Point counting pores and illuvial clay in thin section

Six soil thin sections containing various amounts of illuvial clay, previously estimated by ten operators, were point-counted four times by an additional experienced operator. The results indicate that a count of 6000 points over a section area of 25 × 25 mm is sufficient to quantify satisfactorily the pore space of the section. Replicated results for illuvial clay, however, differed widely for some sections. These differences are attributed both to difficulties in recognising illuvial clay and to orientation and variability of soil components. Variability of results for illuvial clay in this study was less than that reported for ten operators but, nonetheless, it is evident that for most sections the amount of illuvial clay cannot be estimated precisely by a single count of 6000 points. Suggestions are made for improving the reliability of estimates of illuvial clay in soil thin sections and an improved basis for reporting results is proposed.     

A MATHEMATICAL MODEL FOR THE DIFFERENTIAL MOVEMENT OF TWO SOIL CONSTITUENTS INTO ILLUVIAL HORIZONS: APPLICATION TO CLAY RATIOS IN ARGILLIC HORIZONS

The effects of the migration of two soil constituents into illuvial horizons is described by a set of equations. Differential movement of clay fractions during illuviation causes changes in the fine to total clay ratios in A and B horizons. A mathematical model is used for the interpretation of clay fraction data in order to estimate the degree of profile development, the amounts of fine and total clay which have moved, and to determine the original composition of the parent material. No bulk density data of the soil horizons are necessary for the computation. The equations can be programmed on desk calculators. Comparison with measurements on Alfisols in temperate regions was found to be satisfactory.     

The anisotropy of the structure and the microspatial pattern of the pores at the aggregate level of texturally differentiated soils

The anisotropy of the soil pores in texturally differentiated soils is an important soil-genetic index. The morphological study of thin soil sections with vertical and horizontal orientation showed that the pore space of a texturally differentiated light gray forest soil at the aggregate level of organization has isotropic, anisotropic, and partially anisotropic structures in the different horizons. In the horizons with a platy structure, the anisotropy of the pore space is largely determined by the anisometry of the structural units. In the horizons with a massive structure not separated into aggregates, the anisotropic indices can be related to the structural features of the recent and relic biogenic pores. To reveal the total anisotropy of the soil pore space, the most informative and genetically determined indices should be studied: the shape, area, and orientation of the pores. In the soil studied, the variation of the pore sizes in the vertical thin sections was higher than in the horizontal thin sections, which agreed with the concept of the anisotropy of the entire soil profile. The fixed vertical and horizontal orientation of the soil thin sections allowed the obtained results to be integrated into the full-profile anisotropy of the soil properties. The vertical thin sections were found to be of greater information value for the profile-genetic analysis of the structure and variability of the soil pore space than their horizontal analogues.     

PORE SPACE VARIABILITY IN A SUB-SURFACE HORIZON OF TWO SOILS

Image analysis was used to investigate the variability of pore space in soil thin sections. Two fine-textured soil profiles (or pedons) were sampled by inserting eight Kubiena tins (7.5 × 6 × 4 cm) in ledges at 50 cm depth. From each soil block three horizontal thin sections (7.5 × 6 cm) were made and photographed. Each photograph was then divided into nine ‘frames’ so that the voids in each of these frames could be measured using the Quantimet 720 Image Analysing Computer. The results show the variability of three specific pore-space characters and the consequent need to sample a number of large thin sections from several sample blocks for each soil horizon to obtain estimates of sample means with suitable accuracy.     

