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51.
The prediction of grain and stover quality parameters in maize {Zea mays L.) by near infra-red reflectance spectroscopy (NIRS) was studied. A total of 110 grain and 135 stover samples originating from different genotypes and environments were assayed. Calibration equations for content of crude protein (CP), crude fat (CF), starch (ST), and water soluble carbohydrates (WSC) in grain were obtained by multiple linear regression of known manual values on NIRS data from the odd numbered samples. Calibrations for CP, acid detergent fibre (ADF), in vitro digestible organic matter according to the Tilley & Terry (IVDOM-T & T) and the gas production (IVDOM-Gp) method, respectively, and metabolizable energy (ME) in stover were developed analogously. Equations were validated with the evennumbered .samples and for ME additionally with the 1584 stover samples from an experiment with 66 F1 hybrids tested in six environments. The coefficients of multiple determination (R2) of the prediction equations ranged from 0.80 for IVDOM-Gp and ME in stover to 0.94 for CP in grain. Standard errors of calibration (SEC) and prediction (SEP) were in most cases not higher than commonly reported for conventional manual assays. With regard to the correct ranking of hybrids, prediction equations for ME applied well to stover samples from other environments with one exception. We concluded that NIRS can evaluate the quality traits investigated to a similar degree to that of conventional methods of analysis. Since NIRS is simple and safe to operate and allows rapid screening of several quality traits simultaneously, it should be particularly attractive for breeding purposes. 相似文献
52.
介绍了人工神经网络的原理、结构、算法和研究进展,以及该方法在近红外光谱分析中的重要地位和应用。 相似文献
53.
傅立叶变换近红外光谱法检测白酒总酸和总酯 总被引:9,自引:0,他引:9
该文研究白酒总酸和总酯的快速检测技术,通过解析不同白酒样品的近红外光谱图,对光谱数据进行不同的处理,结果表明:用一阶导数预处理光谱,谱区选择6102~5446 cm-1,利用人工神经网络与傅立叶变换近红外光谱相结合,采用内部交叉验证法建立模型,效果较好。其中,总酸模型的决定系数为96.73%,内部交叉验证均方根差为0.048 g/L;总酯模型的决定系数为99.58%,内部交叉验证均方根差为0.085 g/L;进一步对总酸和总酯的模型进行验证和评价,结果表明总酸模型验证集的相关系数为99.2%,预测标准偏差为0.074 g/L;总酯模型验证集的相关为99.7%,预测标准偏差为0.134 g/L,表明建立的模型可靠,预测效果好,能满足白酒生产中总酸和总酯的快速检测要求。 相似文献
54.
The backward interval partial least squares (BiPLS) and the synergy interval partial least squares (SiPLS) were applied to select the characteristic spectral regions representing the germination rate of 84 wheat seeds and build the near infrared (NIR) quantitative analysis model of wheat seed germination rate.Results from comparison showed that the models built by two variable selection methods had better predictive ability than full-spectral partial least squares(PLS) model.The optimal model was obtained by SiPLS with the calibration and prediction correlation coefficient(R) at 0.902 and 0.967 respectively, and ratio of performance to standard deviate (RPD) at 3.75.Based on this, the physical chemistry significance of characteristic spectral regions was analyzed.The characteristic spectral of wheat seed germination rate contained characteristic peaks of water, protein, starch, fiber, which were the internal nutrients of the seed that influence the germination ability, thus explaining the mechanism of measuring wheat seed germination rate using NIR to a certain extent. 相似文献
55.
根据野外工作,在地理信息系统和遥感技术的支持下,探讨以防止风蚀为目的的首都圈的范围及主要特征,着重分析首都圈典型地区土地退化的机制、分布状况和防治的季节。结果表明,土地退化的主要原因是近年持续干旱少雨,土地利用的强度过大,以及在干旱季节里没有适当的防护措施等。建议采用适宜于首都圈的封育和垄耕等防治措施。 相似文献
56.
