土壤水流通量对饱水带溶质运移参数的影响

The transport processes of solutes in two soil columns filled with undistrubed soil material collected from an unsaturated sandy aquifer formation in Belgium subjected to a variable upper boundary condition were identified from breakthrough curves measured by means of time domain reflectometry(TDR),Solute breakthrough was measured with 3 TDR probes inserted into each soil column at three different depths at a 10 minutes time interval.In addition,soil water content and pressure head were measured at 3 different depths.Analyteical solute transport models were used to estimate the solute disperison coefficient and average pore-water velocity from the observed breakthrough curves,the results showed that the analytical solutions were suitable in fitting the observed solute transport,The dispersion coefficient was found to be a function of the soil depth and average proe-water velocity,imposed by the soil water flux.the mobile moistrue content on the other hand was not correlated with the average pore-water velocity and the dispersion coefficient.     

An analytical solution for advance of solute front in soils

Based on the assumption that solute transport in a semi-infinite soil column or in a field soil profile can be described by the boundary-layer method, an analytical solution is presented for the advance of a solute front with time. The traditional convection-dispersion equation (CDE) subjected to two boundary conditions: 1) at the soil surface (or inlet boundary) and 2) at the solute front, was solved using a Laplace transformation. A comparison of resident concentrations using a boundary-layer method and an exact solution (in a semi-infinite-domain) showed that both were in good agreement within the range between the two boundaries. This led to a new method for estimating solute transport parameters in soils, requiring only observation of advance of the solute front with time. This may be corroborated visually using a tracer solution with marking-dye or measured utilizing time domain reflectometry (TDR). This method is applicable to both laboratory soil columns and field soils. Thus, it could be a step forward for modeling solute transport in field soils and for better understanding of the transport processes in soils.     

分形模型在利用颗粒分布数据评价土壤持水性质中的应用

Soil water retention characteristics are the key information required in hydrological modeling.Frac-tal models provide a practical alternative for indirectly estimating soil water retention characteristics from particle-size distribution data.Predictive capabilities of three fractal models,i.c.,Tylcr-Wheatcraft model,Rieu-Sposito model,and Brooks-Corey model,were fully evaluated in this work using experimental data from an international database and literature.Particle-size distribution data were firstly interpolated into 20 classes using a van Genuchten-type equation.Fractal dimensions of the tortuous pore wall and the pore surface were then calculated from the detailed particle-size distribution and incorporated as a parameter in fractal water retention models.Comparisons between measured and model-estimated water retention cha-racteristics indicated that these three models were applicable to relatively different soil textures and pressure head ranges.Tyler-Whcatcraft and Brooks-Corey models led to reasonable agreements for both coarse-and medium-textured soils,while the latter showed applicability to a broader texture range.In contrast,Rieu-Sposito model was more suitable for fine-textured soils.Fractal models produced a better estimation of water contents at low pressure heads than at high pressure heads.     

中国洞庭湖区稻田土壤氮素淋溶损失的系统研究

A two-year lysimeter study was conducted to study the effects of different fertilizers and soils on nitrogen leaching loss in a double rice cropping system by considering three major types of paddy soils from the Dongting Lake area. The results showed that N concentration in the leachate did not differ significantly among the treatments of urea, controlled release N fertilizer and pig manure and that all these fertilizers produced higher total nitrogen (TN) concentrations in the leachate compared to the case where no fertilizer was applied. The TN leaching loss following urea treatment accounted for 2.28%, 0.66%, and 1.50% of the amount of N applied in the alluvial sandy loamy paddy soil (ASL), purple calcareous clayey paddy soil (PCC), and reddish-yellow loamy paddy soil (RYL), respectively. Higher TN loss was found to be correlated with the increased leachate volume in ASL compared with RYL, and the lowest TN loss was observed in the PCC, in which the lowest leachate volume and TN concentration were observed. Organic N and NH4+ -N were the major forms of N depleted through leachate, accounting for 56.8% and 39.7% of TN losses, respectively. Accordingly, soil-specific fertilization regimens are recommended; in particular, the maximum amount of fertilizer should be optimized for sandy soils with a high infiltration rate. To avoid a high N leaching loss from rice fields, organic N fertilizers such as urea or coated urea should primarily be used for surface topdressing or shallow-layer application and not for deep-layer application.     