Clay illuviation and calcium carbonate accumulation along a precipitation gradient in Kansas

One of the significant features of loess-derived soils in Kansas is the occurrence of clay-rich subsurface horizons above a layer enriched with pedogenic carbonates. In order to examine the extent of clay increase and pedogenic carbonate enrichment in a precipitation gradient, ten soil profiles from three different precipitation regions were studied using micromorphological and mineralogical techniques. The precipitation gradient was divided into three groups: 400–550 mm, 550–750 mm, and 750–1100 mm regions. The objectives were to (1) understand the cause of clay orientation in clay-rich horizons (2) investigate the reasons for the clay increase, and (3) observe the interaction of clay and pedogenic carbonate accumulation features along a precipitation gradient in Kansas. Although clay films were identified in the field for soils in the 400–550 mm regions, illuvial clay films were not observed in thin section analysis. The clay accumulations mostly occurred as grain coatings. The rest of the clay accumulations observed were very thin, striated, and mostly associated with voids. The argillic horizons had a granostriated b-fabric, which indicates stress orientation of micromass caused by high shrink–swell activity. Thick and continuous illuvial coatings were observed in the buried horizons of paleosols. In the other two regions where precipitation exceeds 550 mm, illuvial clay coatings with strong orientation were observed along with thin and striated stress-oriented clay. Both types of clay orientations exceeded 1% of the cross-sectional area for the thin section. Although illuvial clay features and pedogenic carbonates were observed in all soils at approximately the same depth, complete obliteration of clay coatings was not observed in these horizons. In-situ weathering of biotite was one of the reasons for the clay increase in all soil profiles. In all soils studied, the clay increase and cause of clay orientation cannot be attributed to a single genetic process or event. Both illuviation and shrink–swell activity were involved in the orientation of clay. Although orientation of clay and pedogenic carbonates were observed in all soils at approximately the same depth, the decomposition of clay coatings was not observed in these horizons.     

The origin and early genesis of clay bands in youthful sandy soils along lake Michigan,U.S.A.

A beach ridge and dune complex with good radiocarbon control sampling the last 3500 radiocarbon years B.P. provides new insights on the early genesis of clay bands in sandy soils. Soil profiles were sampled by age groups, described in the field, and then subjected to laboratory analyses for particle-size distribution, pH, organic carbon, carbonate minerals, and extractable iron and manganese. This study suggests that small increases in pH, brought about by small increases in carbonate content within the soil profile, are responsible for flocculating small amounts of illuviated clay. This process, along with a transition to a greater hydraulic conductivity with soil depth due to coarser textures in any given profile, partly explains the existence and possible reason for the initiation of illuvial zones and eventually for clay-band horizons. A pronounced increase in the thickness of incipient clay-band horizons in soils older than 2300 years appears due to finer textures in the parent materials than are present in younger soils. Because of slightly reduced porosity and lower permeability, carbonates and a high pH are retained in both illuvial and eluvial horizons of some of these older soils. In addition, only in those profiles older than 2300 years do clay and iron oxide concentrations coincide and is there some suggestion of greater amounts of extractable manganese in horizons of minimum iron and clay. A pronounced segregation of clay-iron bands is not apparent at the study area but should occur in future years as additional amounts of iron and clay are deposited.     

The relation between silty soil structures and their mercury porosimetry curve counterparts: fractals and percolation

Mercury porosimetry data can be interpreted in terms of soil structure using ideas drawn from (i) network modelling and percolation theory and (ii) fractal geometry. We linked mercury intrusion to soil structure quantified by image analysis within a relevant common pore radius scale. We compared (i) three independent methods for computing fractal dimensions of the matrix and of the solid–pore interface, namely fitted square boxes method and pore chord distribution on scanning electron microscope images of soil thin sections, and mercury porosimetry, and (ii) two independent methods for characterizing pore connectivity (image analysis) and percolation process (pressure threshold from mercury porosimetry). The results from analyses of the pore size distribution by mercury porosimetry differed from those from the image analysis. Mercury intrusion is controlled by both the connectivity of the pore space network and locally by pore throats leading to larger pore bodies. By contrast, image analysis is unaffected by pore connectivity and measures pore bodies. On the other hand, the chord length method might not adequately capture the scaling properties of the solid–pore interface, whereas the mercury porosimetry data were also difficult to interpret in terms of fractal geometry because of the effects of pore connectivity. However, fractal dimension values of both the solid phase and the solid–pore interface increased as a function of clay content, whereas both percolation probability values and throat radius values at the mercury percolation threshold decreased. The results show the merit of applying both fractals and percolation theory for determining structural parameters relevant to mercury and water transport in soil.     

