Effect of sulphur dioxide on precipitation and on the sulphur content and acidity of soils in Alberta,Canada

Rain and snow in Alberta are seldom acid. The S content of snow is so low that the snow pack gives a deposition of less than 1 kg S ha^?1, even downwind from large SO₂ emission sources. Rainfall contributes at the most 4 kg S ha^?1 yearly near SO₂ sources, and only about 1 kg S ha^?1 in clean areas. However, rain intercepted by forest trees exposed to SO₂ emission becomes acid (pH 3.5 to 4.5) and has a S content of 3 to 4 times greater than rain. Soils absorb large amounts of S from emissions (up to 50 kg S ha ^?1 annually) but much of the S is found in non-sulphate form. Soils are slowly acidified by the SO₂ at a rate estimated at 1 pH unit in 10 to 20 yr. Water surfaces will absorb SO₂ emissions at a rate of about 4 to 15 kg S ha^?1 annually. Particulates deposit 3 to 4 times as much S as is deposited by rainfall.