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Distribution of fertiliser N among fixed ammonium fractions as affected by moisture and fertiliser source and rate
Authors:Gregory A. Gouveia  Gaius D. Eudoxie
Affiliation:(1) Department of Food Production, Faculty of Sciences and Agriculture, University of the West Indies, St. Augustine Campus, St. Augustine, Trinidad and Tobago
Abstract:The relevance of fixed $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$ in certain soils and its categorisation has made it necessary to re-examine N behaviour. A replicate factorial experiment was designed to investigate the influence of soil type, soil moisture and fertiliser source and rate on $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$ fixation dynamics with particular attention to the distribution between weakly and strongly fixed pools. Fixation of $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$ was <20% of added N for all soils except River Estate. The percentage of added N present as fixed $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$ was greater for the low application rate. Soil moisture did not significantly influence weakly fixed $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$. However, the dry soil treatment showed greater fertiliser 15N present as strongly fixed $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$. Fertiliser 15N present as weakly and strongly fixed $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$ decreased and increased, respectively, at the second sampling, indicating movement between the pools. The importance of the weakly fixed $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$ fraction as a transitory pool between strongly fixed $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$ and available $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$ was observed.
Keywords:15N Recovery  Fixed   IEq11"  >  /content/b657k415k6842uj6/374_2007_171_Article_IEq11.gif"   alt="  $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$"   align="  middle"   border="  0"  >   Weakly fixed   IEq12"  >  /content/b657k415k6842uj6/374_2007_171_Article_IEq12.gif"   alt="  $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$"   align="  middle"   border="  0"  >   Strongly fixed   IEq13"  >  /content/b657k415k6842uj6/374_2007_171_Article_IEq13.gif"   alt="  $$ {text{NH}}^{{text{ + }}}_{{text{4}}} $$"   align="  middle"   border="  0"  >
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