Particle packing and organization of the textural porosity in clay–silt–sand mixtures

The packing of elementary particles in soil largely determines the properties that depend on the textural soil pore space, but is studied little. The relations between packing and size and nature of soil particles were studied using fractions of clay, silt and sand, mixed when wet and then dried. Ternary mixtures (clay:silt:sand) were compared with binary mixtures (clay:silt, clay:sand). The pore space of the mixtures was studied using mercury porosimetry and scanning electron microscopy. In all the mixtures the textural pore space was divided into two compartments: (1) lacunar pores due to the presence of skeleton particles and to the shrinkage of the clay phase between these particles, and (2) the clay–fabric pores due to the packing of the clay. In the ternary mixtures, lacunar pores could be divided into two classes: (1) those due to sand particles within the clay–slit phase considered as a single phase, and (2) those due to silt particles within this same phase. For certain mixtures, lacunar pores, referred to as hidden lacunar pores, were not interconnected but were occluded. This occurred both for hidden pores caused by the presence of sand and occluded by the clay–slit phase, and for hidden pores caused by the presence of silt and occluded by the clay phase. The relations between these types of textural pores and the proportions of different size fractions in the mixtures provide guidelines for making optimum use of the particle-size characteristics of the soil to determine its properties.     

A casting method for the three-dimensional analysis of the intraprism structural pores in vertisols

The structural voids in vertisols contain easily available water for plants and their volume can be calculated from the shrinkage curve. Access by plants to that water depends also on the geometric arrangement of the pores so that the water can flow through them. We have devised a method for studying the structural porosity by casting the pores in resin. The intraprism pore space of wet soil clods is impregnated with a UV fluorescent polyester resin under vacuum. When this has set we use the swelling properties of the clay to separate the clay matrix from the resin. A cast so obtained is the real three-dimensional solid reproduction of the structural porosity. This representation of the pore system is easier to study than results from computerized reconstitution of the three-dimensional space from two-dimensional images of soil in thin sections. Channels, packing pores and planar voids can be observed directly in three dimensions as the method saves the integrity and continuity of pores as small as 10 μm in diameter. The geometry of the cast shapes agrees with the interpretation of shrinkage and moisture characteristic curves. The method offers direct qualitative observation of pore organization and volume measurements of the intraprism structural porosity in vertisols.     

Extractable Al and Si compounds in pale-podzolic soils of the Central Forest Reserve: Contents and distribution along the profile and by size fractions

The profile distributions of oxalate- and pyrophosphate-soluble Al compounds and oxalate-soluble Si compounds in the main horizons of pale-podzolic soils of the Central Forest Reserve and the fractions <1. 1–5, and >5 μm have been considered. In the clay-eluvial part of soil profile, the content of these compounds is differentiated by the eluvial–illuvial type with a clear accumulation in the EL horizon compared to the AEL horizon. This distribution is largely ensured by their differentiation in the clay and fine silt fractions, while an accumulative distribution of mobile Al compounds is observed in fractions >5 μm. The high correlation between the Al and Si contents in the Tamm extracts from the clay and fine silt fractions with the (Al_ox–Al_py)/Si_ox molar ratios, which are in the range of 1–3 in the EL horizon, confirms that mobile compounds are accumulated in these fractions in the form of amorphous aluminosilicates. In the AEL and EL horizons, an additional amount of Al can pass into the oxalate solution from the fine fractions due to the dissolution of Al hydroxide interlayers of soil chlorites. The eluvial–illuvial distribution of mobile Al and Si compounds typical for Al–Fe–humus podzols within the clay-illuvial part of profiles of the soils under study can be considered as an example of superimposed evolution.     

