中国东南部红壤施用石灰和石膏后底土酸性的减缓

Application of lime or gypsum is a common agricultural practice to ameliorate soils with low pH which prohibits crop production. Its integrated effect on soil properties in a red soil derived from Quaternary red clay in Southeast China is discussed in this paper. Application of gypsum in the topsoil without leaching raised soil pH and promoted the production of soil NH₄, but lime addition had a contrary effect. Generally, application of lime and/or gypsum has little effect on soil electrical properties. Gypsum had a little effect on soil exchange complex and its effect went down to 30 cm in depth. The effect of lime reached only to 5 cm below its application layer. With leaching, Ca transferred from top soil to subsoil and decreased exchangeable Al in subsoil. Gypsum application led to a sharp decrease in soil exchangeable Mg but had no effect on K.     

灌溉施用氮肥后氮素在土壤中的转化及淋失状况: 土柱模拟研究

A soil column method was used to compare the effect of drip fertigation (the application of fertilizer through drip irrigation systems, DFI) on the leaching loss and transformation of urea-N in soil with that of surface fertilization combined with flood irrigation (SFI), and to study the leaching loss and transformation of three kinds of nitrogen fertilizers (nitrate fertilizer, ammonium fertilizer, and urea fertilizer) in two contrasting soils after the fertigation. In comparison to SFI, DFI decreased leaching loss of urea-N from the soil and increased the mineral N (NH₄⁺-N + NO₃^--N) in the soil. The N leached from a clay loam soil ranged from 5.7% to 9.6% of the total N added as fertilizer, whereas for a sandy loam soil they ranged between 16.2% and 30.4%. Leaching losses of mineral N were higher when nitrate fertilizer was used compared to urea or ammonium fertilizer. Compared to the control (without urea addition), on the first day when soils were fertigated with urea, there were increases in NH₄⁺-N in the soils. This confirmed the rapid hydrolysis of urea in soil during fertigation. NH₄⁺-N in soils reached a peak about 5 days after fertigation, and due to nitrification it began to decrease at day 10. After applying NH₄⁺-N fertilizer and urea and during the incubation period, the mineral nitrogen in the soil decreased. This may be related to the occurrence of NH₄⁺-N fixation or volatilization in the soil during the fertigation process.     

钙盐诱导下土壤锰和铁的释放及其对胡椒的生物有效性

Releases of manganese and iron ions from an albic soil (Albic-Udic Luvisol), a yellow-red soil (Hap-Udic Ferrisol) and a yellow-brown soil (Arp-Udic Luvisol) induced by calcium salt addition and their bioavailability to pepper (Capsicum frutescens L.) were studied in a pot experiment. Addition of Ca(NO₃)₂ decreased soil pH and increased both exchangeable and DTPA (diethylenetriamine pentaacetic acid)-extractable Mn and Fe in soils. Meanwhile, total Mn accumulation in the shoots of Capsicum frutescens L. on the salt-treated soils increased significantly (P< 0.01) compared with the control, suggesting that salt addition to soil induced Mn toxicity in Capsicum frutescens L. Although exchangeable and DTPA-extractable Fe increased also in the salt-treated soils, Fe uptake by the shoots of Capsicum frutescens L. decreased. The effect of added salts in soils on dry matter weight of pepper varied with the soil characteristics, showing different buffer capacities of the soils for salt toxicity in an order of yellow-brown soil > albic soil > yellow-red soil. Fe/Mn ratio in shoots of Capsicum frutescens L. decreased with increasing salt addition for all the soils, which was ascribed to the antagonistic effect of Mn on Fe accumulation. The ratio of Fe/Mn in the tissue was a better indicator of the appearance of Mn toxicity symptoms than Mn concentration alone.     

可变电荷土壤对酸雨敏感度的影响因子

The sensitivity of a large number of variable charge soils to acid rain was evaluated through examining pH-H₂SO₄ input curves. Two derivative parameters, the consumption of hydrogen ions by the soil and the acidtolerant limit as defined as the quantity of sulfuric acid required to bring the soil to pH 3.5 in a 0.001mol L^-1 Ca(NO₃)₂ solution, were used. The sensitivity of variable charge soils was higher than that of constant charge soils, due to the predominance of kaolinite in clay mineralogical composition. Among these soils the sensitivity was generally of the order lateritic red soil > red soil > latosol. For a given type of soil within the same region the sensitivity was affected by parent material, due to differences in clay minerals and texture. The sensitivity of surface soil may be lower or higher than that of subsoil, depending on whether organic matter or texture plays the dominant role in determining the buffering capacity. Paddy soils consumed more acid within lower range of acid input when compared with upland soils, due to the presence of more exchangeable bases, but consumed less acid within higher acid input range, caused by the decrease in clay content.     

