Pyrolytic characteristics of burning residue of fire-retardant wood |
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Authors: | Guangjie Zhao Wensheng Luo T Furuno Qiang Ren Erni Ma |
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Institution: | (1) College of Material Science and Technology, Beijing Forestry University, Beijing, 100083, China;(2) Shengda Huayuan Technology Co. Ltd, Beijing, 100071, China;(3) Faculty of Science and Engineering, Shimane University, Matsue 609228504, Japan |
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Abstract: | In order to investigate the pyrolytic characteristics of the burning residue of fire-retardant wood, a multifunctional fire-resistance
test oven aimed at simulating the course of a fire was used to burn fire-retardant wood and untreated wood. Samples at different
distances from the combustion surface were obtained and a thermogravimetric analysis (TG) was applied to test the prrolytic
process of the burning residue in an atmosphere of nitrogen. The results showed that: 1) there was little difference between
fire-retardant wood and its residue in the initial temperature of thermal degradation. The initial temperature of thermal
degradation of the combustion layer in untreated wood was higher than that in the no burning wood sample; 2) the temperature
of the flame retardant in fire-retardant wood was 200°C in the differential thermogravimetry (DTG). The peak belonging to
the flame retardant tended to dissipate during the time of burning; 3) for the burning residue of fire-retardant wood, the
peak belonging to hemicellulose near 230°C in the DTG disappeared and there was a gentle shoulder from 210 to 240°C; 4) the
temperature of the main peaks of the fire-retardant wood and its burning residue in DTG was 100°C lower than that of the untreated
wood and its burning residue. The rate of weight loss also decreased sharply; 5) the residual weight of fire-retardant wood
at 600°C clearly increased compared with that of untreated wood. Residual weight of the burning residue increased markedly
as the heating temperature increased when burning; 6) there was a considerable difference with respect to the thermal degradation
temperature of the no burning sample and the burning residue between fire-retardant wood and untreated wood.
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Translated from Journal of Beijing Forestry University, 2006, 28(3): 133–138 译自: 北京林业大学学报] |
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Keywords: | fire-retardant wood burning residue pyrolytic characteristics thermogravimetric analysis |
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