麦秸/木材三层结构无机刨花板的制备工艺

以麦秸、木材碎料和无机胶黏剂制备麦秸/木材三层结构刨花板。研究麦秸与木材配比、板材密度、热压时间和温度对板材性能的影响。结果表明:随麦秸配比增加,板材抗弯性能降低,内结合强度增大,吸水厚度膨胀率(TS)减小;随密度增加和热压时间延长,板材力学性能增大,TS降低;随热压温度升高,板材力学性能先增大后减小,TS呈相反趋势。优化制板工艺为:碎料配比5:5,密度1.2g/cm~3,热压时间30min,温度100℃。     

无胶干法硬质纤维板热压工艺的探讨

本文采用正交试验方法,探讨了热压工艺中的温度、压力和时间对无胶干法硬质纤维板主要物理力学性能的影响,筛选出最佳热压工艺参数。对最佳热压工艺参数进行验证试验表明,所制无胶干法硬质纤维板的主要性能,可达到湿法纤维板的水平。     

喷蒸热压法棉秆无胶碎料板的研制

以棉秆为原料,采用喷蒸热压法研制无胶碎料板,探讨板的密度、蒸汽压力及喷蒸时间对棉秆无胶碎料板的物理力学性能的影响.结果表明:在试验范围内,随着板密度增大,无胶碎料板的静曲强度、弹性模量与内结合强度明显提高;提高蒸汽压力及延长喷蒸时间,能明显降低无胶碎料板的吸水厚度膨胀率.     

混凝土模板用复合竹碎料板工艺研究

用正交试验法研究了施胶量、热压温度和热压时间3个因素对复合竹碎料板物理力学性能的综合影响．结果表明：热压温度是影响板材物理力学性能的主要因素．较佳工艺参数为，施政量12％，热压温度150℃，热压时间22min，板材物理力学性能能满足混凝土模板材料性能的需要．     

苯酚-尿素-甲醛共缩聚树脂制取竹胶板模板热压工艺试验

利用自行研制的苯酚-尿素-甲醛共缩聚树脂(PUF)以热压压力、时间、温度3个因素3水平的正交实验设计进行竹胶板模板热压工艺试验,结果表明,PUF压制的竹胶板模板物理力学性能优良,超过JG/T156-2004<竹胶合板模板>质量要求,与目前生产上使用的PF胶压制的竹胶板模板性能相当,但用胶成本可节省13.5%;PUF压制竹胶板模板的较优工艺参数为热压压力2.5 MPa、热压时间1.2 min/mm、热压温度150℃.     

不同热压方法对无胶竹碎料板力学性能影响

分别采用普通热压和喷蒸热压两种热压方法制备了无胶竹碎料板,对它们的物理力学性能进行了对比研究与分析.结果表明,与普通热压法相比,喷蒸热压法制备的无胶竹碎料板的静曲强度、弹性模量与内结合强度明显提高,吸水厚度膨胀率显著减小,这可能是因为两种热压法热压过程中竹碎料发生的化学变化不同所致.     

干法蔗渣中密度纤维板热压工艺的研究

通过正交试验法，分析了热压中温度、压力和时间对干法蔗渣ＭＤＦ各项物理力学性能的影响。确定了蔗渣ＭＤＦ（板厚为１２ｍｍ）热压的较佳工艺参数为：热压温度１７５℃，热压时间８．５ｍｉｎ，热压压力４ＭＰＡ。     

漆酶/碳源系统预处理对稻草碎料板性能的影响

利用添加少量碳源与漆酶组成的体系对稻草进行预处理,以改善其压板性能,研究了漆酶预处理的最佳工艺条件、漆酶／碳源系统(LCS)与漆酶／介体系统(LMS)预处理结果比较及酶处理对稻草碎料板性能的影响。结果表明:LCS完全可以代替昂贵的LMS来降解稻草中木质素;预处理最适条件为pH值5.0,温度45℃,液比1:7,时间4-6h,酶用量20-30IU／g;当酶用量为20IU/g,时间4h条件下预处理稻草碎料板的各项力学性能均有显著改善,与粗碎料板相比,酶处理对细碎料板的性能改善效果更是明显:内结合强度(IB)增加20％,静曲强度(MOR)增加21％,弹性模量(MOE)增加31％,吸水厚度膨胀率(TS)降低35％,甲醛释放量可达到F1级标准。     