红壤交换性钙、镁和钾的分布及施肥对其影响

A leaching experiment was Carried out with repacked soil columns in laboratory to study the leaching process of a red soil derived from sandstone as affected by various fertilization practices.The treatments were CK(as a control),CaCO3,CaSO4,MgCO3,Ca(H2PO4)2,Urea,KCl,Multiple(a mixture of the above mentioned fertilizers) and KNO3,The fertilizers were added to the bare surface of the soil columns,and then the columns were leached with 120 mL deionized water daily through perstaltic pumps over a period of 92 days,At the end of leaching process,soils were sampled from different depths of the soil profiles ,i.o.,of 92 days,At the end of leaching process,soils were sampled from different depths of the soil profiles,I.e.0-5cm,5-10cm,10-20cm,20-40cm,and 40-60cm,The results showed when applying Ca,Mg,and K to the bare surface of the soil columns,exchangeable Ca^2 ,Mg^2 ,and K^ in the upper layer of the soil profile increased correspondingly,with an extent depending mainly on the application rates of Ca,Mg,and K and showing a downward trend,CaCO3,CaSO4,MgCO3,and Ca(H2PO4)2 treatments had scarcely and effect on movement of exchangeable K^ ,while CaCO3,and CaSO4 treatments singnificantly promoted the downward movement of exchangealble Mg^2 although these two treatments had no obvious effect on leaching losses of Mg,The fact that under Urea treatment,exchangeable Ca^2 and Mg^2 ,were higher as compared to CK treatment showed urea could prevent leaching of exchangeable Ca^2 and Mg^2 ,the obvious downward movement of exchangeable Ca^2 and Mg^2 was noticed in KCl treatment ,In Multiple treatment,the downward movement of exchangeable Ca^2 and Mg^2 was evident,while that of K^ was less evident,Application of KNO3 strongly promoted the downward movement of exchangeable Ca^2 and Mg^2 in the soil profile.     

黄淮海平原小麦-玉米轮作制度下的地下水NO3-N污染研究

The North China Plain, where summer corn (Zea mays L.) and winter wheat (Triticum aestivum L.) are the major crops grown, is a major agricultural area in China. Permeable soils make the region susceptible to groundwater pollution by NO₃-N, which is applied to fields in large amounts of more than 400 kg NO₃-N ha^-1as fertilizer. A field experiment was established in 2002 to examine the relationship among N fertilization rate, soil NO₃-N, and NO₃-N groundwater contamination. Two adjacent fields were fertilized with local farmers' N fertilization rate (LN) and double the normal application rate (HN), respectively, and managed under otherwise identical conditions. The fields were under a traditional summer corn/winter wheat rotation. Over a 22-month period, we monitored NO₃-N concentrations in both bulk soil and soil pore water in 20-40 cm increments up to 180 cm depth. We also monitored NO₃-N concentrations in groundwater and the depth of the groundwater table. No significant differences in soil NO₃-N were observed between the LN and HN treatment. We identified NO₃-N plumes moving downward through the soil profile. The HN treatment resulted in significantly higher groundwater NO₃-N, relative to the LN treatment, with groundwater NO₃-N consistently exceeding the maximum safe level of 10 mg L^-1, but groundwater NO₃-N above the maximum safe level was also observed in the LN treatment after heavy rain. Heavy rain in June, July, and August 2003 caused increased NO₃-N leaching through the soil and elevated NO₃-N concentrations in the groundwater. Concurrent rise of the groundwater table into NO₃-Nrich soil layers also contributed to the increased NO₃-N concentrations in the groundwater. Our results indicate that under conditions of average rainfall, soil NO₃-N was accumulated in the soil profile. The subsequent significantly higherthan-average rainfalls continuously flushed the soil NO₃-N into deeper layers and raised the groundwater table, which caused continuous groundwater contamination with NO₃-N. The results suggest that under common farming practices in the North China Plain, groundwater contamination with NO₃-N was likely, especially during heavy rainfalls, and the degree of groundwater contamination appeared to be proportional to the N application rates. Decreasing fertilization rates, splitting fertilizer inputs, and optimizing irrigation scheduling had potential to reduce groundwater NO₃-N contamination.     

