| 4-甲氧基-2,2,6,6-四甲基哌啶-1-氧化物及其溴化物的氧化性能研究 |
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| 引用本文： | 覃兆海,张政. 4-甲氧基-2,2,6,6-四甲基哌啶-1-氧化物及其溴化物的氧化性能研究[J]. 中国农业大学学报, 1998, 0(Z4) |
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| 作者姓名： | 覃兆海 张政 |
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| 作者单位： | 中国农业大学应用化学系;100094; |
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| 摘 要： | 本文合成并研究了4-MeO-TEMPO 及其溴化物对醇的氧化性能,结果表明,4-MeO-TEMPO 对NaClO 的氧化性能有较大的促进,是一个较好的 NaClO 氧化反应的助氧化剂;其溴化物本身是一个较好的限制性氧化剂。
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| 关 键 词： | 4-甲氧基-2 2 6 6-四甲基哌啶-1-氧化物 4-甲氧基-1-氧-2 6-四甲基哌啶溴化物 氧化 氧化剂 |
Selective Oxidation of Alcohols With Oxoammonium Salts |
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| Qin Zhaohai Zhang Zheng. Selective Oxidation of Alcohols With Oxoammonium Salts[J]. Journal of China Agricultural University, 1998, 0(Z4) |
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| Authors: | Qin Zhaohai Zhang Zheng |
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| Affiliation: | Qin Zhaohai Zhang Zheng (Dept.of Applied chemistry CAU,Beijing 100094) |
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| Abstract: | 4-MeO-2,2,6,6-tetramethyl piperidine-l-oxide and 4-MeO-l-oxo-2,2,6,6-te- tramethyl piperidinium bromide were synthesized and tested for oxidating performance to several alcohols.The results indicated that the former could improve the oxidating perfor- mance of NaClO obviouly;the latter itself was a good selective oxidating agent. |
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| Keywords: | 4-Methoxy-2 2 6 6-tetramethyl piperidine-1-oxide 4-Methoxy-1-oxo-2 6-tetramethyl piperidinium bromide oxidation oxidating agent |
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