Microstructure and Properties of the Dacromet Coating for 20 Steel

The Dacromet technology,which is a potential surface treatment method,has achieved extensive application in automobile industry.The Dacromet coating is prepared through dipping & curing process,and the microstructure and anticorrosion performance of zinc,aluminum galvanized specimens are comparatively investigated.The results shows that the zinc,aluminum,chromium distributed evenly and Zn/Al flakes overlapped and embedded in amorphous chromium binder in Dacromet coating which anticorrosion is superior to hot dip galvanized but slightly inferior to hot dip aluminum coating with lowered adhesion,its adhesive ability to matrix is weaker than that of aluminum coating.     

Effect of phytic acid modification AZ31 magnesium alloy on the cell surface adhesion property

Phytic acid coatings on the surface of AZ31 magnesium alloys are prepared by immersion method. Then cell culture and detection of cell survival rate on treated or untreated AZ31 magnesium alloy with phytic acid is carried out by the direct method and the indirect method respectively,and surface morphology and chemical composition of coatings are studied by scanning electron microscopy with energy dispersive spectrometer. The results show that uniform phytic acid coating forms on the surface of magnesium alloy,and there is a similar cell survival rate on the treated or untreated AZ31 magnesium alloy surface. But the adhesive ability of cells on the surface of phytic acid modification magnesium alloy is significantly different. Phytic acid modification can effectively improve the cell adhesion properties of AZ31 magnesium alloy.     

Formation Model of Alumina in the Course of Directed Oxidation of Aluminum Magnesium Alloy

By analyzing the characteristics of magnesium volatilization and linear growth kinetic of Al/ Al_2O_(3 )in directed oxidation of Al-Mg alloy, as the formation process of MgO is considered to be the process of which Al_2O_(3)dissolved in the scale MgO and MgO is partially n-type oxide, formation condition of Al_2O_(3)is established easily in the coure of oxidation. Volatilization of magnesium is to promote the growth of p-type MgO in the surface layer and the formation of Al_2O_(3 )in the inner layer of n-type MgO, and to promote the transformation of MgO toMgAl_2O_(4).MgAl_2O_(4)plays an important role in the formation process of Al_2O_(3), growth stress between MgO and MgAl_2O_(4)cause the formation of cavity in the MgAl_2O_(4 )and aluminum alloy melts is easier to transfer to oxidation front by means of this cavity. The transformation velocity ofMgO to MgAl_2O_(4 )depends on growth kinetic of Al_2O_(3),the faster transformation velocity of MgO to MgAl_2O_(4)is main reason that growth kinetic of Al/Al_2O_(3)transformation exhibits linear relationship.     

Review on the Research of High-strength Wrought Magnesium Alloy ZK60

ZK60 magnesium alloy is one of high-strength wrought magnesium alloys. Owing to its high strength and low density, it has nearly the highest strength to density ratio among existing materials. Because its strength approximates to high-strength aluminum alloy 7075, it has promising application future. The history of magnesium alloy ZK60 and researches on its microstructure, mechanical properties, surface treatment, and the effects of alloy elements and microelements are reviewed . Further more, the authors put forward methods to improve its microstructure and mechanical properties and prospected the development future of this alloy in the aspects of surface treatment and application.     

LASER REMELTING OF THE NiCoCrAlY PROTECTIVE COATING

NiCoCrAlY protective coating is remelted on the GH140 alloy surface by 2KWCO2 gas laser,the results of which show that,by controlling proper laser technological parameters, the constitution can be fined,the composition can be well distributed,and the coating compactness and adhesion can be obviously enhanced in the laser-remelting zone. Thus,corrosion resistance and thermal fatigue resistance is effectively improved,and the good plasticity of the original coating is remained.     

