Interference of quantized transition-state pathways in the H + D2 -> D + HD chemical reaction |
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Authors: | Dai Dongxu Wang Chia C Harich Steven A Wang Xiuyan Yang Xueming Der Chao Sheng Skodje Rex T |
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Affiliation: | State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China. |
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Abstract: | The collision-energy dependence of the state-resolved differential cross section at a specific backward-scattering angle for the reaction H + D2 --> D + HD is measured with the D-atom Rydberg "tagging" time-of-flight technique. The reaction was modeled theoretically with converged quantum scattering calculations that provided physical interpretation of the observations. Oscillations in the differential cross sections in the backward-scattering direction are clearly observed and are attributed to the transition-state structures that originate from the interferences of different quantized transition-state pathways. |
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