| 异长叶烷酮的制备和立体化学 |
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| 引用本文： | 蒋凤池,王甡,李希成. 异长叶烷酮的制备和立体化学[J]. 林产化学与工业, 1988, 0(2) |
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| 作者姓名： | 蒋凤池 王甡 李希成 |
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| 作者单位： | 江西师范大学化学系 南昌(蒋凤池，王甡)，江西师范大学化学系 南昌(李希成) |
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| 摘 要： | 在冰醋酸中以硫酸为催化剂,长叶烯可以异构成异长叶烯,不经分离,加入H_2O_2,主要产物是饱和的异长叶烷酮3α。本文探讨了氧化反应的历程和产物的立体化学。
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| 关 键 词： | 长叶烯 异长叶烯 异长叶烷酮 氧化反应 立体化学 |
CONTROL OXIDATION FOR ISOLONGIFOLENE |
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| Jiang Fengchi Wang Shen Li Xicheng. CONTROL OXIDATION FOR ISOLONGIFOLENE[J]. Chemistry & Industry of Forest Products, 1988, 0(2) |
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| Authors: | Jiang Fengchi Wang Shen Li Xicheng |
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| Abstract: | Longlfolene was isomerized in glacial acetic acid to isolongifolene with H2S04 as catalyst, when H2O2 (30%) was added into the mixture without seperation the main product was isolongifolanone. This paper discusses the mechanism of the oxidation reaction and stereochemistry of the product. |
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| Keywords: | Isolongifolene Isolongifolanone Oxidation reaction Stereo-chemistry. |
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