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ZnO-mediated photocatalytic degradation of Benzopurpurine BP4B in aqueous solution
Authors:Laouedj?Nadjia  Email author" target="_blank">Elaziouti?AbdelkaderEmail author  Bekka?Ahmed
Institution:1.DR. Moulay Tahar University,Saida,Algeria;2.LCPCE Laboratory, Faculty of Sciences, Department of Industrial Chemistry,University of the Science and the Technology of Oran,Oran,Algeria
Abstract:The photocatalytic degradation of a commercial azo dye Benzopurpurine 4B (BP4B) in aqueous solution was investigated under UV-A light at different operating conditions, including irradiation time, pH solution, initial dye concentration, amount of catalyst, light intensity as well as band gap of other semiconductor groups by UV-spectrophotometric monitoring. The highest decomposition efficiency was obtained at pH 8 as a result of 97.24 % degradation of BP4B for 80 min of irradiation time. Photodecomposition reaction of BP4B dye was correlated with pseudo-first-order kinetic model. The degradation data of BP4B dye were satisfactory described by Langmuir-Hinshelwood (L-H) mechanism.
Keywords:
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