| 超离域度和VitB_2的递氢反应机理 |
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| 引用本文： | 谢育才,翟仁通. 超离域度和VitB_2的递氢反应机理[J]. 山西农业大学学报(自然科学版), 1991, 0(2) |
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| 作者姓名： | 谢育才 翟仁通 |
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| 作者单位： | 山西农业大学无机化学教研室 太谷 |
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| 摘 要： | 本文用HMO方法计算得到VitB_2及其反应中间态的异咯嗪环的前线超离域度,可以很好地解释和预计某些脱氢酶和非酶模型的递氢反应机理。包括离子型反应和自由基反应机理。
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| 关 键 词： | 核黄素 超离域度 |
THE SUPERDEL OCALIZABILITTES OF VITAMIN B_2 AND ITS MECHANISM FOR TRANSHYDROGENATION |
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| Xie Yucai. THE SUPERDEL OCALIZABILITTES OF VITAMIN B_2 AND ITS MECHANISM FOR TRANSHYDROGENATION[J]. Journal of Shanxi Agricultural University(Nature Science Edition), 1991, 0(2) |
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| Authors: | Xie Yucai |
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| Abstract: | The frontier superdelocalizabilities of the oxidized and reduced isoalloxazine rings of riboflavin (i. e. vitamin B_2) have been calculated by HMOmethod. Using these indices can illustrate the mechanism of transport—hydrogen reactions including both specific dehydrogenase enzymes and nonemzymes. The result seems to be reasonable. |
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| Keywords: | Riboflavin SuperdelocaUzability |
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