Spatial distribution of mineral components in microcombinations of agrogrey soils with the second humus horizon in the Vladimir opolie area

Mineralogical composition of silt and clay fractions (<1.1–5 and 5–10 µm) in heavy loamy agrogrey soils (Luvic Retic Phaeozems) considerably changes both in the vertical (along the soil profile) and horizontal (along soil microcatenas) directions. The eluvial–illuvial distribution pattern of the clay fraction in the podzolized agrogrey soils with the second humus horizon is replaced by the homogeneous distribution in the agrogrey soils with residual carbonates. The distribution of silt fractions in the soil profiles is relatively homogeneous. The clay (<1 µm) fraction of the parent material is represented by the poorly ordered micasmectite interstratifications minerals, the proportion between which changes in the soil profiles in dependence on the particular pedogenetic processes. Hydromicas represent the second important component of the clay fraction. They consist of di- and trioctahedral varieties, the proportion between which changes in the soil profiles. Kaolinite and iron–magnesium chlorite are present in smaller amounts. The second humus horizon is characterized by the lowest content of mica-smectite interstratifications minerals with the high content of smectitic layers and by the lowest content of the clay fraction. Silt fractions are composed of quartz, micas, potassium feldspars, and plagioclases.     

土壤发育指数及其在黄土──古土壤序列中的应用

以洛川坡头和兰州九州台黄土剖面为例，系统地观测和描述了各层黄土与古土壤的形态（包括微形态）特征，选取了１０个土壤形态属性以评价古土壤发育状况：红化作用（颜色彩度和色调）、总质地（质地类型、粘结性和可塑性）、黑化作用（颜色亮度）、微结构（类型、结构性发育程度、孔隙类型和总孔度）、细物质（丰度）、原生碳酸盐（丰度）、黑云母（丰度及蚀变程度）、铁氧化物（丰度）、次生碳酸盐（类型及丰度）和淀积粘粒（干涉色、淀积粘粒特征、胶膜丰度、胶膜厚度）。在此基础上，建立了土壤发育指数，并初步讨论了该指数在环境变化研究方面的应用。     

The relation between the moisture-release curve and the structure of soil

The limit to the precision with which moisture-release data may be related to soil structure is examined. Thin sections in two orthogonal planes were prepared from cores for which moisture release data and saturated conductivity measurements were also collected. Structural parameters are inferred indirectly through estimation of the mass fractal dimension from the moisture-release curve, and directly through measurement of the scaling properties of the pore space and solid matrix from the thin sections using image analysis. Theoretical results are presented which show that, in the absence of additional information, the interpretation of the moisture-release curve is ambiguous for several reasons. A power-law exponent is a consequence of either a fractal pore volume; a fractal solid volume; a fractal pore wall; or a non-fractal, self-similar pore wall, and one cannot infer from the measurement which is the case. Experimental results are presented which confirm that direct measurement of the fractal dimension of the solid matrix is a good predictor of the Brooks–Corey exponent for the soils studied here. Therefore, although a specific structural parameter characterizes the moisture-release curve, the latter cannot be used as a detailed measure of soil structure.     

A VERSATILE METHOD FOR TREATMENT OF CLAY SOILS FOR THIN-SECTION FABRIC STUDIES

In an earlier investigation three different methods had to be used for the treatment of laboratory-compacted clay soils prior to the preparation of thin sections for use in fabric studies. The three methods, viz., the Carbowax method, the Araldite-resin impregnation method, and the Aquax method, had limited application depending on the degree of saturation and the clay-mineral composition of the soil. A new method has been developed which can be applied to all clay soils irrespective of their mineralogy and degree of saturation. In this method, the pore water of the soil specimen is first replaced with monostyrene using a two-step diffusion process. Then the specimen is impregnated with an Araldite-resin mixture which can be cured at a temperature of 55°C. The method has yielded better thin sections than those obtained by any of the three previous methods. Pure montmorillonite soils can be treated with a greater degree of success than hitherto possible.     