红麻秆无胶碎料板的研究

制定了红麻秆(Hibiscus cannabinus)材料在无任何添加剂的条件下制作无胶碎料板的相关工艺,探讨了红麻杆无胶碎料板的密度与其物理力学性能(静曲强度、内结合强度、吸水厚度膨胀率)间的关系,根据国家标准GB/T4897.2-2003干燥状态下使用的普通刨花板要求评价了红麻杆无胶碎料板的性能,结果表明:当密度大于0.7g/cm3时,红麻秆无胶碎料板的性能即能够满足标准要求。并使用傅里叶红外光谱研究了其在热压过程中的官能团变化,进而初步分析红麻秆无胶碎料板的胶合机理。     

覆膜厚帘竹胶合板模板的研制

研究了以3 mm以上厚度的竹篾片编织竹帘生产厚帘竹胶合板模板的工艺条件,讨论了热压时间、热压压力、热压温度及浸胶的胶液浓度对覆膜厚帘竹胶合板模板物理力学性能的影响,总结确定出最佳的可供生产应用的热压工艺条件.结果表明,在热压压力1.4 MPa、热压时间60 s/mm板厚、热压温度135 ℃、浸胶胶液浓度26%的条件下生产出的产品各项力学性能指标均达到或超出竹胶合板模板国家标准.     

热压工艺对竹重组板材性能的影响

探讨了以竹材为主要原料的竹重组板材热压工艺的优化,研究了热压工艺对竹重组板材力学性能的影响,讨论分析了热压压力、热压时间、热压温度对竹重组板材吸水厚度膨胀率、耐沸水性、静曲强度、弹性模量、耐磨性、耐化学腐蚀性、浸渍剥离率和甲醛释放量等性能的影响。通过正交试验,得出的优化热压工艺为:①热压压力2.0MPa、热压温度145℃、热压时间1.7min/mm,热压压力对竹重组板材耐酸性、静曲强度和弹性模量等影响显著,对耐沸水性、耐碱性、耐盐性、耐磨性和浸渍剥离率等影响不显著。②热压时间对竹重组板材静曲强度有显著影响,对其他试验指标影响不显著。③热压温度对竹重组板材各试验检测指标均有一定的影响,但不显著。     

Evaluation of the self-bonding ability of sugi and application of sugi powder as a binder for plywood

Binderless particleboards were manufactured from sugi (Cryptomeria japonica D. Don) heartwood and sapwood by hot-pressing (pressure: 5 MPa; temperatures: 180°, 200°, and 220°C; times: 10, 20, and 30 min), and the board properties [internal bonding (IB), thickness swelling (TS), water absorption (WA)] were investigated to evaluate the self-bonding ability. The IB, TS, and WA of the boards from sugi heartwood were better than those of the boards from sugi sapwood at any hot-pressing condition. Therefore, it was suggested that the self-bonding ability of sugi heartwood was superior to that of sugi sapwood. Then, sugi heartwood and sapwood powder with grain size 10 βm were used as a binder for plywoods. Four kinds of plywood were manufactured from the combination of powder and veneer, both of which were prepared from sugi heartwood and sapwood under the same hot-pressing conditions as the binderless particleboard, and the adhesive shear strength and wood failure of the plywood were investigated. As a result, the plywood composed of sugi heartwood veneer met the second grade of JAS for plywood, when either powder was used as a binder, when they were pressed at 200°C for 20–30 min and 220°C for 10 min.     