Salt-Water Dynamics in Soils: Ⅰ. Salt-Water Dynamics in Unsaturated Soils Under Stable Evaporation Condition

A long term simulation test on salt-water dynamics in unsaturated soils with different groundwater depths and soil texture profiles under stable evaporation condition was conducted.Salinity sensors and tensiometers were used to monitor salt and water variation in soils.The experiment revealed that in the process of fresh groundwater moving upwards by capillary rise in the column,the salts in subsoil were brought upwards and accumulated in the surface soil,and consequently the salinization of surface soil took place.The rate of salt accumulation is determined mainly by the volume of capillary water flow and the conditions of salts contained in the soil profile.Water flux in soils decreased obviously when groundwater depths fell below 1.5m.When there was an interbedded clay layer 30cm in thickness in the silty loam soil profile or a clay layer 100cm in thickness at the top layer,the water flux was 3-5 times less than in the soil profile of homogeneous silty loam soil.Therefore,the rate of salt accumulation was decreased and the effect of variation of groundwater depth on the water flux in soils was weakened comparatively.If there was precipitation or irrigation supplying water to the soil,the groundwater could rarely take a direct part in the process of salt accumulation in surface soil,especially,in soil profiles with an interbedded stratum or a clayey surface soil layer.     

华北矿区残留态铜、铅在土壤剖面中的分布与迁移

Residual heavy metals are commonly considered to be immobile in soils, leading to an underestimation of their environmental risk. This study investigated the distribution and transport of residual heavy metals along soil profiles, using the Xiaoqinling gold mining region in North China as a case study. Soil samples were collected at three depths from three locations near the tailing heap. The speciation of copper (Cu) and lead (Pb) (exchangeable, carbonate-bound, Fe-Mn oxide-bound, organic matter-bound, and residual fractions) was determined using a sequential extraction procedure. The residual fraction’s morphology was observed using scanning electron microscopy (SEM). Results showed that metal fraction distributions along the soil profiles were influenced by each fraction’s mobility. Residual fraction with high chemical stability cannot be transformed from or into other fractions. This led to the conclusion that the high concentration of residual metals in soils mainly resulted from residual fraction transport.The SEM analysis showed that fine particles (submicrons) were mainly attached to large particles and were likely released and transported by water flow. The more sorptive fractions (non-residual fractions) were mainly retained in the top soil, and the more mobile fractions (residual fraction) were mainly leached to the deep soil. Cu and Pb concentrations in the residual fraction decreased slightly and those in the non-residual fractions decreased significantly with soil depth. These suggest a relatively higher residual metal mobility along the soil pro?les. Therefore, residual metals can be transported in soils and their environmental risk can not be ignored in assessing soil contamination.     

Salt-Water Dynamics in Soils: II. Effect of Precipitation on Salt-Water Dynamics

Through a simulation test carried out with soil columns (61.8cm in diameter),the effect of precipitation on salt-water dynamics in soils was studied by in-situ monitoring of salt-water dynamics using soil salinity sensors and tensioneters.The results show that in the profile of whole silty loam soil,the surface runoff volume due to precipitation and the salt-leaching role of infiltrated precipitation increased with the depth of ground water;and in the profile with an intercalated bed of clay or with a thick upper layer of clay,the amount of surface runoff was greater but the salt-leaching role of precipitation was smaller than those in the profile of whole silty loam soil.In case of soil water being supplemented by precipitation,the evaporation of groundwater in the soil columns reduced,resulting in a great decline of salt accumulation from soil profile to surface soil.The effect of precipitation on the water regime of soil profile was performed via both water infiltration and water pressure transfer.The direct infiltration depth of precipitation was less than 1m in general,but water pressure transfer could go up to groundwater surface directly.     

