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Penetration of hardwoods by liquids
Authors:Alfred J. Stamm
Affiliation:(1) Agricultural Experiment Station, North Carolina State University, Raleigh, N. C.
Abstract:Summary Oven dry highly evacuated sticks of the sapwood of various hardwoods, 40 cm long by 1.0 to 1.2 cm in the radial and tangential directions, took up water to the extent of 44 to 82% of saturation by capillary flow in one minute. Heartwood sticks took up 15 to 38% of saturation in one minute. The initial rapid penetration was followed by a penetration in which the take up increase directly with the square root of elapsed time. In this range, the slope of toluene take up plots was about twice that of the water take up. This is close to the theoratical value on the basis of viscous flow control. The linear portion of the plots is followed by a curvilinear decrease in rate of take up to a final equilibrium value. Water take ups approached 100% of the theoretical values.Times to 0.99 of theoretical filling with water varied from 9 minutes for tupelo gum sapwood to 14.6 to 17.3 days for white oak heartwood. Complete filling with toluene was never attained. Diffuse porous hardwoods filled to the extent of 93.5 to 96.5% of saturation. Ring porous oaks filled to the extent of 88 to 92%, the lower values being for heartwood. Edge coating of the sapwood of yellow poplar and yellow birch with epoxy glue reduced the rate of penetration only slightly. End coating reduced the rate to a higher degree. Moisture gradients in the fiber direction for tyloses-free hardwoods were negligible at various stages of penetration, indicating that filling of the vessels was practically instantaneous. White oak heartwood gave an initial longitudinal gradient followed by a negligible gradient, indicating that longitudinal penetration is primarily through the lumen of the fibers rather than continously through the vessels. Longitudinal penetration was calculated to be 31.5 times as deep as transverse penetration in 100 minutes and 33.3 times as deep in 25 minutes for white oak heartwood. The ratios are of the same order of magnitude as for Loblolly pine. In both cases the ratios are smaller than values calculated from the fiber dimensions alone as ray cell penetration and cross grain effects tend to lower the ratios.Paper No. 3947 of the Journal Series of North Carolina State University Agricultural Experiment Station, Raleigh, N. C.
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