以硬脂酸作为增塑剂,胱氨酸作为交联剂制备具有一定力学性能和良好抗湿性能的大豆分离蛋白复合膜。将膜放在25℃,相对湿度为50%的干燥器中平衡两天,用质构仪测定膜的抗拉强度(TS),延伸率(E(%))。在水分活度aw为0.10~0.90的范围内研究了复合膜在25℃的吸湿特性。吸湿速率和吸湿等温线数据分别拟合到Peleg's 方程和GAB(Guggenheim-Anderson-de Boer)模型。结果表明:大豆蛋白复合膜的TS、延伸率E(%)以及吸湿速率随着硬脂酸和胱氨酸的添加比率显著地变化。硬脂酸和胱氨酸的最佳添加比率为40∶60(w/w)(每升蛋白质溶液中加入10 g混合添加剂),此时,大豆蛋白膜的强度比原来提高2倍,并且有最佳的吸湿速率。吸湿数据和GAB 模型有很高的拟合度,拟合系数最高达0.99。 相似文献
57.
Thomas Terhoeven‐Urselmans Kerstin Michel Mirjam Helfrich Heiner Flessa Bernard Ludwig 《植物养料与土壤学杂志》2006,169(2):168-174
The usefulness and limitations of near‐infrared reflectance spectroscopy (NIRS) for the assessment of several soil characteristics are still not sufficiently explored. The objective of this study was to evaluate the ability of visible and near‐infrared reflectance (VIS‐NIR) spectroscopy to predict the composition of organic matter in soils and litter. Reflectance spectra of the VIS‐NIR region (400–2500 nm) were recorded for 56 soil and litter samples from agricultural and forest sites. Spectra were used to predict general and biological characteristics of the samples as well as the C composition which was measured by 13C‐CPMAS‐NMR spectroscopy. A modified partial least‐square method and cross‐validation were used to develop equations for the different constituents over the whole spectrum (1st to 3rd derivation). Near‐infrared spectroscopy predicted well the C : N ratios, the percentages of O‐alkyl C and alkyl C, the ratio of alkyl C to O‐alkyl C, and the sum of phenolic oxidation products: the ratios of standard deviation of the laboratory results to standard error of cross‐validation (RSC) were greater than 2, the regression coefficients (a) of a linear regression (measured against predicted values) ranged from 0.9 to 1.1, and the correlation coefficients (r) were greater than 0.9. Satisfactorily (0.8 ≤ a ≤ 1.2, r ≥ 0.8, and 1.4 ≤ RSC ≤ 2.0) assessed were the contents of C, N, and production of DOC, the percentages of carbonyl C and aromatic C and the ratio of alkyl C to aromatic C. However, the N‐mineralization rate and the microbial biomass were predicted unsatisfactorily (RSC < 1.4). The good and satisfactory predictions reported above indicate a marked usefulness of NIRS in the assessment of biological and chemical characteristics of soils and litter. 相似文献
58.
近红外光谱技术及其在农产品品质分析中的应用 总被引:1,自引:0,他引:1
庞新安 《广西农业生物科学》2007,26(1):83-87
近红外光谱技术是一种高效、快速的现代分析技术,已在很多领域得到广泛应用。文章对近红外光谱分析的技术原理、技术方法、技术特点作了简要介绍,并对其在农产品品质分析中的应用现状和应用前景进行了综述。 相似文献
59.
酶法改性大豆分离蛋白成膜条件的研究 总被引:1,自引:0,他引:1
以大豆分离蛋白为成膜主料,在一定条件下与交联剂(TG酶)、增塑剂(甘油)等共同作用,制备出可降解具有一定机械强度的大豆分离蛋白膜,可部分替代塑料用于食品包装领域,减少环境污染。结果表明,大豆分离蛋白膜的实验室制膜工艺参数为:质量分数为5.0%的大豆分离蛋白,2.0%的甘油,0.15%的TG酶、pH值8.0。 相似文献
60.
GUO Chao ZHANG Yong-xing LUO Jun-cai ZHOU Zhi-ming ZHANG bo-hu LI Jin-long XIE Wen-ting WU De-jun 《保鲜与加工》2011,(4):106-112
By using near crack line analysis method and Mohr-Coulomb strength criterion,the elastic-plastic solution for near crack line of an eccentric cracks loaded by the pore water pressure under large scale yielding condition is analyzed.The elastic stress fields,the plastic stress field,the unit normal vector of the elastic-plastic boundary near the crack line,the elastic-plastic stress fields near crack line are identified.The change pattern of the length of the plastic zone and the pore water pressure is presented.Besides,the elastic-plastic analytical solution for an eccentric cracks loaded by the pore water pressure is obtained. 相似文献