第四纪红色粘土发育的红壤中营养元素的淋失

A red soil derived from Quaternary red clay was employed to study nutrient leaching with soil columns repacked in laboratory. The objective was to identify the effects of fertilization practices on leaching patterns and magnitudes of Ca²⁺, Mg²⁺, K⁺, NH₄⁺, and NO₃^-. The treatments were CK (as a control), CaCO₃, CaSO₄, MgCO₃, Ca(H₂PO₄)₂, urea, KCl, and multiple (a mixture of the above-mentioned fertilizers). The fertilizers were added to the bare surface of the soil columns, and then the columns were leached with 120 mL deionized water daily through peristaltic pumps over a period of 92 days. Leaching processes of NH₄⁺, and NO₃^- were only measured in CK, urea, and multiple treatments which were directly related to N leaching. Results showed that sole application of CaSO₄, and Ca(H₂PO₄)₂ scarcely had any effect on the leaching losses of Ca²⁺, Mg²⁺, and K⁺; the application of MgCO₃ stimulated the leaching of Mg²⁺; the application of CaCO₃ promoted the leaching of Ca²⁺, Mg²⁺ and K⁺; urea treatment also promoted the leaching of K⁺ and NH₄⁺, and NO₃^- leaching mainly occurred at late stage of leaching process in particular; under KCl treatment, leaching of Ca²⁺, Mg²⁺, and K⁺ was promoted to a large extent; under multiple treatment, leaching of Ca²⁺, Mg²⁺, K⁺, NH₄⁺, and NO₃^- was all increased and NO₃^- was mainly leached at the end of leaching process and still had a trend of increase.     

中性盐和pH对红壤、砖红壤胶体交换性酸的影响

In the present work, the exchangeable acidity of a red soil colloid and a latosol colloid at different pH during reacting with four neutral salts was measured. The results show that the exchangeable acidity increased with increasing amounts of the neutral salts added, and the relation between them was almost linear. When the amount of the neutral salt added was lower than a certain value, the slope of the line was high, and the slope turned low when the amount exceeded that value, so there was a turning point in each line. The addition amounts of the neutral salts for the turning points were affected by the cation species of the neutral salts, but pH had less effect on them. After the turning points occurred, the exchangeable acidity of the red soil colloid still gradually increased with the addition amounts of the neutral salts, but that of the latosol colloid did not increase any more. The exchangeable acidity in NaClO₄, KClO₄ and NaCl solutions increased at first, and then decreased with increasing pH, that is to say, peak values appeared. The peak positions of the exchangeable acidity in relation to pH changed with neutral salt solutions and were affected by the surface characteristics of the soil colloids, but not affected by the amounts of the neutral salts added. The exchangeable acidity in the Ba(NO₃)₂ solution increased continuously with increasing pH. The exchangeable acidity of the red soil colloid was obviously larger than that of the latosol colloid.     

中国杉连作对土壤肥力的影响

The changes in soil fertility under continuous plantation of Chinese fir were studied by comparing soil samples from different forest stands:the first and second plantations of Chinese fir,evergreen broad-leaved forests,and clear-cut and burnt Chinese fir land located at Xihou Village,Nanping of Fujian Province.The soils were humic red soil originated from weathered coarse granite of the Presinian system.Soil pH,CEC,base saturation ,exchangeable Ca^2 ,exchangeable Mg^2 and A1-P declined after continuous plantation of Chinese fir.The same trends were also found in the soils under broad-leaved stands and slash burnt lands.The explantation was that not merely the biological nature of the Chinese fir itself but the natural leaching of nutrients,soil erosion and nutrient losses due to clear cutting and slash burning of the preceduing plantation caused the soil deterioration .Only some of main soil nutrients decreased after continuous plantation of Chinese fir,depending on specific silvicultural system,which was different from the conclusions in some other reports which showed that all main nutrients,such as OM,total N,available P and available K decreased,Some neccessary step to make up for the lost base,to apply P fertilizer and to avoid buring on clear cut lands could be taken to prevent soil degradation and yield decline in the system of continuous plantation of Chinese fir.     

上海市土壤中持久性毒害污染物和盐分含量特征研究

Some farmland soils in Shanghai had high salinity levels, suggesting secondary salinization of the soils. The soil problems in Shanghai were studied, including the salinity and nitrate nitrogen (NO₃^--N) concentrations, heavy metal pollution characteristics, and organochlorine pesticide (OCP) residual levels and polycyclic aromatic hydrocarbon (PAH) contents. Accumulation of NO₃^--N in vegetable soils was the most significant among different functional soils. Heavy metal pollution was significant in the samples collected from the sewage-irrigated land and roadside. The identification of the metal sources through multivariate statistical analysis indicated that Pb, Zn, Cu and Cr in urban soils were from the traffic pollutants; excessive application of fertilizer and irrigation were the main reasons for the metal pollution in agricultural soils; Ni in the observed soils was controlled by parent soils. OCPs could still be detected in farmland soils but degraded greatly in last 20 years after prohibition of their usage. PAHs with 2-3 rings were the main components in industrial soils. The concentrated PAHs in the investigated soils were likely from petroleum and coal combustion.     

