| 蓝花楹木质素-碳水化合物复合体在硫酸盐法蒸煮过程中的变化 |
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| 引用本文： | 周燕,谢益民,甘定能,杨志勇,王鹏. 蓝花楹木质素-碳水化合物复合体在硫酸盐法蒸煮过程中的变化[J]. 林产化学与工业, 2007, 27(2): 49-52 |
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| 作者姓名： | 周燕 谢益民 甘定能 杨志勇 王鹏 |
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| 作者单位： | 山东轻工业学院,制浆造纸工程省级重点学科,山东,长清,250353;潍坊科技职业学院化学工程学院,山东,寿光,262700;山东轻工业学院,制浆造纸工程省级重点学科,山东,长清,250353;湖南岳阳纸业股份有限公司,湖南,岳阳,414002;华南理工大学,制浆造纸工程国家重点实验室,广东,广州,510640 |
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| 基金项目： | 国家自然科学基金资助项目(30471365)，山东省青年科学家奖励基金资助项目(04BS05005) |
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| 摘 要： | 以蓝花楹为原料提取木质素-碳水化合物复合体(LCC),并对LCC的结构进行分析,同时模拟硫酸盐法蒸煮过程,采用蒸煮的方法对LCC进行处理,并对处理后的产物进行红外光谱和核磁共振分析,研究蓝花楹LCC的结构变化,探讨其在硫酸盐法蒸煮过程中LCC的形成和降解情况。研究发现:蓝花楹LCC中的碳水化合物在蒸煮过程中非常不稳定,大部分发生降解,而蒸煮产物中含有对碱稳定的LCC结构,也含有新形成的LCC结构,这种新形成的LCC是5-5缩合型木质素结构与木聚糖形成的以化学键连接的LCC结构,且其对碱也非常稳定。
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| 关 键 词： | 木质素-碳水化合物复合体 硫酸盐法蒸煮 碳水化合物 蓝花楹 |
| 文章编号： | 0253-2417（2007）02-0049-04 |
| 修稿时间： | 2005-10-17 |
Change of Lignin-carbohydrate Complexes in Jacaranda copaia Aubl.D.Don.during Kraft Cooking |
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| ZHOU Yan,XIE Yi-min,GAN Ding-neng,YANG Zhi-yong,WANG Peng. Change of Lignin-carbohydrate Complexes in Jacaranda copaia Aubl.D.Don.during Kraft Cooking[J]. Chemistry & Industry of Forest Products, 2007, 27(2): 49-52 |
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| Authors: | ZHOU Yan XIE Yi-min GAN Ding-neng YANG Zhi-yong WANG Peng |
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| Affiliation: | 1. Shandong Key Lab. of Pulp and Paper Engineering,Shandong Institute of Light Industry, Changqing 250353, China; 2. Weifang Science and Technology Vocational College, Shouguang 262700, China;3. Hunan Yueyang Paper Co. Ltd, Yueyang 414002, China; 4. State Key Lab. of Pulp and Paper Engineering,South China University of Technology, Guangzhou 5113640, China |
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| Abstract: | Lignin-carbohydrate complexes(LCC)from Jacaranda copaia Aubl.D.Don.was prepared.In order to research the degradation of LCC during cooking,LCC was treated by kraft method.The combination of infrared spectra analysis and 13C NMR was used to identify LCC formed during kraft cooking.The research indicated that carbohydrates in LCC were unstable and most of them were cleaved during kraft cooking.There were undegraded LCC and newly formed LCC structures after kraft cooking.The structure of newly formed LCC was from lignin structure and xylan,such as 5-5 lignin structure,which were connected with benzyl ether linkage.The newly formed LCC were stable in alkaline solution. |
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| Keywords: | lignin-carbohydrate complexes kraft cooking carbohydrate Jacaranda copaia Aubl.D.Don. |
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