Evaluation of coal combustion byproducts as soil liming materials: their influence on soil pH and enzyme activities

There is considerable interest in the use of coal combustion byproducts as soil liming materials in agricultural production, but there is concern that such use may be detrimental to the quality of agricultural soils. To evaluate these byproducts as liming materials and address issues related to soil quality, we compared the influence of different amounts of four combustion byproducts [fly ash and bed ash from a fluidized bed combustion furnace, lime-injected multistage burner residue, and spray dryer residue] and CaCO₃ on soil pH and activities of urease, phosphatase, arylsulfatase, and dehydrogenase in an acidic soil. Studies comparing the influence of the combustion byproducts and CaCO₃ on soil pH showed that on a weight basis of application, substantial differences were observed in the ability of these materials to influence soil pH but that such differences decreased markedly after the data were transformed to a CaCO₃ equivalent basis of application. Analysis of covariance for these transformed data indicated that whereas the liming abilities of fly ash and CaCO₃ were not significantly different when compared on the CaCO₃ equivalent basis, those of bed ash, multistage burner residue, and spray dryer residue were less than that of CaCO₃. Studies comparing the influence of the byproducts and CaCO₃ on soil enzyme activities showed that the effect of these liming materials on the enzyme activities studied was largely due to their influence on soil pH. The relationships obtained between soil pH and enzyme activities in soil amended with the liming materials generally demonstrated the marked similarities in the influence of the combustion byproducts and CaCO₃ on these activities when observed within the domain of soil pH. These studies showed that the combustion byproducts tested functioned as soil liming materials in a manner similar to that of CaCO₃ and seemed to have little adverse effect on soil quality.