Effect of leaching events on the fate of polyhalite nutrient minerals used for crop fertilization

Abstract

Polyhalite is a natural mineral containing potassium (K), calcium (Ca), magnesium (Mg) and sulfur (S) and is proposed as a fertilizer source for these essential nutrients. Application of polyhalite is expected to be most relevant in soils where the availability of these nutrients is low: in sandy soils, in highly leached soils, or in areas where crops are irrigated by water with low content of these nutrients or are rain-fed. A controlled lysimeter experiment investigated the efficacy of surface applied polyhalite as a fertilizer supplying K, Ca, Mg and S compared to soluble sulfate salts in two soils (sandy and loamy) with or without simulated rain leaching events through two cycles of cropping. In the first cycle, carrot response and nutrient uptake, transport, and loss through leaching were studied, while in the second cycle the residual effect of the fertilizer was considered on maize without additional fertilizer application or leaching. Polyhalite plus rain led to increased carrot yield due to augmented Ca uptake in sandy soil. In both soils, polyhalite behaved as a prolonged availability fertilizer with more nutrients retained in the top soil layer and not leached below the root zone. The treatments did not affect maize growth or nutrient uptake except for lower K and S uptake in soils where rain had been simulated for the previous crop. We conclude that polyhalite shows potential as a commercial fertilizer to supply K, Ca, Mg, and S nutrients under conditions of dryland agriculture where occasionally leaching by rainfall occurs.     

磷钾肥施用对日光温室土壤溶液离子组成的影响

采用土培模拟试验研究了施用磷、钾肥对大田和温室土壤溶液电导率（EC）、离子含量及其比例的影响。结果表明,温室栽培土壤溶液EC、K+、Na+、Ca2+、Mg2+、NO3-含量以及K+ / Ca2+、K+ / Mg2+摩尔比分别为大田土壤的2.5、95.0、16.6、1.9、3.2、4.0、31.0和39.0倍,说明日光温室土壤离子累积及养分比例失调问题突出。施用磷、钾肥对土壤溶液中不同离子含量的影响不同,增加磷肥施用量,显著降低了大田和温室土壤溶液EC和Ca2+、Mg2+离子含量,而对土壤溶液K+、NO3--N和NH4+-N离子浓度均无显著影响;随施钾量增加,大田及温室土壤溶液EC、K+、Na+、Ca2+、Mg2+和K+/Ca2+、K+/Mg2+摩尔比均呈显著增加趋势。温室栽培实践中因过量施用磷、钾肥而造成的阳离子养分比例失调而带来的营养及生态环境问题值得关注。     

秸秆还田下氮肥用量对稻田养分淋洗的影响

通过田间试验,研究秸秆还田配施氮肥对稻田土壤养分淋洗的影响。结果表明,随氮肥用量增加,田间渗漏水中NH4+-N、NO3--N、全氮浓度随之增加;与秸秆未还田相比,秸秆还田降低了田面水与渗漏水中NH4+-N、NO3--N的浓度;秸秆还田下各处理30cm土层渗漏水中全氮和NO3--N浓度最高,其浓度范围分别为1.09~12.76mg·L-1和0.76~3.74mg·L-1;全磷浓度范围为0.02~0.79mg·L-1,田面水中全磷浓度随施氮量增加而增加,30cm渗漏水中全磷浓度大于60cm渗漏水。氮肥用量180kg·hm-2时,施肥后5~10d内30cm、60cm渗漏水中的养分以NH4+-N为主,其后均以NO3--N为主。氮肥与秸秆配合施用,可降低田面水和渗漏水中的氮磷浓度,改善肥料利用效率。     

