Improvement of physical and hydraulic properties of desert soil with amendment of different biochars

Purpose

The objective of this study was to investigate the effects of amendment of different biochars on the physical and hydraulic properties of desert soil.

Materials and methods

Biochars were produced with woodchip, rice straw, and dairy manure at temperatures of 300 and 700 °C, respectively. Each biochar at 5% (w/w) was mixed with desert soil, and the mixtures were incubated for 120 days.

Results and discussion

The different biochar treatments greatly reduced soil bulk density and saturated hydraulic conductivity. Especially the rice straw biochar addition resulted in the lowest saturated hydraulic conductivities among the treatments. Biochar addition significantly increased water retention of desert soil at any suction. At the same suction and experimental time, the treatment with the rice straw biochar produced at the lower temperature resulted in higher water content than the other treatments. The biochar additions slightly enhanced formation of soil macro-aggregates in the early experimental time. However, the aggregate contents gradually decreased with time due to the lack of effective binding agents (e.g., soil organic matter and clay minerals).

Conclusions

The changes of hydraulic properties of desert soil were attributable to the biochar properties. The higher fine particle content, porosity, and surface hydrophilicity of rice straw biochars were the most beneficial properties to increase soil water retention and to reduce water flow in the desert soil. The improvement of hydraulic properties by biochar addition may provide a potential solution to combat desertification.

     

Suitability of a hydraulic‐conductivity model for predicting salt effects on swelling soils

Many empirical approaches have been developed to analyze changes in hydraulic conductivity due to concentration and composition of equilibrium solution. However, in swelling soils these approaches fail to perform satisfactorily, mainly due to the complex nature of clay minerals and soil–water interactions. The present study describes the changes in hydraulic conductivity of clay (Typic Haplustert) and clay‐loam (Vertic Haplustept) soils with change in electrolyte concentration (TEC) and sodium‐adsorption ratio (SAR) of equilibrium solution and assesses the suitability of a model developed by Russo and Bresler (1977) to describe the effects of mixed Na‐Ca‐Mg solutions on hydraulic conductivity. Four solutions encompassing two TEC levels viz., 5 and 50 mmol_c L^–1 and two SAR levels viz., 2.5 and 30 mmol^1/2 L^–1/2 were synthesized to equilibrate the soil samples using pure chloride salts of Ca, Mg, and Na at Ca : Mg = 2:1. Diluting 50 mmol_c L^–1 solution to 5 mmol_c L^–1 reduced saturated hydraulic conductivity of both soils by 66%, and increasing SAR from 2.5 to 30 mmol^1/2 L^–1/2 decreased saturated hydraulic conductivity by 82% and 79% in clay and clay‐loam soils, respectively. Near saturation, the magnitude of the change in unsaturated hydraulic conductivity due to the change in TEC and SAR was of 10³‐ and 10²‐fold, and at volumetric water content of 0.20 cm³ cm^–3, it was of 10¹⁴‐ and 10⁶‐fold in clay and clay‐loam soils, respectively. Differences between experimental and predicted values of saturated hydraulic conductivity ranged between 0.6% and 11% in clay and between 0.06% and 2.1% in clay‐loam soils. Difference between experimental and predicted values of unsaturated hydraulic conductivity widened with drying in both soils. Predicted values were in good agreement with the experimental values of hydraulic conductivity in clay and clay‐loam soils with R² values of 0.98 and 0.94, respectively. The model can be satisfactorily used to describe salt effects on hydraulic conductivity of swelling soils in arid and semiarid areas, where groundwater quality is poor.     