中子辐照对锆合金显微组织的影响研究进展

作为反应堆的第一道安全屏障，锆合金包壳材料的显微组织一直是国内外的研究热点。针对目前国内外在中子辐照对锆合金显微组织的影响研究领域现状进行了综述，总结了现有研究的不足并提出了对未来研究方向的建议：采用微观分析手段，针对不同中子注量下锆合金包壳的第二相、氢化物和氧化膜展开研究，获得其在实际使用工况下的演变规律，为我国锆合金包壳材料的优化改进提供支撑。     

Current Status of DIMOX in Synthesizing Al/Al2O3 by Aluminum Alloy

The processes, microstructures, properties and mechanisms of DIMOX in synthesizing Al/Al 2O 3 by Al-Mg-Si alloy are reviewed and their problems are considered mainly as following:non_homogeneous oxidation growth of Al/Al 2O 3 at the surface of melts and the porosity of Al/Al 2O 3 limites structural application of Al/Al 2O 3 composite. The mechanisms and models of microchannel,magnesium action,silicon action,and induction are outlined. Several problems which need to be noticed are pointed out,which are diffusion and transfer of oxygen in aluminium melts;the role of MgO and MgAl 2O 4 at outer layer;the reaction feature of solid_gas in the oxidation microstructures of Al_Mg_Si alloy;SiO 2 induction mechanism of silicon and its correlation with the mechanism of magnesium action in Al_Mg_Si alloy.     

Loading behavior analysis of an aluminum alloy roof structure system under wind loads

The numerical analysis of a conventional aluminum alloy roof system taken from an actual international airport under wind uplift is conducted. A two-step simulation analysis approach is proposed, which effectively overcomes the computational difficulties brought by the contact between panels and supports. Through numerical analysis of roof components, the failure mode of the roof connection and the load bearing capacity of the roof are obtained. And the efficiency of material strength in each component is evaluated as well. It can provide reference for the design and application of aluminum alloy roof structure.     

Calculation of Fatigue Reliable Life of Natural Gas Pipeline

Various defects and cracks may be produced in the welding process in natural gas pipeline.Under variable pressure of natural gas,the cracks will be propagated it may lead to break and invalidity.The effect of internal surface cracks are more serious.It has been researched that the propagation along radial direction of internel surface cracks in the natural gas pipeline.The fatig life of pipeline has been calculated.On the other hand,considering the size of cracks, pressure of gas and character of material are random variable,and by using reliability method,the fatig reliable life of pipeline has been determined.This method has some practical value in design, working and overhaul of pipeline.     

生物质可降解地膜的田间降解过程及其对玉米生长的影响

为了有效解决农业白色污染和固体废弃物处理问题,通过使用实验室自制生物质可降解地膜进行了田间覆膜试验,研究了生物质可降解地膜的田间降解过程及其对玉米生长的影响。结果表明：生物质降解地膜的降解过程为首先出现裂纹,然后出现孔洞,最后出现裂缝,中间伴随着地膜变脆,变薄,膜表面出现黑霉的过程,经过120天的降解,地膜的失重率达到69%~73%,SEM照片显示降解地膜表面发生明显变化。在玉米生长的前期和中期,生物质降解地膜具有良好的保温和保墒作用,保温效果可维持50天左右,保墒作用可维持70天左右,均能满足农作物生长期的需要。生物质降解地膜富含多种有机质和营养元素,有利于玉米的生长,可以提高玉米产量8%左右。说明生物质降解地膜降解性良好并可显著促进玉米生长。     

Effects of the Seed Film Coating Salicylic Acid on the Chilling Tolerance of Cotton Seedlings

The objective of this study was to investigate the effect of the different concentrations of the seed film coating salicylic acid on the cold tolerance of cotton seedlings using the sand culture method. The physiological response of cell membrane permeability, protective enzyme activity and osmotic adjustment of cotton seedling were measured before and after at low temperature stress and at normal temperature. The results showed that 1-10 mmol·L^－1 of seed film coating with salicylic acid seed coating treatment could effectively alleviate damage to cotton seedlings at low temperature, and the accumulation of the relative electrical conductivity and malondialdehyde were reduced on cotton seedlings. The activity of superoxide dismutase, peroxidase, catalase, and soluble protein, soluble sugar and proline contents increased sharply. These results indicate that film coating with salicylic acid can alleviate the effects of low temperature stress on seedling growth inhibition and improve the cotton seedlings by providing chilling tolerance, and the optimum treatment concentration salicylic acid is 5 mmol·L^－1.     

