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Two-dimensional nanosheets produced by liquid exfoliation of layered materials
Authors:Coleman Jonathan N  Lotya Mustafa  O'Neill Arlene  Bergin Shane D  King Paul J  Khan Umar  Young Karen  Gaucher Alexandre  De Sukanta  Smith Ronan J  Shvets Igor V  Arora Sunil K  Stanton George  Kim Hye-Young  Lee Kangho  Kim Gyu Tae  Duesberg Georg S  Hallam Toby  Boland John J  Wang Jing Jing  Donegan John F  Grunlan Jaime C  Moriarty Gregory  Shmeliov Aleksey  Nicholls Rebecca J  Perkins James M  Grieveson Eleanor M  Theuwissen Koenraad  McComb David W  Nellist Peter D  Nicolosi Valeria
Affiliation:School of Physics and Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, D2, Ireland. colemaj@tcd.ie
Abstract:If they could be easily exfoliated, layered materials would become a diverse source of two-dimensional crystals whose properties would be useful in applications ranging from electronics to energy storage. We show that layered compounds such as MoS(2), WS(2), MoSe(2), MoTe(2), TaSe(2), NbSe(2), NiTe(2), BN, and Bi(2)Te(3) can be efficiently dispersed in common solvents and can be deposited as individual flakes or formed into films. Electron microscopy strongly suggests that the material is exfoliated into individual layers. By blending this material with suspensions of other nanomaterials or polymer solutions, we can prepare hybrid dispersions or composites, which can be cast into films. We show that WS(2) and MoS(2) effectively reinforce polymers, whereas WS(2)/carbon nanotube hybrid films have high conductivity, leading to promising thermoelectric properties.
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