| 松油烯-4-醇酯类衍生物的合成及杀虫活性 |
| |
| 引用本文： | 黑育荣,马志卿,张兴.松油烯-4-醇酯类衍生物的合成及杀虫活性[J].农药学学报,2011,13(2):133-137. |
| |
| 作者姓名： | 黑育荣 马志卿 张兴 |
| |
| 作者单位： | 1.西北农林科技大学 无公害农药研究服务中心∕陕西省生物农药工程技术研究中心,陕西 杨凌 712100 |
| |
| 基金项目： | 国家自然科学基金资助项目 |
| |
| 摘 要： | 松油烯-4-醇具有较高的生物活性,在前期研究基础上,以松油烯-4-醇为原料,对其羟基进行改造,合成了12个松油烯-4-醇酯类衍生物 Z1~Z12,其中Z3、Z4、Z8、Z9、Z10、Z11、Z12为新化合物。所有化合物的结构均经核磁共振氢谱、碳谱及质谱确证。初步杀虫活性测定结果表明:各化合物对粘虫均有一定的触杀作用,其中Z5 活性最高,其LD50值为0.072 8 mg/头,为松油烯-4-醇的1.32倍;除 Z9 外,其余11个化合物对家蝇均具有一定的熏蒸作用,但其毒力均低于松油烯-4-醇。
|
| 关 键 词： | 松油烯-4-醇 酯类衍生物 杀虫活性 |
| 收稿时间： | 6/8/2010 12:00:00 AM |
| 修稿时间： | 2010/10/21 0:00:00 |
Synthesis and insecticidal activity of ester derivatives of Terpinen-4-ol |
| |
| HEI Yu-rong,MA Zhi-qing and ZHANG Xing.Synthesis and insecticidal activity of ester derivatives of Terpinen-4-ol[J].Chinese Journal of Pesticide Science,2011,13(2):133-137. |
| |
| Authors: | HEI Yu-rong MA Zhi-qing and ZHANG Xing |
| |
| Institution: | 1.Research & Development Center of Bio-rational Pesticide,Northwest A & F University/Technology and Engineering Center of Bio-pesticide,Yangling 712100,Shaanxi Province,China2.Yangling Vocational & Technical College,Yangling 712100,Shaanxi Province,China |
| |
| Abstract: | Terpinen-4-ol has been exhibited good biological activity.Based on the primary research,12 ester derivatives were synthesized with Terpinen-4-ol.The chemical structures of compounds were confirmed by NMR and MS.The Z3,Z4,Z8,Z9,Z10,Z11 and Z12 are new compounds.The preliminary bioassay results indicated that 12 compounds all showed contact activity against Mythima separata W.,among which Z5 had the highest activity with LD50 value of 0.072 8 mg/insect,11 compounds exhibited fumigation activity against Musca domestica L.,the fumigation toxicity of them was weaker than Terpinen-4-ol. |
| |
| Keywords: | Terpinen-4-ol ester derivative insecticidal activity |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《农药学学报》浏览原始摘要信息 |
| 点击此处可从《农药学学报》下载免费的PDF全文 |
|