Salinity and sodicity induced changes in dispersible clay and saturated hydraulic conductivity in sulfatic soils

Abstract

Irrigation is becoming a more commonly used practice on glacially derived soils of the Northern Great Plains. Threshold salinity and sodicity water quality criteria for soil‐water compatibility in these sulfatic soils are not well defined. This study was conducted to relate soil salinity and sodicity to clay dispersion and saturated hydraulic conductivity (K_sat) in four representative soils. Soil salinity (EC treatment levels of 0.1 and 0.4 S m^‐1) and sodicity (SAR treatment levels of 3, 9, and 15) levels were established to produce a range of conditions similar to those that might be found under irrigation. The response of each soil to changes in salinity and sodicity was unique. In general, as sodicity increased clay dispersion also increase, but the magnitude of the increase varied among the soils. In two of the soils, clay dispersion across a range of sodicity levels was lower under the 0.4 S m^‐1 treatment than under the 0.1 S m^‐1 treatment and in the other two soils, clay dispersion across a range of sodicity levels was similar between the two salinity treatments. Changes in K_sat were greatest in the finer textured soil (decreasing an order of magnitude across the range of sodicity levels), but was unchanged in the coarse textured soils. Results suggest that these sulfatic soils are more susceptible to sodicity induced deterioration than chloridic soils. These results and earlier field observations suggest that sustainable irrigation may be limited to sites with a water source having a SAR <5 and an EC not exceeding 0.3 S m^‐1 for these sulfatic glacially derived soils.     

Soil hydraulic and physico-chemical properties of Ultisols and Inceptisols in south-eastern Nigeria

Understanding soil water dynamics and storage is important to avoid crop failure on highly weathered, porous and leached soils. The aim of the study was to relate soil moisture characteristics to particle-size distributions and chemical properties. On average, Atterberg limits were below 25% in the A-horizon and not more than26.56% in the B-horizon, whereas soil bulk density was between 1.27 and 1.66Mgm^?3. The saturated hydraulic conductivity (K_sat) was generally between 0.20 and 5.43 cm h^?1 in the top soil and <1.31 cm h^?1 in the subsoil. The higher K_sat values for the A-horizons were attributed to the influence soil microorganisms operating more in that horizon. The amount of water retained at field capacity or at permanent wilting point was greater in the B-horizons than in the A-horizons, suggesting that clay accumulation in the B-horizon and evapotranspiration effects in the A-horizon may have influenced water retention in the soils. Soil moisture parameters were positively related to clay content, silt content, exchangeable Mg²⁺, Fe₂O₃ and Al₂O₃, and negatively related to sand content, SiO₂, sodium absorption ratio, exchangeable sodium percentage and bulk density. The low clay content may explain why drainage was so rapid in the soils.     

Applicability of cavity-throat connecting model for estimating the hydraulic conductivity of fine-grained soils: a geometrical and mathematical approach

Purpose

Determining the hydraulic conductivity of low permeable fine-grained soils is difficult and time-consuming. This work develops a new method with an eye to the pore morphology to correlate hydraulic conductivity with pore-size distribution (PSD) parameters obtained from mercury porosimeter data. In order to realize this method, calculating percolation loss along the flow paths in pore channels and quantifying the spatial morphology of pore channels by proposing a cavity-throat connecting model is necessary.

Materials and methods

In order to establish the standard process of the new method, a kind of sedimentary mucky clay with regular dual-structural PSD has been collected. The samples are divided into three series: (a) vibrated with variable frequencies; (b) frozen at variable temperatures and unfrozen, making the freezing-thawing effect as the variable; and (c) remolded with different water contents. The PSD of freeze-dried samples at the end of each process is obtained by mercury intrusion porosimetry. After that, the method is demonstrated with application to 12 series of fine-grained soils.

Results and discussion

Deduced from mercury porosimeter data, the volume-based PSD curves of fine-grained soils are bimodal, due to the presence of inter-aggregate and intra-aggregate pores. Two important hypotheses have been proposed: (i) one is that in the smaller pore scales, the experimental extrusion curve controlled by the hysteresis loop has a really approximate part compared to the theoretical overall retraction curve, making the experimental extrusion curve characterize the pore cavity size approximately, and (ii) the pore system consists of a series of multistage cavity-throat connections. Accumulating the effects of single connection on the percolation can be used to measure the overall effects of pore system on the percolation. Based on fluid-driven path analysis of percolation, the pore system is quantified by a series of cavity-throat connections and the percolation loss has been derived to estimate the hydraulic conductivity.

