Effects of sorbed orthophosphate on zinc status in three soils of eastern Canada

P-Zn interactions can affect fertilizer use and produce Zn deficiencies with certain crops. Phosphorus-Zn sorption-desorption reactions were studied in topsoil and subsoil samples from three Quebec soils. Soils were equilibrated with P solutions, then with Zn solutions, and finally with solutions containing no P or Zn. The first equilibration evaluated P sorption (P_s), the second evaluated Zn sorption (Zn_s) after P sorption (P_s), and the third evaluated Zn desorption (Zn_D) as related to added P. Subsequently, Zn fractions were extracted sequentially with KNO₃ (Zn _{kno 3}), NaOH (Zn_NaOH) solutions and concentrated HN0₃+ H₂0₂(Zn_HNO,).
One mmole sorbed P resulted in increases of 0.5 to 1.0 meq (mean = 0.72) increases in cation exchange capacity (CEC). Increased Zn_s with added P was equivalent to 4 to 5% of the increase in CEC induced by P_s in the Uplands (sand) and St. Bernard (loam) soils, and 0.4 to 0.9% in the Dalhousie (clay) soils, while one meq increase in CEC resulted in 1.5-3.5% decrease in Zn_D. There existed positive correlations between P_s and extractable soil Fe materials. Phosphate sorption enhanced associations between Zn_s, Zn_D or Zn fractions and soil organic or crystalline Fe contents, confirming that P addition increased specific sorption of Zn on Fe components. Other mechanisms including precipitation, P-induced negative charge and 'bridge' effects are also discussed.