DMPP硝化抑制效果受其浓度、施用方式及土壤基质势的影响

The efficacy of nitrification inhibitors depends on soil properties and environmental conditions. The nitrification inhibitor 3.4-dimethylpyrazole phosphate （DMPP） was investigated in a sandy loam and a loamy soil to study its effectiveness as influenced by inhibitor concentration, application form, and soil matric potential. DMPP was applied with concentrations up to 34.6 mg DMPP kg^-1 soil as solution or as ammonium-sulfate/ammonium-nitrate granules formulated with DMPP. DMPP inhibited the oxidation of ammonium in both soils, but this effect was more pronounced in the sandy loam than in the loamy soil. When applied as solution, increasing DMPP concentrations up to 7 mg DMPP kg^-1 soil had no influence on the inhibition. The effectiveness of DMPP formulated as fertilizer granules was superior to the liquid application of DMPP and NH4^＋, particularly in the loamy soil. Without DMPP, a decline in soil matric potential down to -600 kPa decreased nitrification in both soils, but this effect was more pronounced in the sandy loam than in the loamy soil. DMPP was most effective in the sandy loam particularly under conditions of higher soil moisture, i.e., under conditions favorable for nitrate leaching.     

长白山地区不同植被下土壤酸度状况

The acidity regimes of representative soils on the north slope of the Changbai Mountains were examined through determinations of pH and pCa of the soil paste as well as in-situ determinations,For soils under broad-leaf forest or broad-leaf-Korean pine forest,the pH decreased from the litte to lower layers gradually until it did not change or decreased further slightly .For soils under coniferous of Erans birch forest,ther was a minimum in pH at a depth of 3-6 cm where the content of humus was high,The pCa increased gradually from the soil surface downward to a constant value.The lime potential(pH-0.5pCa) showed a similar trend as the pH in its distribution.For a given soil,the measured pH value of the thick paste,ranging from 4.5 to 5.5,was lower by about 0.5 units than the value determined by the conventional method with a water to soil ratio of 5:1 ,The pH determined in situ was even lower.It was found that there was a firly close relationship between soil acidity and the type of vegetation.The pH showed a trend of decreasing from soils under broda-leaf forest through broad-leaf-conifer mixed rorest and coniferos forest to Ermans birch forest,and the pCa showed an opposite trend in variation.     

黄河下游冲积平原土壤盐分的时空变异研究——个例研究

Soil salinity and hydrologic datasets were assembled to analyze the spatio-temporal variability of salinization in Fengqiu County, Henan Province, China, in the alluvial plain of the lower reaches of the Yellow River. The saline soil and groundwater depth data of the county in 1981 were obtained to serve as a historical reference. Electrical conductivity (EC) of 293 surface soil samples taken from 2 km × 2 km grids in 2007 and 40 soil profiles acquired in 2008 was analyzed and used for comparative mapping. Ordinary kriging was applied to predict EC at unobserved locations to derive the horizontal and vertical distribution patterns and variation of soil salinity. Groundwater table data from 22 observation wells in 2008 were collected and used as input for regression kriging to predict the maximum groundwater depth of the county in 2008. Changes in the groundwater level of Fengqiu County in 27 years from 1981 to 2008 was calculated. Two quantitative criteria, the mean error or bias (ME) and the mean squared error (MSE), were computed to assess the estimation accuracy of the kriging predictions. The results demonstrated that the soil salinity in the upper soil layers decreased dramatically and the taxonomically defined saline soils were present only in a few micro-landscapes after 27 years. Presently, the soils with relatively elevated salt content were mainly distributed in depressions along the Yellow River bed. The reduction in surface soil salinity corresponded to the locations with deepened maximum groundwater depth. It could be concluded that groundwater table recession allowed water to move deeper into the soil profile, transporting salts with it, and thus played an important role in reducing soil salinity in this region. Accumulation of salts in the soil profiles at various depths below the surface indicated that secondary soil salinization would occur when the groundwater was not controlled at a safe depth.     