Conclusions

The permeable parameter (κ) representing the overall effects of pore connections on the hydraulic conductivity (K) is suited to correlate the microstructure and hydraulic conductivity by the linear relationship with the fixed slope in semilogarithmic coordinate for the fine-grained soils. It is the destruction and recombination of cavity-throat connections that are dominant during the treatments like freezing, remolding, and reinforcing.

     

Evaluating the Impact of Combined Application of Biochar and Compost on Hydro-physical Properties of Loamy Sand Soil

ABSTRACT

Biochar, compost and their combination are important organic amendment materials for improving the hydro-physical properties of sandy soils. Series of soil columns experiments were conducted for investigating the application effects of date palm biochar and compost on evaporation, moisture distribution, infiltration, sorptivity (Sp), saturated hydraulic conductivity (K_sat) and water holding capacity (WHC) at application rates of 1%, 2%, 3% and 4% (10, 20, 30 and 40 g kg^?1). The columns were filled manually with air-dried soil with 35 cm depth and the thickness of surface amended layer was 10 cm (T10) and 20 cm (T20) from soil surface at bulk density of 1400 kg m^?3. The results showed that the behavior of soil moisture distribution was influenced by application of biochar, compost and biochar-compost mixture. Moreover, in the amended layer T10, applying biochar at rate of 1%, 2%, 3% and 4% reduced significantly cumulative evaporation by 5.8%, 10.8%, 12.8% and 16.1%, respectively. Meanwhile, the reduction for the biochar-compost mixture at application rates of 1%, 2%, 3% and 4% was 10%, 12.2%, 14.5% and 20%, respectively. In layer T20, applying biochar at rate of 1%, 2%, 3% and 4% reduced cumulative evaporation by 10.24%, 13.0%, 18.3% and 21.5% but this reduction amounted to 18.2%, 21%, 23% and 24% for the biochar-compost mixture, respectively. It was generally observed that the highest application rate (4%) for applied amendments was the most effective impact on Sp, K_sat and WHC compared with other rates.     

Potentially hazardous element accumulation in rice tissues and their availability in soil systems after biochar amendments

Purpose

Biochar has shown to be a great product to control the bioavailability of potentially hazardous elements (PHE) in contaminated soils. Despite the advantages associated with the application of biochar in agricultural soils, relatively few studies have focused on the effects of biochar amendments on soil chemical properties, accumulation of arsenic, cadmium, zinc, and lead in rice tissues, and their availability in soil systems.

Materials and methods

The field experiment was conducted at the paddy soils in Hunan Province, China. The soil texture was sandy clay loam. Wheat-derived biochar was applied once to the experimental plots at the rates of 0, 10, 20, 30 and 40 t ha^?1, and referenced as A0, A10, A20, A30, and A40, respectively. For PHE determination, soil samples and plant samples were digested with a mixed solution of HCl:HNO₃ (4:1, V:V) and HCl:HClO₄ (4:1, V:V), respectively, and the arsenic, cadmium, zinc, and lead in the digest solution were measured by ICP-MS (Thermo Fisher Scientific, USA). The soil available fraction of PHE (arsenic, cadmium, zinc, and lead) was extracted by diethylenetriamine pentaacetic acid (DTPA) and measured by inductively ICP-MS.

