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| 三苄基杯[6]芳烃固相微萃取-气相色谱联用测定中草药中有机氯含量 | |
| 引用本文： | 张廉奉,闫书波,朱铭立.三苄基杯[6]芳烃固相微萃取-气相色谱联用测定中草药中有机氯含量[J].河南农业科学,2009(3). |
| 作者姓名： | 张廉奉 闫书波 朱铭立 |
| 作者单位： | 1. 南阳师范学院,化学与制药工程学院,河南,南阳,473061 2. 南阳市农业科学研究所,河南,南阳,473083 3. 广州市农业标准与监测中心,广东,广州,510315 |
| 基金项目： | 河南省科技攻关项目，南阳师范学院资助项目 |
| 摘 要： | 采用三苄基杯6]芳烃/羟基硅油(C6]/OH-TSO)探头固相微萃取(SPME)与气相色谱(GC)联用测定中草药中有机氯农药的残留量。结果表明:萃取温度为70℃,时间为30 min,加入NaCl 2.0 g时,C6]/OH-TSO探头对有机氯农药的萃取效果最佳。8种有机氯农药的加标回收率在88.56%~103.2%,相对标准偏差在6.23%~9.85%,能满足中草药中有机氯农药残留的检测要求。 |
| 关 键 词： | 中草药 有机氯农药 固相微萃取 三苄基杯[6]芳烃 |
Residues of Organochlorine Pesticides(OCPs) in Chinese Herbal Medicines |
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| ZHANG Lian-feng,YAN Shu-bo,ZHU Ming-li.Residues of Organochlorine Pesticides(OCPs) in Chinese Herbal Medicines[J].Journal of Henan Agricultural Sciences,2009(3). | |
| Authors: | ZHANG Lian-feng YAN Shu-bo ZHU Ming-li |
| Institution: | 1.College of Chemistry and Pharmacy Engineering;Nanyang Normal University;Nanyang 473061;China;2.Institute of Agricultural Sciences of Nanyang City;Nanyang 473083;3.Guangzhou Agricultural Standard and Supervisory Center;Guangzhou 510315;China |
| Abstract: | A SPME-GC method was developed to determine the residues of organochlorine pesticides in Chinese herbal medicines.The results indicated that C6]/OH-TSO fiber showed optimal extraction efficiency for OCPs under the conditions of 70℃ and 30 min of extraction time with addition of 2.0g of sodium chloride.The recovery rates of eight organochlorine pesticides were from 88.56 % to 103.2 %.The relative standard deviation(n = 6) values were from 6.23 % to 9.85%,which could meet the detection requirement to the residues of organochlorine pesticides in Chinese herbal medicines. |
| Keywords: | Chinese herbal medicines Organochlorine pesticides Solid-phase microextraction Calix[6]arene |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ | |