| Abstract: | It is suggested that stopping liming on agricultural land could lead to a potential chemical time bomb (CTB). the sequence of interrelated events leading to the CTB include the end of liming, perhaps caused by a change in land use, a progressive decrease in soil pH and increased solubility of potentially toxic contaminants that accumulate in soils as a result of agricultural practices. Data are presented on rates of long-term soil acidification and modelled changes in the solubility of some trace metals in soil as a result of acidification. Soil acidification rates depend primarily on acid input rates and the soil's acid neutralizing capacity, possibly limited by neutralization kinetics. Experimental data illustrating this point show that the pH decreased rapidly in a field soil receiving ammonium rather than nitrate fertilizer treatment. on a limed agricultural field that was later abandoned and converted to deciduous woodland, The pH of the 0-23 cm soil layers decreased over 100 years from pH 7 to 4.2. Deeper layers acidified at a slower rate. Thermodynamic model calculations simulating the solubilities of metals in a sandy topsoil showed zinc, cadmium and aluminium solubilities increasing exponentially with decreasing pH, resulting in several-fold solubility increases between pH 5 and 4. These results suggest how metal solubility increases after liming stops. the model pH-solubility relationships depended on the type of metal, The solid phase controlling the solubility, and the amount of metal in the soil if adsorption controlled the solubility. Decreasing pH and the resultant increase in metal solubility expected on abandoned farmland might be managed through techniques such as liming or planting forests of selected tree species. |