Results and discussion

Biochar amendment increased chemical properties of soil organic matter, pH, electrical conductivity, cation exchange capacity, nitrate nitrogen, and available phosphorus. Soil DTPA extractable arsenic, cadmium, zinc, and lead concentrations were significantly reduced. Arsenic, cadmium, zinc, and lead in rice shoots, and arsenic, cadmium, and zinc in roots significantly decreased after amendment. Concentrations in rice tissues positively and negatively correlated with the soil available fraction of PHE and soil chemical properties, respectively. Soil electrical conductivity negatively correlated with the soil available fraction of PHE. Concentrations of arsenic, zinc, cadmium, and lead in rice roots declined relative to increases of cation exchange capacity (arsenic, zinc), available phosphorus (cadmium), and nitric nitrogen (lead) content. Similar relationships were observed between cation exchange capacity and PHE in shoots.

Conclusions

Biochar creates avoidance of PHE through regulating chemical properties through biochar sorption capacity. Cation exchange capacity, available phosphorus, and nitric nitrogen were the principle factors affecting roots uptake of arsenic, zinc, cadmium, and lead. Biochar soluble salts could decline availability of metals/metalloids in soils through precipitation. Wheat-derived biochar application is an alternative safe product to immobilize PHE in rice paddy soils by restricting the risk of PHE.

     

Effects of biochar and phosphorus fertilizer rates on soil physical properties and wheat yield on clay textured soil in middle Nile Delta of Egypt

ABSTRACT

Biochar has not been adequately used by farmers to improve the clay textured soil productivities in the world. Therefore, the objective of this study is to investigate the effect of the co-application of biochar with different rates of phosphorus (P) fertilizer on selected soil physical properties and wheat yield on clay textured soil over two growth seasons. Biochar treatments occupied the main plots at a rate of 0.0 and 10 t ha^?1, while the sub-plots were devoted to phosphorus rates at rates of 0%, 50%, 100%, and 150% of recommended P fertilizers. Biochar (10 t ha^?1) and P at different rates decreased soil bulk density significantly. Meanwhile, it increased aggregate stability, saturated hydraulic conductivity and soil water retention significantly at (p < .05), and it improved the grain yield of wheat. More grain yields in the soil treated with biochar than untreated soil under all P application rates for both years were probably caused partially by more nutrients (N, P, and K) were applied from biochar itself. Grain yield of wheat in the soil-amended biochar and P did not increase significantly between the application at 50%, 100% and 150% P. The results of this study indicate that phosphorus blends with biochar can be used to decrease the bulk density of clay textured soils and to improve crop production in these soils.     

Anisotrope Variation der gesättigten Wasserleitfähigkeit einer unterschiedlich beweideten Salzmarsch im Deichvorland

Anisotropic variation of saturated hydraulic conductivity of a variously grazed salt marsh soil Undisturbed core samples were taken in horizontal and vertical direction from a variously grazed salt marsh soil for investigation of the anisotropic variation of saturated hydraulic conductity K_sat, bulk density, and pore size distribution. The results show that saturated hydraulic conductivity varies significantly anisotropically. The average Kv/Kh ratio is 0.38 for the soil profile and 0.44 for the surface soil. This anisotropy of K_sat is mainly attributed to the stratified structure of soil due to the sedimentation conditions in the salt marsh environment and decreases if soil structure development through pedological processes progresses. Furthermore. K_sat decreases significantly if the stocking rate of grazing is larger than 1.0 sheep unit/ha and the effect is more pronounced near the dike. However, both the Kv and Kh are affected by grazing in the same manner, so that the anisotropy of K_sat is independent from grazing. Bulk densitiy and macroporosity are affected by grazing but not by the direction of sampling. There are significant correlations between K_sat and > 50 μm as well as > 10 μm pore volume. The correlation between K_sat and total porosity is however not significant. The anisotropy of K_sat implicates the favouring of the lateral water flux and in the hydrological research and modelling of the salt marsh ecosystem the anisotropy of K_sat should be taken into account.     

