Composite materials of thermoplastic starch and fibers from the ethanol-water fractionation of bagasse |
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Authors: | Maria E Vallejos Aprigio AS CurveloEliangela M Teixeira Fernanda M MendesAntonio JF Carvalho Fernando E FelissiaMaria C Area |
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Institution: | a Programa de Investigación de Celulosa y Papel, Facultad de Ciencias Exactas, Químicas y Naturales, Universidad Nacional de Misiones, Félix de Azara 1552, 3300 Posadas, Misiones, Argentina b Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Argentina c Instituto de Química de São Carlos, Universidade de São Paulo, São Carlos, 13560-970 São Paulo, Brazil d Embrapa, 13560-970, São Carlos, São Paulo, Brazil e Department of Materials Engineering, University of São Paulo, São Carlos, São Paulo, Brazil |
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Abstract: | The aim of this study was to evaluate the potential of the fibrous material obtained from ethanol-water fractionation of bagasse as reinforcement of thermoplastic starches in order to improve their mechanical properties. The composites were elaborated using matrices of corn and cassava starches plasticized with 30 wt% glycerin. The mixtures (0, 5, 10 and 15 wt% bagasse fiber) were elaborated in a rheometer at 150 °C. The mixtures obtained were pressed on a hot plate press at 155 °C. The test specimens were obtained according to ASTM D638. Tensile tests, moisture absorption tests for 24 days (20-23 °C and 53% RH, ASTM E104), and dynamic-mechanical analyses (DMA) in tensile mode were carried out. Images by scanning electron microscopy (SEM) and X-ray diffraction were obtained. Fibers (10 wt% bagasse fiber) increased tensile strength by 44% and 47% compared to corn and cassava starches, respectively. The reinforcement (15 wt% bagasse fiber) increased more than fourfold the elastic modulus on starch matrices. The storage modulus at 30 °C (E30 °C′) increased as the bagasse fiber content increased, following the trend of tensile elastic modulus. The results indicate that these fibers have potential applications in the development of biodegradable composite materials. |
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Keywords: | Biodegradable composite Thermoplastic starch Sugarcane bagasse Ethanol-water fractionation Mechanical properties Thermal analysis |
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