Multi-orientation thin sectioning for the determination of 3-D morphology

A new soil thin sectioning technique which gives thin cross-sections (called sliver sections) of thin sections, is described. Optical analysis of soil thin sections and soil sliver sections, using plain, crossed polarized and circularly polarized light provides three-dimensional information on the micromorphology of clay coatings. This new technique is applied to a common type of clay plug and shows that these features consist of a stack of bowl-shaped clay coatings.     

THE EFFECT OF CULTIVATION ON THE STRUCTURE AND OTHER PHYSICAL CHARACTERISTICS OF GRASSLAND AND ARABLE SOILS (194–970)

Cultivating grassland changes the physical state of the soil. The paper describes observations and measurements made in the field and the laboratory on a wide range of soils (with series names) in England over a period of 25 years. Dry sieving showed that natural weathering of grassland aggregates after three months'exposure was very considerable. The drawbar-pull on ploughing soil recently out of grass, as compared with old arable, increased with the number of years out of grass. The number of earthworms per hectare on old grassland was 6 to 9 times that on old arable of the same soil series: after three years'cultivation it was reduced by about a half. The possibility of erosion by wind increased with the number of years out of grass. Old arable land on gentle slopes had its resistance to flowing water (sheet erosion) much increased by as little as 2 years under grass. The apparent densities of soils were at a minimum under old grass and increased under cultivation. On some soils arable for many decades, the apparent densities were near those considered limiting for root penetration. The volurne of water per cent in the soil at the sticky point decreased as the years out of grass increased, suggesting a decrease in the number of days the soil could be cultivated without smearing. The water-stability of soil aggregates decreased as the number of years after ploughing old grassland increased. Whatever the texture, on ploughing old grassland, the water stability of air-dry aggregates feil sharply in the first – years and then approached the value corresponding to that of old arable soils more slowly, apart from soils of low clay content in which it differed little from old arable land after 2 years. Measurement of changes in water stability and field observations in a 6-course rotation (3 years ley, 3 years cereal) on a loam which had been in a similar rotation for about a decade after old grassland, suggested that this balance was probably right for maintaining such a soil at a good cropping level. Puddling (poaching) by animals of wet arable loam soils overlying clay resulted in gleying to the surface: ferrous iron was detected chemically. On putting down to grass there was little increase in water stability of the aggregates after 4 years. The reduction in the total pore space caused by harvesting machinery and also as a result of some years'cultivation of grassland was considerable. The ease of penetration of soils when taking cores was compared by counting the number of blows to drive in a corer: the number was much less in a soil recently out of old grass compared with old arable. The root development of cereals was poor in old arable silt soils very unstable to wetting and drying and with few visible biopores (> 10–00 μm). On soils with many visible pores, root development was much greater and yields with similar rates of nitrogen were double. The total N in the soils feil when old grassland was ploughed, sometimes by as much as 75 per cent in about 20 years. There was sometimes a significant corre-lation between total N and the reduction in water-stable aggregation during the years following ploughing grassland: the correlation coefficient was much higher on ploughing old grassland rather than leys. The N level dropped much more quickly in the first few years after ploughing old grassland than later. All single-property measurements give only a limited assessment of the physical state of a soil. Soils can be assessed satisfactorily only by making a range of measurements appropriate to the farming System.     

The Impact of Multiple Freeze–Thaw Cycles on the Microstructure of Aggregates from a Soddy-Podzolic Soil: A Microtomographic Analysis