Changes in selected soil physical properties caused by sodicity of soil and irrigation water

Abstract

Sodic water and spring water percolated through clay, clay loam, and sandy loam (SL) soils with exchangeable sodium percentages (ESPs) of 0, 10, 30, and 50. Reduction in saturated hydraulic conductivity and water stable aggregates recorded at higher ESPs. At ESP ≈30, application of sodic and spring water to clay soil (C) reduced saturated hydraulic conductivity from 1.2 to 3 mm hr^?1, whereas in SL soil, the values were 2.8 and 6.2 mm hr^?1, respectively. Results indicated that at any ESP and water source, the highest free swelling obtained was in the C soil. This study has practical importance to the management of irrigation water quality with respect to soil deterioration.     

Effect of compaction on pore functions of soils in a Saalean moraine landscape in North Germany

Soil compaction and related changes of soil physical parameters are of growing importance in agricultural production. Different stresses (70, 230, 500, and 1000 kPa) were applied to undisturbed soil core samples of eight typical soils of a Saalean moraine landscape in N Germany by means of a confined compression device to determine the effect on (1) total porosity/pore‐size distribution, (2) saturated hydraulic conductivity, and (3) air conductivity to assess the susceptibility towards compaction. Different deformation behaviors after exceeding the mechanical strength particularly resulted from a combination of soil characteristics like texture and initial bulk density. The saturated hydraulic conductivity, as an indicator for pore continuity, was largely affected by the volume of coarse pores (r² = 0.82), whereas there was no relationship between bulk density and saturated hydraulic conductivity. Since coarsely textured soils primarily possess a higher coarse‐pore fraction compared to more finely textured soils, which remains at a high level even after compaction, only minor decreases of saturated hydraulic conductivity were evident. The declines in air conductivity exceeded those in hydraulic conductivity, as gas exchange in soils is, besides the connectivity of coarse pores, a function of water content, which increases after loading in dependence of susceptibility to compaction. A soil‐protection strategy should be focused on more finely textured soils, as stresses of 70 kPa may already lead to a harmful compaction regarding critical values of pore functions such as saturated hydraulic conductivity or air capacity.     

生物质炭对土壤物理性质影响的研究进展

生物质炭在农业与环境中的应用已成为近期国内外研究热点,有关生物质炭特性以及生物质炭对土壤化学、生物学性质和作物产量的影响,已经有一些综述,但是生物质炭对土壤物理性质影响的相关综述很少。本文对近10年生物质炭对土壤物理性质影响相关的研究成果进行了整理分析。研究结果发现生物质炭可以降低土壤容重,提高土壤团聚体稳定性,增加田间持水量和土壤有效水含量,降低饱和导水率等。生物质炭影响土壤物理性质的主要原因是生物质炭具有较大的比表面积和孔隙度。此外,生物质炭与土壤矿质颗粒结合,并通过对土壤微生物活性和植物生长的影响间接影响土壤物理性质。生物质炭对土壤物理性质的影响与多种因素有关,如生物质炭原料、裂解温度、施用量和颗粒大小,土壤质地和处理时间等。关于生物质炭对土壤物理性质影响的长期研究很少,且缺乏田间试验。因此,将来的研究应更加倾向于长期田间条件下生物质炭对土壤物理性质的影响,并逐渐发现生物质炭的作用机理,为实际的农业生产和生态治理提供科学依据。     

生物炭对沙质土水分蒸发和导水率的影响

Biochar, as a kind of soil amendment, has important effects on soil water retention. In this research, 4 different kinds of biochars were used to investigate the influences of biochar addition on hydraulic properties and water evaporation in a sandy soil from Hebei Province, China. Biochar had strong absorption ability in the sandy soil. The ratio of water content in the biochar to that in the sandy soil was less than the corresponding ratio of porosity. Because of the different hydraulic properties between the sandy soil and the biochar, the saturated hydraulic conductivity of the sandy soil gradually decreased with the increasing biochar addition. The biochar with larger pore volume and average pore diameter had better water retention. More water was retained in the sandy soils when the biochar was added in a single layer, but not when the biochar was uniformly mixed with soil. Particle size of the added biochar had a significant influence on the hydraulic properties of the mixture of sand and biochar. Grinding the biochar into powder destroyed the pore structure, which simultaneously reduced the water absorption ability and hydraulic conductivity of the biochar. For this reason, adding biochar powder to the sandy soil would not decrease the water evaporation loss of the soil itself.     

