Odor-active alcohols from the fungal transformation of alpha-farnesene |
| |
Authors: | Krings Ulrich Hardebusch Björn Albert Dieter Berger Ralf G Maróstica Mario Pastore Glaucia M |
| |
Institution: | Zentrum für Angewandte Chemie, Institut für Lebensmittelchemie, Leibniz Universit?t Hannover, Wunstorfer Strasse 14, D-30453 Hannover, Germany. |
| |
Abstract: | Submerged microbial cultures were screened for their potential to oxifunctionalize alpha-farnesene. The major oxidation product in all transforming cultures, 3,7,11-trimethyldodeca-1,3(E),5(E)10-tetraen-7-ol, showed a pleasant citrus-like odor and peak concentrations of 170 mg L-1. An Aspergillus niger isolate from mango generated another two terpene alcohols identified as diastereomeric menth-1-en-3-2-methyl-1,3-butadienyl]-8-ol, a new natural compound with an apricot-like odor. The regiospecifity of the oxygen attack with concurrent lack of stereoselectivity suggested that the initial step of the bioconversion resembled the chemical autoxidation starting with the generation of an intermediate resonance-stabilized carbon-centered radical or carbocation. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|