With the help of computed X-ray microtomography with a resolution of 2.75 μm, changes in the microstructure and pore space of aggregates of 3 mm in diameter from the virgin soddy-podzolic soil (Glossic Retisol (Loamic)) in the air-dry, capillary-moistened, and frozen states after five freeze–thaw cycles were studied in a laboratory experiment. The freezing of the samples was performed at their capillary moistening. It was shown that capillary moistening of initially air-dry samples from the humus (AY), eluvial (EL), and illuvial (BT1) horizons at room temperature resulted in the development of the platy, fine vesicular, and angular blocky microstructure, respectively. The total volume of tomographically visible pores >10 μm increased by 1.3, 2.2, and 3.4 times, respectively. After freeze–thaw cycles, frozen aggregates partly preserved the structural arrangement formed during the capillary moistening. At the same time, in the frozen aggregate from the AY horizon, the total tomographic porosity decreased to the initial level of the air-dry soil. In the frozen aggregate from the EL horizon, large vesicular pores were formed, owing to which the total pore volume retained its increased values. The resistance of aggregate shape to the action of freeze–thaw cycles differed. The aggregate from the EL horizon completely lost its original configuration by the end of the experiment. The aggregate from the AY horizon displayed definite features of sagging after five freeze–thaw cycles, whereas the aggregate from the BT1 horizon preserved its original configuration.     

A comparative study of three methods of water removal prior to resin impregnation of two soils

The water in replicate samples from sub-surface horizons of a clayey and a fine-silty soil was removed either by oven-drying, freeze-drying or by acetone-replacement prior to resin impregnation. Pore space photograms (pores >60 μm diam.) from thin sections were analysed on a Quantimet 720 image analysing computer following each drying technique. During oven- and freeze-drying the clayey soil contracted considerably and subsequently satisfactory impregnation of these samples was either difficult or impossible. This macro-shrinkage caused a decrease in number and lengths of most planar pores and a decrease in size and number of all intra-aggregate pores. The loss in pore space and continuity obviously affected resin impregnation. The clayey samples in which water was replaced by acetone, and all samples of the silty soil, however pretreated, showed no measurable macro-shrinkage and all impregnated well. Oven-drying the silty soil appears to increase the porosity, causing an increase in size of all pores. A mechanism for this apparent enlargement is proposed. It is evident that acetone-replacement of the soil water prior to resin impregnation is the best of the three methods used here and should be seriously considered when image analysis is to be carried out on resin-impregnated blocks from soils of similar or related textures.     

Investigation into the fractal scaling of the structure and strength of soil aggregates

The hierarchical nature of soil structure is examined by measuring the physical properties of a range of aggregate sizes obtained using repetitive fracture. Fractals are used to assess the change with aggregate size of the specific volume, the proportion of pre-existing cracks which link to form the aggregate failure surface, and the aggregate failure stress. The pore size distribution, evaluated using mercury porosimetry and the application of the box counting algorithm to thin sections and thick sections, is also used to obtain a fractal dimension, D. Our results show that D depends upon the measurement approach for mass fractal scaling. This finding may limit the application of fractals to predict the scaling behaviour of soil physical properties.     

Mikrosonden- und Röntgenbeugungs-Untersuchungen an Tonbelägen von lessivierten Böden aus Löß

Microprobe and x-ray diffraction studies of clay coatings in leached soils derived from loess Point analyses of Si, Al, K, Mg, Ca, Fe, Mn, as well as of Zn and Pb of clay coatings in soil thin sections from illuvial horizons of four leached soils were carried out using an electron microprobe (EMA). The K, Mg, Si, and Al content, the Si/Al-molar ratio of coatings and XRD-analyses indicate that the clay coatings consist mainly of illitic clay minerals. This suggests either a mineral-specific displacement of illite or the formation of illitic clay coatings from migrated smectite or expanded illite (“illitization”) through subsequent K uptake. The clay coatings show, with the exception of Fe, Mn, Zn and Pb, only little variation in their chemical composition within the same horizon. Between the horizons of the investigated soils, however, distinct differences in the total element content, especially in the K content may occur. The strong vertical variation of the K content in clay coatings in some horizons is probably due to acidic conditions and lateral infiltration which lead to an increased weathering of illite and the depletion of K. The EMA results show that Pb is predominantly bound in Fe-Mn-Oxide coatings on the surface of clay minerals or in Fe-Mn-Oxide precipitates within clay coatings. Microanalyses of K depleted clay coatings indicate on the other hand an increased fixation of Zn in expanded illites.