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纳米金对碳点荧光猝灭的研究
引用本文:沈冬君,、郑鹄志,、隆异娟.纳米金对碳点荧光猝灭的研究[J].西南农业大学学报,2015,37(5):118-122.
作者姓名:沈冬君  、郑鹄志  、隆异娟
作者单位:西南大学化学化工学院 ,重庆,400715
基金项目:国家自然科学基金,西南大学中央高校基本业务费,西南大学博士基金
摘    要:实验发现纳米金(AuNPs)能有效地猝灭碳点(CDs)的荧光.考察了CDs质量浓度、pH值、反应温度和时间等多种因素对荧光猝灭的影响,在最佳实验条件下猝灭常数为9.1×108 L/mol.此外,加入猝灭剂AuNPs前后CDs的荧光寿命基本不变;且随温度升高,猝灭常数减小.因此,推测AuNPs对CDs的荧光猝灭为静态猝灭.

关 键 词:碳点(CDs)    纳米金(AuNPs)    静态猝灭    猝灭常数

A Study of Fluorescence Quenching of Carbon Dots by Gold Nanoparticles
SHEN Dong-jun,ZHENG Hu-zhi,LONG Yi-juan.A Study of Fluorescence Quenching of Carbon Dots by Gold Nanoparticles[J].Journal of Southwest Agricultural University,2015,37(5):118-122.
Authors:SHEN Dong-jun  ZHENG Hu-zhi  LONG Yi-juan
Abstract:We found in this study that gold nanoparticles (AuNPs) could effectively quench the fluorescence of car-bon dots (CDs) .The effects of CDs concentration ,pH ,temperature and inacbating time on fluorescence quenching were investigated .Under the optimal conditions a quenching constant of 9.1 × 108 L/mol was a-chieved .It is worth noting that with increasing inacbating temperature ,the quenching constant decreased . On the other hand ,the fluorescence lifetime of CDs hardly changed in the presence of AuNPs .Therefore , we speculated that the fluorescence quenching of CDs by AuNPs was static quenching .
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