| 七元瓜环与8-氮杂腺嘌呤的超分子相互作用研究 |
| |
| 引用本文： | 王娟,黄英,陶朱,薛赛凤,祝黔江. 七元瓜环与8-氮杂腺嘌呤的超分子相互作用研究[J]. 山地农业生物学报, 2011, 30(4): 352-356 |
| |
| 作者姓名： | 王娟 黄英 陶朱 薛赛凤 祝黔江 |
| |
| 作者单位： | 1. 贵州省大环化学及超分子化学重点实验室,贵州贵阳,550025
2. 贵州大学西南药用生物资源教育部工程研究中心,贵州贵阳,550025 |
| |
| 基金项目： | 国家自然科学基金（NSFC20972034）;贵州大学人才引进项目[贵大人基合字（2009）023号] |
| |
| 摘 要： | 利用紫外吸收光谱考察七元瓜环(Q[7])与8-氮杂腺嘌呤(8-AA)的主客体相互作用,同时研究了作用体系酸度对Q[7]与8-AA相互作用的影响;计算了不同温度下相应的稳定常数及热力学参数等。结果表明:Q[7]与8-AA主客体包结计量比为1∶1,包结平衡常数为(2.55±1.52)×104 L/mol;通过热力学参数测定,其相互作用是自发进行的,且范德华力是反应的主要驱动力。并用1H NMR法进一步证实了主客体的作用模式。
|
| 关 键 词： | 七元瓜环 8-氮杂腺嘌呤 包结复合物 紫外吸收光谱法 |
Inclusion Interactions of Cucurbit [7] uril with 8-Azaadenine |
| |
| WANG Juan,HUANG Ying,TAO Zhu,XUE Sai-Feng,ZHU Qian-Jiang. Inclusion Interactions of Cucurbit [7] uril with 8-Azaadenine[J]. Journal of Mountain Agriculture & Biology, 2011, 30(4): 352-356 |
| |
| Authors: | WANG Juan HUANG Ying TAO Zhu XUE Sai-Feng ZHU Qian-Jiang |
| |
| Affiliation: | 1. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province , Guizhou University, Guiyang Guizhou 550025, Chi- na ; 2. The Engineering and Research Center for Southwest Bio-Pharmaceutical resources of National Education Ministry of China, Guizhou University, Guiyang Guizhou 550025, China) |
| |
| Abstract: | Interactions of cucurbit [ 7 ] uril （ Q [ 7 ] ） with 8-azaadenine （8-AA） were investigated by UV absorption spectroscopy in the present work. The result showed that the inclusion ratio of Q[T] and 8-AA was 1： 1, and the formation constant was （2.55 ± 1.52） × 10^4 L·mol-1. Moreover, the thermodynamic parameters of the complex formation were also determined, and it showed that the binding process was spontaneous and Van der Waals force was the main driving forces. The inclusion complex was further proved by 1H NMR. |
| |
| Keywords: | Cucurbit[ 7 ] uril 8-Azaadenine Inclusion complexes UV absorption spectroscopy |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
