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草坪缓冲带限制斜坡上葡萄园敌草隆向地表水和地下水迁移效果的研究
引用本文:J.-G. LACAS,N. CARLUER,M. VOLTZ. 草坪缓冲带限制斜坡上葡萄园敌草隆向地表水和地下水迁移效果的研究[J]. 土壤圈, 2012, 22(4): 580-592
作者姓名:J.-G. LACAS  N. CARLUER  M. VOLTZ
作者单位:IRSTEA, UR Qualité des Eaux et Prévention des Pollutions, 3 bis quai Chauveau, 69 336 Lyon Cedex 09 (France);INRA, UMR L. I. S. A. H. INRA-IRD-SupAgro, 2 place Viala, 34060 Montpellier Cedex 1 (France);IRSTEA, UR Qualité des Eaux et Prévention des Pollutions, 3 bis quai Chauveau, 69 336 Lyon Cedex 09 (France);INRA, UMR L. I. S. A. H. INRA-IRD-SupAgro, 2 place Viala, 34060 Montpellier Cedex 1 (France)
基金项目:Supported by the Ministry of Environmental Protection of China(No.201109020)
摘    要:Trichloroethylene (TCE), as one of the most common chlorinated organic compounds in soils and aquifers at many industrial sites, is carcinogenic and often recalcitrant in environment. TCE degradation in artificially contaminated soil samples was conducted using Fenton-like processes, i.e., by addition of excess hydrogen peroxide (H2O2 ). H 2 O 2 could directly oxidize TCE without addition of ferrous iron in contaminated soil. Under the optimal condition (H2O2 concentration of 300 mg kg 1 , pH at 5.0, and reaction time of 30 min), the removal efficiency of TCE in the soil was up to 92.3%. When the initial TCE concentration increased from 30 to 480 mg kg 1 in soil, the TCE removal rates varied from 89.2% to 86.6%; while the residual TCE in soil ranged from 2.28 to 47.57 mg kg 1 . Results from successive oxidations showed that the TCE removal rate with the TCE concentration of 180 mg kg 1 increased slightly from 91.6% to 96.2% as the number of successive oxidation cycle increased from one to four. Therefore, increasing the frequency of H2O2 oxidation was perhaps a feasible way to increase TCE removal rate for TCE-contaminated soil.

关 键 词:chemical oxidation  Fonton  remediation  soil contamination  successive oxidation

Efficiency of a grass buffer strip for limiting diuron losses from an uphill vineyard towards surface and subsurface waters
J.-G. LACAS,N. CARLUER and M. VOLTZ. Efficiency of a grass buffer strip for limiting diuron losses from an uphill vineyard towards surface and subsurface waters[J]. Pedosphere, 2012, 22(4): 580-592
Authors:J.-G. LACAS  N. CARLUER  M. VOLTZ
Affiliation:South China Institute of Environmental Sciences, Ministry of Environmental Protection, Guangzhou 510655 (China);South China Institute of Environmental Sciences, Ministry of Environmental Protection, Guangzhou 510655 (China); School of Chemistry and Environment, South China Normal University, Guangzhou 510630 (China);South China Institute of Environmental Sciences, Ministry of Environmental Protection, Guangzhou 510655 (China); School of Chemistry and Environment, South China Normal University, Guangzhou 510630 (China);School of Chemistry and Environment, South China Normal University, Guangzhou 510630 (China);South China Institute of Environmental Sciences, Ministry of Environmental Protection, Guangzhou 510655 (China);South China Institute of Environmental Sciences, Ministry of Environmental Protection, Guangzhou 510655 (China); College of Resources and Environment, Hunan Agricultural University, Changsha 410128 (China)
Abstract:Trichloroethylene (TCE), as one of the most common chlorinated organic compounds in soils and aquifers at many industrial sites, is carcinogenic and often recalcitrant in environment. TCE degradation in artificially contaminated soil samples were conducted using Fenton-like processes, i.e., by addition of excess hydrogen peroxide (H2O2). H2O2 could directly oxidize TCE without addition of ferrous iron in contaminated soil. At the optimal condition (H2O2 concentration of 300 mg kg-1, pH at 5.0, and reaction time of 30 min), the removal efficiency of TCE in the soil was up to 92.3%. When the initial TCE concentration increased from 30 to 480 mg kg-1 in soil, the TCE removal rates varied from 89.2% to 86.6%; while the residual TCE in soil ranged from 2.28 to 47.57 mg kg-1. Results from successive oxidations showed that the TCE removal rate with the TCE concentration of 180 mg kg-1 increased slightly from 91.6% to 96.2% as the number of successive oxidation cycle increased from one to four. Therefore, increasing the frequency of H2O2 oxidation was perhaps a feasible way to increase TCE removal rate for TCE-contaminated soil.
Keywords:chemical oxidation   Fonton   remediation   soil contamination   successive oxidation
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