Assessing Passive Capillary-Wick Samplers for monitoring resident nitrate concentration in real field

Abstract. We evaluated the effectiveness of capillary-wick samplers (PCAPS) for continuous monitoring of resident nitrate concentration in three 'soil-crop-climate' systems differing in soil type, land use and climate. These systems involved: (i) acid silty soils under a beech-oak forest affected by heavy N-NH₄⁺ deposition in Belgium; (ii) silty soils under wheat cropping and a short rotation willow coppice plantation (SRC) in Belgium; and (iii) volcanic ash soils under plantain cultivation with and without urea fertilization in Colombia. The PCAPS continuously applied a suction of 0 to 5.4 kPa to the soil water below the effective rooting zone without the need for an auxiliary vacuum source. The nitrate concentrations showed large variations over time and ranged between 6–192 mg l^–1 under forest, 19–143 mg l^–1 under wheat, 11–47 mg l^–1 under SRC and 3–138 mg l^–1 under fertilized plantain. The analysis of the soil leachates collected with PCAPS confirms previous results dealing with leaching of nitrate and alkaline and alkaline-earth cations in similar 'soil-crop-climate' systems. It was concluded that PCAPS was a suitable tool to collect soil solutions and that it could help to assess nitrate leaching losses in various ecological or cropping conditions.