Anisotropy of pore functions in structured Stagnic Luvisols in the Weichselian moraine region in N Germany

In order to determine if soil hydraulic properties present a direction‐dependent behavior, undisturbed samples were collected at different horizons and orientations (vertical, diagonal [45°], and horizontal) in structured soils in the Weichselian moraine region in northern Germany. The water‐retention curve (WRC), the saturated hydraulic conductivity (k_f), and the air permeability (k_a) were measured. The air‐filled porosity (?_a) was determined, and pore‐continuity indices (k_a/?_a, k_a/?_a², N) and blocked porosities (?_b) were derived from the relationship between k_a and ?_a. The development of soil structures with defined forms and dimensions (e.g., platy by soil compaction or prismatic up to subangular‐blocky by swelling–shrinkage processes) and the presence of biopores can induce a direction‐dependent behavior of pore functions. Although the pore volume as a scalar is isotropic, the saturated hydraulic conductivity and air permeability (as a function of air‐filled porosity) can be anisotropic. This behavior was observed in pore‐continuity indices showing that the identification of soil structure can be used as a first parameter to estimate if hydraulic properties present a direction‐dependent behavior at the scale of the soil horizon.     

Change of dry bulk density and Ksat after incubation of a soil in the presence of organic amendments

Abstract

Kamouraska Ap horizon samples were incubated in the presence of organic amendments, peat moss, straw, compost and green manure, applied at a rate equivalent to 7.5 t of carbon/ha. Water was added to reach 80% of field capacity. The soil‐amendement mixtures were incubated at 37°C for periods of 4, 8, 16, 32 or 64 weeks. Settling tests were performed using a jolting volumeter. Minimum dry bulk density (mDBD), saturated hydraulic conductivity (K_sat) and water content at field capacity were determined. For the unamended soil, mDBD corresponded to 1.1 g.cm^‐3 and K_{sat max} to 265 cm/h. After incubation, mDBD varied from 1.02 to 1.12 g.cm^‐3 and K_{sat max} values were generally below 150 cm/h. The results were discussed in relation to the decomposition of the organic amendments and the formation of stable aggregates.     

Effects of organic carbon and clay contents on structure-related properties of arable soils with high clay content

Understanding of factors governing soil structural features is necessary for managing key processes affecting crop productivity and environmental impacts of agriculture, for example, soil water balance, aeration, and root penetration. Organic matter is known to act as a major binding agent in soil aggregation and thus constitutes a central pillar in soil structure formation. However, knowledge of the structural role of organic matter or carbon (OC) in soils highly rich in clay-sized particles (<0.002 mm) is limited. In this study, the effects of clay and OC contents on aggregate stability, water holding capacity, near-saturated hydraulic conductivity, total porosity, and pore size distribution were assessed in cultivated fields with high clay content located in private crop production farms in southern Finland. Significant positive correlations were found between OC content and proportion of water stable aggregates and specific pore sizes from the range of 30 μm up to 1 mm diameter determined by image analysis. Porosities on a smaller size range derived from water retention measurements likewise showed a positive correlation with OC in <0.2 μm sizes. On the range of 0.2–1 μm, a negative relationship was observed, which induced a negative effect of OC on soil plant available water reserves. In line with the positive correlation between OC and larger soil pores, free water, representing the amount of water that can be drained by gravity, exhibited a positive relationship with OC suggesting that OC content can enhance aeration of soils with high clay content. Compared to OC, clay content tended to have an adverse effect on soil structural properties. Clay correlated negatively with pores larger than 30 μm, free water content, and extrapolated field saturated hydraulic conductivity. Further, our imaging results showed how saturated hydraulic conductivity was controlled by pore morphology, and there was a power law relationship between the conductivity and critical pore diameter. $K\propto d_c^2$ in agreement with the percolation theory. Overall, the structural impacts and hydrological implications of OC and clay in heavy clay soils vary by pore size ranges and their emergent practical impacts are thus not straightforward.     