Advance in Spray Forming Technology and Its Prospect

Spray Forming technology gets involved with new materials preparation techniques in multiple domains such as powder metallurgy, fluent metal atomization, rapid cooling and non-equilibrium solidification. High performance alloy and metal matrix composite with high density, low oxygen content and microstructure featuring rapid solidification can be fabricated by spray forming. Spray forming, which is of short process flow, low cost, high deposition efficiency, flexible manufacture system, becomes a kind of near shape forming and rapid solidification technology with great prospect. Therefore the developing process history of spray forming technology is introduced and the current research and development status of spray forming technology in the fields of aluminum alloy, steel material, magnesium alloy, copper alloy and high temperature alloy and metal matrix composite is described. Multi-layer spray forming and in-situ reaction atomization spray forming are also discussed. In addition, evaluation and prospect for the technology are presented.     

IN SITU SPECTROELECTROCEMISTRY AND ITS APPLICATIONS ON CONVENTIONAL FT-IR SPECTROMETER

In situ spectroelectrochemistry on a conventional FT-IR spectrometer and its applications in the following fields are briefly described: electrochemical reactions in solution, the determinations of formal potential ( E01 ) and electron transfer number ( n ) , chemically modified electrode film, the oxidation, corrosion and inhibition on metal surface.     

复合型缓释肥包衣剂理化性质及缓释特性研究

为了探明复合型缓释肥包衣剂的理化性质及其缓释特性,对复合型缓释肥包衣剂的粘度、成膜性、成膜时间、膜韧性、包衣脱落率、包衣肥的养分初期溶出率、养分微分溶出率、养分累积释放曲线等进行了测定。理化性质测试结果显示：缓释肥包衣剂的粘度为44.5 MPa/s、成膜性良好、成膜时间7 min、包衣膜拉长倍数达2.8倍,包衣脱落率< 5%。缓释特性测试结果显示：包衣肥养分N、P、K初期溶解率< 15%、微分溶解率< 2%,符合中国《缓释肥料》标准GB/T23348-2009。其中P的初期溶解率小于N、K的初期溶解率,而N、P、K微分溶解率相差不大。养分累积释放曲线大致呈“S”型,与作物生长需肥规律一致。表明复合型缓释肥包衣剂的理化性质良好,能有效控制普通复合肥养分的缓释。     

Sliding friction test analysis of TiAlN/TiN coatings on 40Cr steel

TiAlN/TiN duplex coating is made on the surface of 40Cr steel by means of multi-arc ion plating technology. Carrying capacity and tribological properties of TiAlN/TiN duplex coating are investigated with a UMT-2 wear tester without lubrication. The surface morphology of wear specimens are observed by scanning electron microscope(SEM). Elements of wear scar center and their content are analyzed by EDS. Tribological properties of TiAlN/TiN coating are evaluated through comparing with 40Cr in friction coefficient and wear volume. The results show that tribological properties of TiAlN/TiN duplex coating is better than 40Cr. The TiAlN/TiN films is superior in reducing friction and wear resistance, and can successfully resist abrasive wear and adhesive wear.     

Experimental Investigation on Buckling Behaviors of Irregularly Shaped Aluminum Alloy Structural Components Under Axial Compression Load

The experimental and numerical investigations on buckling behaviors of aluminum alloy components with different irregularly shaped sections were carried out. The buckling load carrying capacity obtained through experiments, numerical simulations, and equations described in the design code were compared. Results obtained through experiments and numerical simulations in good agreement, which shows the validation of the numerical model. And the validated FEM model will be used for parametric analysis of buckling behavior of irregularly shaped aluminum alloy structural component. Equations in the design code do not include effects of the buckling type and need to be improved further.     