水平微润灌湿润体HYDRUS-2D模拟及其影响因素分析

为探索土壤质地、初始含水率、压力水头和埋深对水平微润灌土壤湿润体特性的影响机理,利用试验数据验证了水平微润灌HYDRUS-2 D模拟结果的可靠性,模拟值与实测值非常吻合。在此基础上,模拟研究了3种土壤质地(砂壤土、壤土、粉壤土)以及壤土中不同初始含水率(0.085、0.106、0.130 cm~3/cm~3)、压力水头(0.6、1.2、1.8 m)和埋深(20、30、40 cm)条件下土壤湿润体动态变化规律。结果表明:土壤湿润锋运移距离皆符合垂直向下水平方向垂直向上的规律,湿润体在形状上差异不大,土壤含水率等值线均为近似"同心圆";土壤质地对湿润体特性有显著影响,土壤质地越黏重,湿润锋运移速率越慢,湿润体体积越小,土壤含水率等值线越密集,其"圆心"越靠近微润管,灌水结束时,壤土和砂壤土湿润体体积分别是粉壤土的1.3倍和2.5倍;在确定的土壤质地条件下,初始含水率和压力水头对湿润体特性有较大影响,湿润锋运移距离及湿润体体积均随土壤初始含水率、压力水头的增大而增大,初始含水率为0.106和0.130 cm~3/cm~3的湿润体体积分别是0.085 cm~3/cm~3的1.2倍和1.5倍,压力水头为1.2和1.8 m的湿润体体积分别是0.6 m的1.6倍和2.2倍;微润管埋深对湿润体分布位置有显著影响,埋深较浅时,湿润锋容易到达地表,埋深较深时,土壤湿润体随埋深下移而同步下移。     

不同形态磷酸盐及施用方式对石灰性土壤磷移动性和有效性的影响

  【目的】  磷的固定是石灰性土壤中磷肥效益低的重要原因，研究两种施肥方式下不同形态磷源在石灰性土壤中的迁移以及有效性，为实现磷肥减施增效提供理论基础。  【方法】  采用土柱模拟试验方法进行研究，供试土壤为粘质和壤质石灰性土壤。供试磷酸盐为磷酸脲、焦磷酸和聚磷酸，壤土施磷量为0.0581 g/柱，粘土为0.0594 g/柱。施用方式包括一次施用和分4次滴施，同时以不施用磷酸盐土柱为对照。于地下室内 (27 ± 1.0)℃培养28天后将土柱在?80℃条件下快速冷冻固形，从土表向下0—100 mm内每隔5 mm作为一个切割单元，100—300 mm间每隔20 mm作为一个切割单元，测定每层土壤的水溶性磷和Olsen-P含量。  【结果】  培养28天后，一次施用条件下，磷在壤土中的移动距离表现为聚磷酸 (90 mm) > 焦磷酸 (60 mm) > 磷酸脲 (50 mm)，粘土中表现为聚磷酸 (80 mm) > 焦磷酸 (70 mm) > 磷酸脲 (60 mm)。分次滴施条件下，聚磷酸 (95 mm) 在壤土中的移动距离比磷酸脲 (65 mm) 和焦磷酸 (70 mm) 分别增加46.2%和35.7%，在粘土中聚磷酸 (90 mm) 的移动距离较磷酸脲 (70 mm) 和焦磷酸 (75 mm) 分别增加28.6%和20.0%。磷浓度下降到一半时所达到土柱深度 (半运移深度) 的结果表明，在壤土一次施用条件下，半运移深度表现为聚磷酸 (15.1 mm) > 焦磷酸 (11.4 mm) > 磷酸脲 (10.5 mm)，分次滴施条件下半运移深度为聚磷酸 (20.0 mm) > 焦磷酸 (14.4 mm) > 磷酸脲 (14.3 mm)。在粘土一次施用条件下，半运移深度为聚磷酸 (17.7 mm) > 焦磷酸 (15.8 mm) > 磷酸脲 (14.8 mm)，分次滴施条件下，聚磷酸、焦磷酸和磷酸脲的半运移深度依次为51.3、27.1和41.4 mm。相关性分析结果表明，不论一次施用还是分次滴施，聚磷酸和焦磷酸处理均随着水溶性磷含量的增加，有效磷含量在粘土上的增加量大于在壤土上的，分次滴施聚磷酸较一次施用在同样水溶性磷含量下，有效磷的含量在粘土和壤土中的差距减小，焦磷酸处理中水溶性磷与有效磷在两种土壤上较为接近。磷酸脲一次施用后，有效磷在粘土中随水溶性磷的变化量大于在壤土中，分次滴施结果则相反。  【结论】  在质地为壤土和粘土的石灰性土壤中，不论是一次性施用还是分次滴施，磷的移动性均表现为聚磷酸 > 焦磷酸 > 磷酸脲，且分次滴施3种磷源时磷的移动性和有效性均显著高于一次施用。同样水溶性磷含量条件下，粘土中磷的有效性高于壤土，分次滴施提高土壤磷素有效性的效果表现为粘土优于壤土。     