牧草品种与生物质炭对植草土壤水分的调控效应

[目的]研究不同牧草品种种植与生物质炭施用对土壤水分的影响及其调控效应,为喀斯特石漠化区生态恢复及土壤改良提供科学依据。[方法]采用盆栽试验在施用生物质炭的土壤上种植雀稗(Paspalum thunbergii)、黑麦草(Lolium perenne)、拉巴豆(Dolichos lablab),定期测定植草土壤的含水率。[结果]种植雀稗、黑麦草、拉巴豆后土壤田间持水量及土壤饱和导水率均出现显著性差异,其大小顺序为:雀稗黑麦草拉巴豆,禾本科牧草种植对提高土壤持水性能的作用优于豆科牧草。施用5%的生物质炭后,雀稗、黑麦草、拉巴豆种植土壤的含水率在春夏季降雨及干旱时段均出现不同程度的增加,植草土壤田间持水量和饱和导水率则出现显著地提高,其大小顺序也为:雀稗黑麦草拉巴豆。[结论]生物质炭施用明显地提高了土壤持水能力,从而有利于牧草生长。     

Remediation of saline-sodic soil using organic and inorganic amendments: physical,chemical, and enzyme activity properties

Purpose

Crops grow poorly in saline-sodic soils, and the productivity of these soils can be dramatically improved with proper amendments. Current research mainly focuses on either organic or inorganic soil amendments, whereas few studies address options of combining organic and inorganic amendments. The objective of this study was to develop new organic and inorganic soil amendments which can lower the soil pH, replace sodium, and improve soil structure.

Materials and methods

Polyhalite (PL), microporous potassium-silicon-calcium mineral fertilizer (MF), furfural residue (FR), and fulvic acid (FA) were mixed with four different ratios to produce organic and inorganic soil amendments: PLFR, PLFA, MFFR, and MFFA. And their optimum mixing ratios were determined by comparing the potassium, calcium concentrations, and pH of filtrate after dissolution. Then, a leaching experiment was conducted by packing mixtures (mass ratio of soil to amendment = 219:1, equivalent to 13 t/hm²) of the saline-sodic soil with each one of these amendments plus two contrasts, gypsum (GP), and no amendment (CK). And the remediation effect was compared by pH, EC, ESP, texture, organic recombination degree of clay, saturated hydraulic conductivity, water-stable aggregates fraction, and enzyme (urease, alkaline phosphatase, and catalase) activities of soil.

Results and discussion

After four times leaching experiment, soil treated with PLFR had lower pH and 25.86% lower exchangeable sodium than untreated soils. The water-stable small macroaggregate fractions and saturated hydraulic conductivity of the MFFR-treated soils were significantly increased by 133% and 31%, respectively. Also, the total soil and heavy fraction organic carbons of the soils treated with MFFR in addition to its alkaline phosphatase activity were all significantly higher than the other treatments.

Conclusions

The results revealed that MFFR has more potential as a soil amendment to improve soil structure and quality and thus help in the development and use of saline-sodic lands for agriculture.

     

Soil slaking sensitivity as influenced by soil properties in alluvial and residual humid tropical soils

Purpose

In the humid Caribbean region characterized by high-intensity tropical rainfall, soil aggregate breakdown and pore blocking due to slaking pressures are major land degradation mechanisms. In this research, we investigated the susceptibility of soils to slaking pressures under rapid wetting as influenced by soil properties and the depositional origin from which the soil is formed using water-stable aggregates (WSAr) and percolation stability (PSc) as indices of the strength of aggregate inter-particle cohesion.