Influence of pressing parameters on mechanical and physical properties of self-bonded laminated beech boards

Abstract

Five-ply self-bonded boards were obtained by pressing beech veneers parallel to the grain without additional adhesives, steam or pre-treatment. Fifteen different combinations of pressing parameters were tested, including temperature (200°C, 225°C and 250°C), pressure (4, 5 and 6 MPa) and pressing time (240, 300 and 360 seconds). Due to severe pressing conditions, the new product showed a higher density and different properties compared to a conventionally glued laminated wooden board. The self-bonding quality was assessed through dry shear strength tests, through a three-point bending test and a water-soaking test at 20°C. The dimensions in the cross section of the boards were measured after soaking in water. Results show that the choice of pressing parameters affects all the mechanical and physical properties tested. A statistical analysis revealed that the pressing temperature is the most influential parameter. Boards pressed at 200°C delaminated rapidly in water, whereas boards pressed at 225°C delaminated only at core-positioned layers after 48 hours and boards pressed at 250°C did not delaminate at all in water. Compared to panels pressed at lower temperatures, boards pressed at 250°C had the highest density, a higher shear and bending strength and a lower water absorption.     

Fundamentals of flakeboard manufacture: wood-moisture relationships

Summary A procedure is presented to estimate the relative vapor pressure, equilibrium moisture content, average flake temperature, and average flake moisture content in a flakeboard mat during hot-pressing. This method is based on measurements of temperature and total gas pressure in the mat during hot-pressing. A heat and mass transfer model was adapted from the literature to predict the temperature and moisture content inside an individual flake. Significant moisture gradients are predicted to develop within flakes. Convective heat transfer appears to control the change of moisture content within a flake. Thermodynamic equilibrium between the gas phase and the wood component is not achieved during hot-pressing.This work was funded by the USDA Competitive Grant Program for Forest and Rangeland Renewable Resources, Project No. 85-FSTY-9-0106 and 87-FSTY-9-0253     

The effects of chemical components and particle size on the mechanical properties of binderless boards made from oak (<Emphasis Type="Italic">Quercus</Emphasis> spp.) logs degraded by shiitake fungi <Emphasis Type="Italic">(Lentinula edodes</Emphasis>)

Binderless boards are composite boards that rely on self-bonding mechanisms for inter-fibre bonding. Quercus acutissima and Quercus serrata logs degraded by Lentinula edodes (shiitake fungi) were used in this study to investigate whether physical and chemical changes induced by shiitake fungi can enhance board mechanical properties. Binderless boards were manufactured with 0.8 g/cm³ target density, 220 °C pressing temperature, 5 MPa pressure, and pressing duration of 10 min. Boards made from logs degraded for ≥?26 months were stronger than control boards and met modulus of rupture (MOR) and internal bonding (IB) requirements for fibreboards. Chemical composition and particle size distribution of the wood powder used to make the boards were determined to elucidate the drivers of board mechanical properties. The proportion of small particles (<?150 µm) showed a strong positive correlation with MOR for both species and hot water extractives showed a strong positive correlation with IB for Q. acutissima boards. Introduction of shiitake fungi pre-treatment to the production process may enhance the mechanical strength of binderless boards.     

热压工艺对竹材加工剩余物制备重组复合板性能影响的研究

采用正交实验法,研究热压工艺对竹材加工剩余物制备重组复合板性能的影响。研究结果表明:热压温度对试验结果的影响最为显著,其次是热压压力,而热压时间对试验结果的影响不明显;综合考虑产品成本及生产效率,确定最佳热压工艺为热压温度140℃、热压压力5.5 MPa、热压时间1.0 min/mm;由此工艺压制的板材,其性能能够满足汽车车厢底板及混凝土模板的要求,应用前景非常广阔。     

