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Metabolism of the fungicide triforine in barley plants
Authors:Jean P. Rouchaud  Jacques R. Decallonne  Joseph A. Meyer
Abstract:The metabolic fate of [3H]-triforine in barley plants has been studied. 15 and 30 days after treatment, unchanged triforine amounted to 57.5 and 43.2% respectively, and of three soluble metabolites detected, piperazine (0.3 and 4.0%) and N-[2, 2,2-trichloro-1-(piperazin-1-yl)ethyl] formamide (12.9 and 8.4%), the latter for the first time as a metabolite in plants, were identified using t.1.c. with four solvent systems. The solid residue contained 23.1 and 38.2% of bound label after 15 and 30 days respectively.
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