Changes in soil chemical and microbiological parameters in small (185 m²) and medium (410 m²) gaps, created in mature silver fir (Abies alba Mill) stands (mean height 30 m) in the Calabrian Apennines (Southern Italy), were studied over 2 years. Medium gaps had high soil temperature and photosynthetically active radiation (PAR) transmittance and low soil moisture. Within small gaps we detected a greater amount of organic matter, with respect to under canopy cover sites and medium gaps. Moreover, a different trend of the organic matter between small and medium gaps was observed. In the medium gaps, with respect to under canopy cover sites and small gaps, we found a relatively low content of organic matter, associated to a lower amount of humic acid, which suggested that the organic substrate undergoes a mineralization rather than a humification process. An opposite trend was observed in small gaps, where the increase of organic matter content, associated to an increase of humic acid and microbial biomass, suggested a better humification process. Moreover, in small gaps the highest level of urease and the greatest fluorescein diacetate (FDA) hydrolysis were observed. The different trend of organic matter observed in small and medium gaps may be related to changes in the environmental conditions. PAR transmittance, significantly higher in medium gaps, contributed to increase soil temperature and decrease soil moisture, affecting soil microbial populations and organic matter trend. These results suggest that the creation of small gaps represents the silvicultural practice with minor environmental impact.