Self-bonding characteristics of binderless kenaf core composites

We investigated optimum self-bonding conditions of kenaf core composites manufactured by steam treatment, and discussed on the roles of cinnamic acids in the self-bonding mechanism. The presence of cinnamic acids in the kenaf core and its composites were analyzed by pyrolysis gas chromatography-mass spectrophotometry in the presence of tetramethyl ammonium hydroxide (TMAH/Py-GC-MS). The results showed that the optimum bonding properties of kenaf core composites were achieved under these conditions: steam pressure of 0.8–1.0 MPa and pressing time of 10–15 min were able to provide shear strength of 0.40–0.42 MPa while having 2–5% of weight loss. Lignin analysis showed that steam-treated kenaf core composites had a lower proportion of syringyl- to guaiacyl-derived moieties and also cinnamic acids to guaiacyl-derived moieties than its native counterpart. The results indicated that some parts of the ester-linked cinnamic acids were also cleaved due to the degradation of hemicelluloses and lignin during steam treatment. Based on these results, it was concluded that in addition to three main components, the cinnamic acid was also suggested to participate in the self-bonding mechanism of non-wood lignocellulosic binderless boards.     

Chemical changes of kenaf core binderless boards during hot pressing (II): effects on the binderless board properties

To provide basic information on self-bonding in kenaf core binderless boards, a series of chemical analyses was conducted on binderless boards and their chemical changes during hot pressing were examined in our previous study. In this study, binderless boards were manufactured under conditions that may accelerate the supposed chemical changes to investigate their effect on the board properties. First, to investigate the influence of the chemical bonds formed by carbonyl compounds on self-bonding, the influence of acetic acid addition prior to board manufacturing was studied and the effect of methanol extractives (containing the carbonyl compounds) was also examined. Second, the influence of the condensation reaction in lignin was discussed from the viewpoint of board density. Last, to examine the influence of thermal softening of lignin, the influences of temperature condition and moisture content, as well as those of microwave pretreatment, were investigated. As a result, the estimated chemical changes were suggested to influence the binderless board properties.     

植物蛋白胶细木工板加工技术的研究

笔者使用的植物蛋白胶是以富含蛋白质的生物质为主要原料制备的无甲醛释放的胶粘剂。由于其初粘性不如"三醛胶"大,因此不能利用传统细木工板的生产工艺。针对该胶粘剂的特点,通过研究新的施胶工艺,确定木材含水率8%～12%,第1次预压15 min,热压第一阶段最佳工艺参数:施胶量170 g/m2,热压时间8 min,压力17 MPa,温度105℃;第2次预压15 min,热压第二阶段最佳工艺参数:施胶量155 g/m2,热压时间4 min,施胶量155 g/m2,温度100℃,压力15 MPa,板材外观能达到优等品标准,理化性能符合GB/T5849-2006的要求。     

The influence of high defibration temperature on the properties of medium-density fiberboard (MDF) made from laccase-treated softwood fibers

This study was carried out to elucidate the effect of defibration temperature in the range 171–202°C on the properties of 12-mm thick MDF boards made without synthetic resins from softwood fibers activated by laccase treatment for the generation of phenoxy radicals on the fiber surfaces. Laccase treatment generated radicals in the fibers. An increase in defibration temperature improved the reactivity of fibers during laccase-catalyzed oxidation. The number of radicals detected in the fibers after laccase treatment in water suspension and the fiber oxygen consumption during the treatments increased with an increase in defibration temperature, while a concurrent improvement was observed in the mechanical strength and thickness swell of dry-process MDF boards made from fibers refined at different temperatures and treated with laccase in the refiner blowline. The different fiber reactivities or board properties were not due to a presence of different amounts of lignin remaining on the fiber surfaces after acetone extraction. The probable reason for them was the fact that the amount of low-molecular weight lignin, a reactive substrate for laccase, increases with increasing defibration temperature. The adhesion occurring during pressing is thus likely to involve coupling or other reactions of radicals located on adjacent fibers, whereby interfiber covalent bonds are formed.