Acidity Changes of Foreign Acidic Soils Introduced into Calcareous Soil Environment

Abstract

Many tropical plant species originated in areas with acidic soils and do not grow well in calcareous (high pH) soils. It is impossible to acidify soils that have high contents of calcium carbonate in south Florida. Replacing calcareous soils with acidic soils obtained from distant regions is an alternative. Unfortunately, such introduced acidic soils may eventually be neutralized by irrigation and ground water that is saturated with calcium carbonate. The objective of this investigation was to examine the acidity changes and buffering capacities of three types of acidic soils (silica sand soil, red loamy sand soil, and a mixed soil) used to establish tropical plants in a rainforest exhibition at Fairchild Tropical Garden, Miami, FL. The three areas were excavated to remove native calcareous soil, limestone bedrock, and filled with acidic soils. Various rainforest plants were planted. Soil samples were collected in contiguous 10 cm‐deep segments from the soil surface to the bedrock shortly after deposition of the soils and one year later. Soil pH, EC, particle distribution, buffering capacity were determined. Results showed that both silica sand and mixed soils had been neutralized and the soil pH values had risen over 7 in all soil depths after one year. However, less than 10 cm of the surface and bottom soil layers of red loamy sand had been neutralized and the soil pH in the middle of soil profile remained unchanged due to its higher buffering capacity. A column leaching study showed that the acidity in the red loamy sand soil would be neutralized by irrigation water and by capillary movement of groundwater with a high concentration of calcium bicarbonate. Buffering curves indicate that it is easier to maintain acidity in sandy soil than of loamy sand and mixed soils with acidified irrigation water. Indeed it is difficult to acidify the mixed soils with high organic matter content after these soils have been neutralized.     

Eine Methode zur Ermittelung der wasserspannungsabhängigen Änderung des Sauerstoffpartialdruckes und der Sauerstoffdiffusion in einzelnen Bodenaggregaten

A method to determine oxygen partial pressure and oxygen diffusion in single soil aggregates as a function of soil moisture tension Anaerobic zones occur even in unsaturated soils of silty or clayey texture, that are aerated sufficiently in their macropore system. These zones can be related to the inner parts of soil aggregates. To describe the oxygen balances in soils it is necessary to measure not only in soil profiles but as well in single soil aggregates within a range of soil matrix potentials. Therefore oxygen partial pressure in single soil aggregates of different texture was measured continuously as a function of soil matrix potential. For that purpose we developed an oxygen sensitive microelectrode with a tip diameter of 0.5 mm, that is sturdy enough to measure even in sandy soils. One microtensiometer (diameter of the tip < 0.5 mm) and one oxygen microelectrode were placed in water saturated soil aggregates. Soil water potential and oxygen partial pressure were measured continuously during soil drying. The results show an aeration of primarily anoxic soil aggregates at different soil matrix potentials due to different texture and structure. The clayey polyhedral aggregates of the Vertisol were aerated at significantly lower soil matrix potentials than the loamy prisms of the Fluvisol. These show higher values of oxygen partial pressure even at soil water potentials less than 150 hPa. In the aggregates of the Vertisol, that have a fine texture, values of rel. aparent diffusion D_s/D_o were in the range of 1 · 10^?3 at soil water potentials < ?     

An amended functional leaching model applicable to structured soils. II. Model application

The performance of a functional leaching model (Hall, 1993) is compared with leaching data from two lysimeter experiments with soils of contrasting texture using sodium bromide and potassium chloride as the non-reactive solutes. The model parameters are optimized using the solute elution curves as standards and compared with the physical properties of the soil. A good match with the measured discharge of both water and solute was achieved for both soils using the moisture release characteristics to define the pore volume available for mobile and immobile water. The results indicate that preferential flow takes place through even coarse-textured soils but that there is negligible diffusive exchange of solute between water passing through the macropores and the rest of the soil.     

