Impacts of elemental S applied under various temperature and moisture regimes on pH and available P in acidic, neutral and alkaline soils

We evaluated the effect of elemental S (S⁰) under three moisture (40, 60, 120% water-filled pore space; WFPS) and three temperature regimes (12, 24, 36°C) on changes in pH and available P (0.5 N NaHCO₃-extractable P) concentrations in acidic (pH 4.9), neutral (pH 7.1) and alkaline (pH 10.2) soils. Repacked soil cores were incubated for 0, 14, 28 and 42 days. Application of S⁰ did not alter the trends of pH in acidic and neutral soils at all moisture regimes but promoted a decrease in the pH of alkaline soil under aerobic conditions (40%, 60% WFPS). Moisture and temperature had profound effects on the available P concentrations in all three soils, accumulation of available P being greatest under flooded conditions (120% WFPS) at 36°C. Application of S⁰ in acidic, neutral and alkaline soils resulted in the net accumulation of 16.5, 14.5 and 13 g P g^–1 soil after 42 days at 60% WFPS, but had no effect under flooded conditions. The greatest available P accumulations in the respective soils were 19, 19.5 and 20 g P g^–1 soil (equivalent to 38, 41, 45 kg P ha^–1) with the combined effects of 36°C, 60% WFPS and applied S⁰. The results of our study revealed that oxidation of S⁰ lowered the pH of alkaline soil (r=–0.88, P<0.01), which in turn enhanced available P concentrations. Also, considering the significant relationship between the release of sulphate and accumulation of P, even in acidic soil (r=0.92, P<0.01) and neutral soil (r=0.85, P<0.01) where the decrease in pH was smaller, it is possible that the stimulatory effect of sulphate on the availability of P was due to its concurrent desorption from the colloidal surface, release from fixation sites and/or mineralization of organic P. Thus, in the humid tropics and irrigated subtropics where high moisture and temperature regimes are prevalent, the application of S⁰ could be beneficial not only in alleviating S deficiency in soils but also for enhancing the availability of P in arable soils, irrespective of their initial pH.