| 微波裂解光皮树油皂化物脱羧制备烃类燃料研究 |
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| 引用本文： | 刘玉环,王允圃,王应宽,万益琴,张锦胜,阮榕生. 微波裂解光皮树油皂化物脱羧制备烃类燃料研究[J]. 农业机械学报, 2012, 43(2): 106-111,105 |
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| 作者姓名： | 刘玉环 王允圃 王应宽 万益琴 张锦胜 阮榕生 |
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| 作者单位： | 南昌大学;南昌大学;农业部规划设计研究院;南昌大学;南昌大学;南昌大学 |
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| 基金项目： | 国家自然科学基金资助项目(30960304)、国际科技合作计划资助项目 (2010DFB63750)、江西省科技厅产业化关键技术攻关资助项目(2007BN12100)、国家林业局948资助项目（2010409）和江西省国际合作资助项目(2010EHB03200) |
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| 摘 要： | 以光皮树果实油脂通过皂化反应获得的皂类为研究对象,利用微波裂解选择性加热优势开展皂类脱羧制备烃类燃料研究。通过气质联用等方法对裂解产物的分析表明,单纯钠皂微波裂解所得到液态产物一般都在皂类干质量的70%以上,裂解液态产物的密度为0.850～0.875g/cm3,运动粘度为2.09～2.85mm2/s,与柴油的性质基本相似。裂解液态产物中最高峰是十五碳烯,证实脱羧是皂类微波裂解的主要反应形式。
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| 关 键 词： | 微波裂解 生物油 脱羧 烃类燃料 |
Microwave-assisted Pyrolysis of Swida wilsoniana Fruit Oil Soap for Preparing Renewable Hydrocarbon Fuel via Selective Decarboxylation |
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| Liu Yuhuan,Wang Yunpu,Wang Yingkuan,Wan Yiqin,Zhang Jinsheng and Ruan Rongsheng. Microwave-assisted Pyrolysis of Swida wilsoniana Fruit Oil Soap for Preparing Renewable Hydrocarbon Fuel via Selective Decarboxylation[J]. Transactions of the Chinese Society for Agricultural Machinery, 2012, 43(2): 106-111,105 |
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| Authors: | Liu Yuhuan Wang Yunpu Wang Yingkuan Wan Yiqin Zhang Jinsheng Ruan Rongsheng |
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| Affiliation: | Nanchang University;Nanchang University;Chinese Academy of Agricultural Engineering;Nanchang University;Nanchang University;Nanchang University |
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| Abstract: | In order to prepare hydrocarbon fuel,sodium soap made from Swida wilsoniana fruit oil was chosen as a model compound with significant molecular polarity for preparing hydrocarbon fuel by microwave-assisted pyrolysis.The result showed that the hydrocarbon content were usually above 70%.In addition,its density and dynamic viscosity were 0.850～0.875g/cm3 and 2.09～2.85mm2/s,respectively,similar with petroleum diesel.The highest peak in the GC-MS profile of liquid product was fifteen carbon alkenes,decarboxylation was proved to be main reaction in microwave-assisted pyrolysis. |
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| Keywords: | Microwave-ssisted pyrolysis Bio-il Decarboxylation Hydrocarbon fuels |
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