施肥对设施菜地土壤硝态氮累积及pH的影响

在甘肃武威市设施栽培条件下,通过田间小区试验研究了不同施肥量及肥料种类（化肥、有机肥、有机＋无机）对设施土壤硝态氮累积、硝态氮在土壤剖面运移及土壤pH值变化的影响。结果表明：施氮量和肥料种类对土壤硝态氮的累积和淋溶均有较大的影响,随施氮量的增加,土壤剖面硝态氮累积量增加,其中对0～20cm土层硝态氮累积量的影响最为显著;在同等施氮量时,单施无机肥处理（NPK）、有机无机肥减半配施处理（1/2MNPK）、单施有机肥处理（M）,在40～150cm土层硝态氮的累积量分别为267.33、211.94、125.72kg.hm-2,表明只施用化肥较有机肥、有机肥与化肥配施更易造成土壤硝态氮淋溶并在深层累积。将农户习惯施肥量（MNPK）减半后施用（1/2MNPK）对蔬菜产量没有影响,并且显著减少了硝态氮在土壤中的累积,表明当地农户设施栽培肥料施用量过高,不仅造成肥料利用率低,栽培成本高,还可能给地下水位较浅的地区带来环境污染的风险。此外,土壤硝态氮含量与pH值呈极显著负相关关系,表明硝态氮在土壤中大量累积会造成土壤pH值的下降。     

菜地土壤养分的空间变异特征

通过地统计学、空间分析方法及结合农户施肥调查,对菜地土壤养分的空间变异特征进行研究。结果表明,农户施肥水平差别较大,整体上施磷相对过多,施钾相对较少,土壤OM、NH4+-N、P、K、Ca、Mg和S的变异系数在28.4%～69.2%之间。土壤各养分的空间变异结构有较大区别,土壤OM及NH4+-N的变异具有强烈空间相关性,土壤P、K、Ca、Mg和S养分含量的变异为中等空间相关性。土壤养分的等值线图显示,OM在空间的分布与土壤质地渐变规律相关,NH4+-N呈现南北向的带状分布,P、K、Ca、Mg和S趋于小块状分布。总的来说,施肥等人为因素加剧了土壤矿质养分的空间变异。     

日光温室栽培对土壤养分累积及交换性养分含量和比例的影响

研究了日光温室栽培下陕西关中地区不同土壤养分累积及交换性养分含量及比例的变化,结果表明：日光温室栽培下土壤有机质、硝态氮、有效磷和速效钾等养分显著累积,土壤阳离子交换量明显增加,而土壤pH却出现下降趋势。日光温室土壤交换性K^＋含量显著增加;日光温室和大田土壤交换性Ca^2＋含量相比无明显差异,而日光温室土壤交换性Mg^2＋的含量及其离子饱和度有所提高。日光温室土壤钙饱和度、Ca/K和M g/K均明显低于大田土壤。认为日光温室栽培下大量施用钾肥,是土壤钙离子饱和度及Ca/K和M g/K比例降低的主要原因,建议在评价日光温室土壤养分有效性时,应综合考虑交换性养分的含量、饱和度及离子间的比例关系。     

潮土定位试验施肥对土壤养分变化及环境质量监测研究 Ⅱ施肥对土壤剖面NO_3-N动态变化的影响

潮土肥力定位试验进行过程中 ,于 1994年探讨土壤剖面NO3 -N不同时空动态分布以及对作物产量、环境质量和地下水质的影响。结果表明 :NPK平衡施肥与有机、无机肥配施 ,在本试验的施肥水平和配合比例条件下 ,小麦—玉米(大豆 )轮作制获得较高的产量。单施N、NK的土壤剖面中NO3 -N含量经常处于超标状态 ,构成了对土壤环境和地下水质的污染。降水、灌溉水量、N肥用量以及肥料利用率是影响土壤NO3 -N淋洗、积累的主要因素     

滇池北岸居民-农田混合区域农田土壤氮素空间分布特征研究

土壤氮含量空间分布特征对评价氮迁移风险和合理施肥具有重要意义。以滇池北岸大清河流域下游46.7 hm2韭菜田与花卉地为对象,于2006年8月通过网格法（40 m×（80～90）m）布点采集112个表层土样,研究了土壤氮素空间变异特征。结果表明,调查区土壤TN为1.28～6.17 g.kg-（1均值3.36 g.kg-1）、NO3--N为3.7～691.7 mg.kg-（1均值89 mg.kg-1）。调查区东北部韭菜种植区由于接受生活污水、养殖废水,土壤总氮含量最高,而西南部韭菜、花卉种植区土壤总氮含量相对较低,高浓度养殖和生活污水的排放是导致土壤总氮含量空间分布差异的主要原因;土壤硝氮含量则以西南部花卉大棚区最高,不同的种植方式（花卉大棚栽培）是土壤硝氮含量差异的主要原因。夏季高温多雨,花卉揭棚将增加土壤硝酸盐淋溶/径流的迁移风险,蔬菜田块土壤氮矿化也可能加剧土壤氮的淋溶/径流迁移。因此,在滇池流域湖滨区居民生活污水、养殖污水的排放,作物种植方式与布局,对农田氮的迁移及水体污染具有重要的影响。