壳聚糖复合涂膜对杏鲍菇保鲜效果的研究

【研究目的】杏鲍菇在采后易失水褐化等原因降低食用及商品价值,为延长其货架期,需筛选出适于杏鲍菇的壳聚糖复合涂膜。【方法】该实验以杏鲍菇（Pleurotus eryngii）为研究材料,在室温（22±2℃）条件下,以去离子水浸涂杏鲍菇为对照,采用不同的壳聚糖复合涂膜处理进行保鲜实验,通过L9（33）正交试验筛选杏鲍菇保鲜的最佳复合涂膜配方,并研究其生理效应。【结果】结果表明,与对照相比,筛选出的最佳壳聚糖复合涂膜液能够有效降低杏鲍菇的褐变程度与含水率,延缓游离氨基酸含量、可溶性蛋白含量、可溶性总糖等各指标的变化幅度,保鲜效果达到显著水平（P＜0.05）。【结论】适于杏鲍菇的壳聚糖复合涂膜的配比为1.5%的壳聚糖+1.0%的乙酸+0.03%的吐温20+3.0%的甘油,该涂膜起到延缓杏鲍菇采后衰老,保持较好的营养价值和加工风味,达到保鲜目的。     

枇杷果实采后处理对保鲜效果的影响

试验目的是调查包装、涂膜和低温贮藏对枇杷果实的保鲜效果,并对枇杷果实的失重率、褐变率及贮藏期的影响进行探讨。试验表明,涂膜包装贮藏能降低失重率和褐变率;贮藏40天后,好果率仍达80%以上。     

复合纳米光催化环保涂料制备及其超临界CO2喷涂研究Ⅱ——复合纳米光催化剂-氟碳树脂涂料制备及超临界CO2喷涂

对纳米SO42-/TiO2-（Ag、Fe）有机包覆研究表明,用钛酸酯偶联剂对纳米SO42-/TiO2-（Ag、Fe）粒子进行有机包覆处理,能有效地增强无机TiO2基粒子在有机涂料体系中的分散性和稳定性,为光催化环保涂料的制备奠定基础。对复合纳米SO42-/TiO2-（Ag、Fe）光催化环保涂料的组成配比试验结果表明：光催化剂添加量为6%时适宜;在14 MPa、60℃下用孔径为0.4 mm的喷嘴对CO2含量为30%的复合SO42-/TiO2-（Ag、Fe）氟碳树脂涂料进行喷涂,喷涂过程有机物排放量降低了43.5%,所得涂膜对罗丹明-B降解速率常数为3.84× 10^-2S^-1,比用普通刷涂提高了17.8%。该涂膜还能将甲基橙、品红、苯酚等多种难降解的有机物彻底矿化,且经5次重复使用,光催化活性无明显下降,在可见光下反应140 min就能将罗丹明-B完全矿化。     

壳聚糖成膜剂包衣性能及对油松种子萌发的影响

成膜剂是种衣剂的重要助剂及关键的功能性成分,壳聚糖的良好成膜性和生理活性,在种衣剂中具有重要应用价值。本文以油松为研究对象,通过制备0.2%和0.5%壳聚糖单膜溶液以及壳聚糖-聚乙烯醇和壳聚糖-纳米TiO2不同配比复合成膜剂,进行包衣性能测定和种子萌发安全性试验,筛选适合油松种子包衣的最佳配方。结果表明,对于油松种子壳聚糖成膜剂及复合成膜剂均能够快速成膜,其中复合成膜剂在成膜性、抗水溶能力以及包衣脱落率表现更优;不同成膜剂配方对种子发芽势、发芽率和活力指数影响显著,具有促进种子萌发作用;综合分析得出最佳成膜剂配方是0.2%壳聚糖+0.03 g纳米TiO2,最佳配方使成膜剂包衣性能有明显提高,并且与CK相比,发芽率、发芽势、发芽指数和活力指数分别提高了22%、64%、15%、59%。