不同类型的污泥对土壤微生物性质的影响: 地中海退化土的田间试验研究

The recycling of suitable organic wastes can enhance soil fertility via effects on soil physical, chemical and biological properties. To compare the effects of digested (DS), thermally dried (TDS) and composted dewatered (CDS) sewage sludge on soil microbiological properties, an experiment was conducted at field sites for more than one year (401 d) when applied to two Mediterranean degraded soils (loam and loamy sand soils). All three types of sewage sludge had a significant effect on measured parameters. I...     

Bromidverlagerung an zwei gedränten Standorten in Schleswig-Holstein

Bromide transport at two tile- drained field sites Within comparative studies on solute movement in tile drained agricultural fields in Schleswig-Holstein a bromide field test was conducted at two field sites. The soil of site ‘Bokhorst’ shows both spatial and profile heterogeneity with significant clay and silt contents (loam) whereas site ‘Hohn’ had a homogeneous particle size distribution within the profile with sand being the dominating particle fraction (sand) but with neglible spatial variability. Rainfall amount, drain discharge and bromide concentrations in drain outflow were monitored over a 6 months period. A rapid response of drain discharge on rain events was observed for the loamy site but not for the sand. The simple water balance yielded + 8.7 mm of drain discharge for site Bokhorst (loam) and ?43 mm for the sandy site Hohn (sand). Largest bromide concentrations were detected shortly after chemical application at the loamy site. The bromide loss curve was characterized by simultaneous in- and decrease of flow rate and bromide concentrations. This solute behaviour was named ‘event-dependent’. Bromide occurred in drain outflow at the sandy site not before 30 mm discharge and maximum concentrations were observed at the end of the monitoring period. Mass balance calculations revealed that 70.5% (loam) and 33% (sand) of the applied solute mass were transported from the fields via the tile drains. A two dimensional, advection dispersion equation based simulation model was applied to predict solute behaviour at site Bokhorst. Computed bromide concentrations were not in line with the observed preferential breakthrough curve. Consequences of preferential transport conditions in tile-drained field soils on surface water quality are briefly discussed, especially concerning the displacement of plantprotective agents and methodical difficulties.     

黄泛平原不同质地土壤的持水特性

用压力膜法对黄泛平原不同质地潮土的持水特性进行了研究.结果指出,土壤的持水性、孔径分布和水容量都与土壤质地有密切关系.在高吸力情况下,土壤的持水性随土壤质地变粘而增强.土壤孔径分布与土壤质地的关系是:重力水孔隙随土壤质地变粘而减小;迟效水孔隙和无效水孔隙随质地变粘而增加;而易效水孔隙偏粘的土壤有减小的趋势.土壤水容量也受土壤质地的影响,重力水水容量随质地变粘而增加,易效水水容量是壤土高于砂性土和粘性大,而迟效水水容量则是轻粘土高于其它质地的土壤.     

Regional pattern of the mobile water fraction in soils as determined by disc infiltrometer experiments

In order to characterize the partitioning of solutes into the mobile and the immobile fraction of pore water at the soil surface, field measurements of infiltration in unsaturated loamy sands were carried out using a disc infiltrometer in a region of about 10 km² at the Lüneburger Heide, Germany. The aims of these measurements were to obtain the mobile water fraction and the hydraulic properties of the soil, to relate them to other measured soil properties like the soil texture, and to assess their spatial variability in the region. From the infiltration results we obtained the hydraulic conductivity K₀ and the sorptivity S₀ using a three-dimensional infiltration analysis and the two-term infiltration equation, respectively. The mobile water fraction θ_m/θ of the soil was estimated from the infiltration results of a second disc infiltrometer filled with bromide solution. The estimated values of K₀ and S₀ were in good agreement with those reported in the literature as typical for loamy sands. The average value of θ_m/θ was calculated to be 71 % under the experimental conditions. Neither the horizontal spatial distribution of water and bromide concentration beneath the disc infiltrometer nor the change of the infiltrometer during the experiment had a notable influence on the experimental results. The spatial variability of the data was analyzed by means of variograms. All variograms were spatially structured and indicated a high small scale variation of the variables. In conclusion, the technique applied is suitable for the estimation of the hydraulic and solute transport properties of soils, especially at larger scales.