Materials and methods

Wet sieving and percolation stability analyses were employed to investigate WSAr and pore blocking, respectively. The combined effect of soil properties of clay, organic matter (OM), cation exchange capacity (CEC), and exchangeable sodium percentage (ESP) was used to determine the slaking sensitivity score (SSc) of 14 physiogeographically important soils in Trinidad, comprising of nine alluvial and five residual soils.

Results and discussion

Results showed that irrespective of alluvial or residual depositional nature of the parent material, samples had high SSc with an average WSAr of 37.8% and PSc of 6.0 mm/10 min. The linear relationships between SSc with WSAr (r²?=???0.12) and SSc with PSc (r²?=???0.012) of all the 14 soils although negative were weak. Clay content accounted for 94.0% of the variation in CEC in alluvial soils and had strong negative relationships with WSAr (r²?=???0.74) and PSc (r²?=???0.79) in residual soils. Additionally, OM with WSAr (r²?=?0.52) and PSc (r²?=?0.24), and CEC with WSAr (r²?=?0.46) and PSc (r²?=?0.39) showed significant positive linear relationships in residual soil.

Conclusions

The predominantly micaceous and kaolinitic clay mineralogy of these soils, coupled with the low OM contents, increases the proneness of the soils to slaking. This suggests that clay mineralogy is responsible for the high slaking sensitivity rather than clay content or just the depositional origin of the soils. As CEC increases, an accompanying increase in OM is required to increase inter-particle cohesion and to impart partial hydrophobicity, which in turn decreases mineralogically induced susceptibility of individual aggregates to slaking.

     

Dissipation and sorption processes of polycyclic aromatic hydrocarbons (PAHs) to organic matter in soils amended by exogenous rich-carbon material

Purpose

The aim of the research was to assess the effect of biochar addition on aging, degradation, and sorption processes of polycyclic aromatic hydrocarbons (PAHs) to soil organic matter. The study was carried out as a sorption experiment in strictly controlled water and air conditions, which allowed for the accurate observation and prediction of PAH behavior in soils.

Materials and methods

Four soils were fortified with a PAH mixture (Fluorene-Flu, Anthracene-Ant, Phenanthrene-Phe, Pyrene-Pyr, Chrysene-Chry) at 20 mg kg^?1 of single-compound concentration level. The experiment was carried out in two trials: soils?+?5PAHs amended with biochar and soil?+?5PAHs without biochar addition with incubation times of 0, 1, 3, 6, and 9 months. After each interval time, the extractable (E-SOM) and stable organic matter (S-SOM) were measured as well as PAHs determined in two forms: total concentration (PAH-tot) and residual concentration (PAH-rest) after E-SOM extraction. The PAH loss and half-life times were estimated according to pseudo first-order kinetics equation.

Results and discussion

The amounts of PAH-tot in the soils without biochar decreased by an average of 92%, while in soil with biochar, this was 41% after 9 months of aging. The amount of PAHs-rest bounded with S-SOM after 9 months of incubation varied from 0.9 to 3.5% and 0.2 to 1.3% of the initial PAH concentration, respectively, for soils non-induced and induced by biochar. In soils without biochar, Flu, Ant, Phe, and Pyr exhibited similar T_1/2 (43–59 days), but Chry was characterized by a much higher and broader T_1/2 than other hydrocarbons (67–280 days). Biochar addition to the soils significantly influenced the half-life changes for all PAHs. The highest changes were noted for Phe (14-fold increase), and the lowest was for Flu (7-fold increase).

Conclusions

The addition of exogenous-rich carbon material such as biochar to the soil significantly changes the behavior and sorption potential of PAHs in the soil. Soils enriched with biochar are characterized by a higher persistence of PAHs, longer aging time, and lower affinity for sorption by native organic matter structures. Soils freshly polluted by PAH are mainly sorbed by E-SOM, which significantly increases their accessibility and reduces formation of bound-residues in the soil.